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Propyl,heptafluoro

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to C3F7+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
>2.70 ± 0.20EIAESpyrou, Hunter, et al., 1985From i-C5F12; B
>2.70 ± 0.20EIAESpyrou, Hunter, et al., 1985From i-C5F12; B
>2.65 ± 0.10EIAESpyrou, Hunter, et al., 1985From i-C4F10; B
>2.60 ± 0.15EIAESpyrou, Sauers, et al., 1983From n-C5F12; B
>2.65 ± 0.20EIAESpyrou, Sauers, et al., 1983From i-C4F10; B
>2.65 ± 0.40EIAESpyrou, Sauers, et al., 1983From C3F8.; B
>2.50 ± 0.40EIAESpyrou, Sauers, et al., 1983From n-C4F10. G3MP2B3 calculations indicate an EA of ca.1.9 eV, and HOF(A-) of -260 kcal/mol; B
>2.75 ± 0.10EIAESpyrou, Sauers, et al., 1983From n-C6F14; B
>2.20 ± 0.20EIAEHarland and Thynne, 1973From n-C4F10. G3MP2B3 calculations indicate an EA of ca.1.9 eV, and HOF(A-) of -260 kcal/mol; B
>2.30 ± 0.20EIAEHarland and Thynne, 1972From C3F8.; B
>2.39999EIAELifshitz and Grajower, 1969From C3F8.; B
>3.40 ± 0.30EIAESpyrou, Hunter, et al., 1985From neo-C5F12; B

Ionization energy determinations

IE (eV) Method Reference Comment
10.1 ± 0.1EIFisher, Homer, et al., 1965RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Spyrou, Hunter, et al., 1985
Spyrou, S.M.; Hunter, S.R.; Christophorou, L.G., A study of the isomeric dependence of low-energy (<10 eV) electron attachment: Perfluoroalkanes, J. Chem. Phys., 1985, 83, 641. [all data]

Spyrou, Sauers, et al., 1983
Spyrou, S.M.; Sauers, I.; Christophorou, L.G., Electron attachment to the perfluoroalkanes n-CnF2n+2 (n = 1-6) and i-C4F10, J. Chem. Phys., 1983, 78, 7200. [all data]

Harland and Thynne, 1973
Harland, P.W.; Thynne, J.C.J., Negative ion formation by perfluoro-n-butane as the result of low energy electron impact, Int. J. Mass Spectrom. Ion Phys., 1973, 11, 445. [all data]

Harland and Thynne, 1972
Harland, P.W.; Thynne, J.C.J., Dissociative electron capture in perfluoropropylene and perfluoropropane, Int. J. Mass Spectrom. Ion Phys., 1972, 9, 253. [all data]

Lifshitz and Grajower, 1969
Lifshitz, C.; Grajower, R., Dissociative electron capture and dissociative ionization in perfluoropropane, Intern. J. Mass Spectrom. Ion Phys., 1969, 3, 211. [all data]

Fisher, Homer, et al., 1965
Fisher, I.P.; Homer, J.B.; Lossing, F.P., Free radicals by mass spectrometry. XXXIII. Ionization potentials of CF2, CF3CF2, CF3CH2, n-C3F7, and i-C3F7 radicals, J. Am. Chem. Soc., 1965, 87, 957. [all data]


Notes

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