7,14-Methano-4H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-4-one, 2,3,7,7a,8,9,10,11,13,14-decahydro-, [7S-(7α,7aβ,14α)]-
- Formula: C15H22N2O
- Molecular weight: 246.3480
- IUPAC Standard InChI: InChI=1S/C15H22N2O/c18-15-6-3-5-14-11-8-12(10-17(14)15)13-4-1-2-7-16(13)9-11/h5,11-13H,1-4,6-10H2
- IUPAC Standard InChIKey: GSQQGCZVTAUICD-UHFFFAOYSA-N
- CAS Registry Number: 32101-29-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Lupanine, 5,6-didehydro-; Lupanine, dehydro-; 5,6-Dehydrolupanine; 7,14-Methano-4H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-4-one, 2,3,7,7a,8,9,10,11,13,14-decahydro-, (7α,7aβ,14α)-; 5,6-dehydroisolupanine
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Normal alkane RI, non-polar column, custom temperature program
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-5 MS | DB-1 | OV-1 | DB-1 | DB-1 |
| Column length (m) | 30. | 15. | 15. | 15. | 30. |
| Carrier gas | Helium | He | He | He | |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.317 | 0.25 | 0.25 | 0.32 |
| Phase thickness (μm) | |||||
| Program | 100 0C (1 min) 40 0C/min -> 200 0C 5 0C/min -> 275 0C (15 min) | 150 0C (2 min) 15 0C/min -> 250 0C 25 0C/min -> 300 0C (5 min) | 120C (2min) => 10C/min => 250C => 15C/min => 300C | 150C(2min) => 10C/min => 250C => 20C/min => 300C (10min) | 150C (2min) => 10C/min => 250C => 20C/min => 300C (5min) |
| I | 2104. | 2132. | 2132. | 2130. | 2130. |
| Reference | Cook, Lee, et al., 2009 | El-Shazly, Ateya, et al., 2001 | Asres, Tei, et al., 1997 | Greinwald, Ross, et al., 1996 | Greinwald, van Rensen, et al., 1995 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary |
|---|---|---|---|
| Active phase | DB-1 | DB-1 | DB-1 |
| Column length (m) | 30. | 30. | 30. |
| Carrier gas | He | He | |
| Substrate | |||
| Column diameter (mm) | 0.32 | 0.3 | 0.32 |
| Phase thickness (μm) | |||
| Program | 150C (2min) => 10C/min => 250C => 20C/min => 300C (5min) | not specified | 150C (2min) => 10C/min => 250C => 20C/min => 300C (5min) |
| I | 2130. | 2132. | 2130. |
| Reference | Greinwald, Ross, et al., 1995 | Wink, Meissner, et al., 1995 | Greinwald, Witte, et al., 1991 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, custom temperature program, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Cook, Lee, et al., 2009
Cook, D.; Lee, S.T.; GArdner, D.R.; Pfister, J.A.; Welch, K.D.; Green, B.T.; Davis, T.Z.; Panter, K.E.,
The alkaloids profiles of lupinus sulphureus,
J. Agric. Food Chem., 2009, 57, 4, 1646-1653, https://doi.org/10.1021/jf803468q
. [all data]
El-Shazly, Ateya, et al., 2001
El-Shazly, A.; Ateya, A.-M.M.; Wink, M.,
Quinolizidine alkaloid profiles of lupunus varius orientalis. L. albus albus, L. hartwegii, and L. densiflorus,
Z. Naturforsch., 2001, 56c, 21-30. [all data]
Asres, Tei, et al., 1997
Asres, K.; Tei, A.; Wink, M.,
Quinolizidine alkaloids from the East-African legume Dicraeopetalum stipulare harms,
Biochem. Syst. Ecol., 1997, 25, 4, 305-308, https://doi.org/10.1016/S0305-1978(97)00004-5
. [all data]
Greinwald, Ross, et al., 1996
Greinwald, R.; Ross, J.H.; Witte, L.; Czygan, F.-C.,
Alkaloids of Templetonia incana,
Biochem. Syst. Ecol., 1996, 24, 5, 423-426, https://doi.org/10.1016/0305-1978(96)00024-5
. [all data]
Greinwald, van Rensen, et al., 1995
Greinwald, R.; van Rensen, I.; Veit, M.; Canto, P.; Witte, L.,
A chemical dichotomy in quinolizidine alkaloid accumulation within the section Spartioides of the genus Genista (Fabaceae: Genisteae),
Biochem. Syst. Ecol., 1995, 23, 1, 89-97, https://doi.org/10.1016/0305-1978(95)93662-M
. [all data]
Greinwald, Ross, et al., 1995
Greinwald, R.; Ross, J.H.; Witte, L.; Czygan, F.-C.,
The alkaloid pattern of Plagiocarpus axillaris (Fabaceae: Brongniartieae),
Biochem. Syst. Ecol., 1995, 23, 6, 645-648, https://doi.org/10.1016/0305-1978(95)00059-3
. [all data]
Wink, Meissner, et al., 1995
Wink, M.; Meissner, C.; Witte, L.,
Patterns of quinolizidine alkaloids in 56 species of the genus Lupinus,
Phytochemistry, 1995, 38, 1, 139-153, https://doi.org/10.1016/0031-9422(95)91890-D
. [all data]
Greinwald, Witte, et al., 1991
Greinwald, R.; Witte, L.; Wray, V.; Czygan, F.-C.,
The alkaloid pattern of Cytisophyllum sessilitolium (Fabaceae-Genisteae),
Biochem. Syst. Ecol., 1991, 19, 3, 253-258, https://doi.org/10.1016/0305-1978(91)90010-W
. [all data]
Notes
Go To: Top, Normal alkane RI, non-polar column, custom temperature program, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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