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7,14-Methano-4H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-4-one, 2,3,7,7a,8,9,10,11,13,14-decahydro-, [7S-(7«alpha»,7a«beta»,14«alpha»)]-


Normal alkane RI, non-polar column, custom temperature program

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5 MSDB-1OV-1DB-1DB-1
Column length (m) 30.15.15.15.30.
Carrier gas  HeliumHeHeHe
Substrate      
Column diameter (mm) 0.250.3170.250.250.32
Phase thickness (mum)      
Program 100 0C (1 min) 40 0C/min -> 200 0C 5 0C/min -> 275 0C (15 min)150 0C (2 min) 15 0C/min -> 250 0C 25 0C/min -> 300 0C (5 min)120C (2min) => 10C/min => 250C => 15C/min => 300C150C(2min) => 10C/min => 250C => 20C/min => 300C (10min)150C (2min) => 10C/min => 250C => 20C/min => 300C (5min)
I 2104.2132.2132.2130.2130.
ReferenceCook, Lee, et al., 2009El-Shazly, Ateya, et al., 2001Asres, Tei, et al., 1997Greinwald, Ross, et al., 1996Greinwald, van Rensen, et al., 1995
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillary
Active phase DB-1DB-1DB-1
Column length (m) 30.30.30.
Carrier gas He He
Substrate    
Column diameter (mm) 0.320.30.32
Phase thickness (mum)    
Program 150C (2min) => 10C/min => 250C => 20C/min => 300C (5min)not specified150C (2min) => 10C/min => 250C => 20C/min => 300C (5min)
I 2130.2132.2130.
ReferenceGreinwald, Ross, et al., 1995Wink, Meissner, et al., 1995Greinwald, Witte, et al., 1991
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, custom temperature program, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cook, Lee, et al., 2009
Cook, D.; Lee, S.T.; GArdner, D.R.; Pfister, J.A.; Welch, K.D.; Green, B.T.; Davis, T.Z.; Panter, K.E., The alkaloids profiles of lupinus sulphureus, J. Agric. Food Chem., 2009, 57, 4, 1646-1653, https://doi.org/10.1021/jf803468q . [all data]

El-Shazly, Ateya, et al., 2001
El-Shazly, A.; Ateya, A.-M.M.; Wink, M., Quinolizidine alkaloid profiles of lupunus varius orientalis. L. albus albus, L. hartwegii, and L. densiflorus, Z. Naturforsch., 2001, 56c, 21-30. [all data]

Asres, Tei, et al., 1997
Asres, K.; Tei, A.; Wink, M., Quinolizidine alkaloids from the East-African legume Dicraeopetalum stipulare harms, Biochem. Syst. Ecol., 1997, 25, 4, 305-308, https://doi.org/10.1016/S0305-1978(97)00004-5 . [all data]

Greinwald, Ross, et al., 1996
Greinwald, R.; Ross, J.H.; Witte, L.; Czygan, F.-C., Alkaloids of Templetonia incana, Biochem. Syst. Ecol., 1996, 24, 5, 423-426, https://doi.org/10.1016/0305-1978(96)00024-5 . [all data]

Greinwald, van Rensen, et al., 1995
Greinwald, R.; van Rensen, I.; Veit, M.; Canto, P.; Witte, L., A chemical dichotomy in quinolizidine alkaloid accumulation within the section Spartioides of the genus Genista (Fabaceae: Genisteae), Biochem. Syst. Ecol., 1995, 23, 1, 89-97, https://doi.org/10.1016/0305-1978(95)93662-M . [all data]

Greinwald, Ross, et al., 1995
Greinwald, R.; Ross, J.H.; Witte, L.; Czygan, F.-C., The alkaloid pattern of Plagiocarpus axillaris (Fabaceae: Brongniartieae), Biochem. Syst. Ecol., 1995, 23, 6, 645-648, https://doi.org/10.1016/0305-1978(95)00059-3 . [all data]

Wink, Meissner, et al., 1995
Wink, M.; Meissner, C.; Witte, L., Patterns of quinolizidine alkaloids in 56 species of the genus Lupinus, Phytochemistry, 1995, 38, 1, 139-153, https://doi.org/10.1016/0031-9422(95)91890-D . [all data]

Greinwald, Witte, et al., 1991
Greinwald, R.; Witte, L.; Wray, V.; Czygan, F.-C., The alkaloid pattern of Cytisophyllum sessilitolium (Fabaceae-Genisteae), Biochem. Syst. Ecol., 1991, 19, 3, 253-258, https://doi.org/10.1016/0305-1978(91)90010-W . [all data]


Notes

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