Methylthiomethyl radical


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
B - John E. Bartmess

View reactions leading to C2H5S+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
0.868 ± 0.051LPESMoran and Ellison, 1988B
0.74 ± 0.10D-EAIngemann and Nibbering, 1985B

Ionization energy determinations

IE (eV) Method Reference Comment
6.85 ± 0.03PEBaker and Dyke, 1993LL

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Moran and Ellison, 1988
Moran, S.; Ellison, G.B., Photoelectron Spectroscopy of Sulfur Ions, J. Phys. Chem., 1988, 92, 7, 1794, https://doi.org/10.1021/j100318a021 . [all data]

Ingemann and Nibbering, 1985
Ingemann, S.; Nibbering, N.M.M., Gas phase chemistry of alpha-thio carbanions, Can. J. Chem., 1985, 62, 2273. [all data]

Baker and Dyke, 1993
Baker, J.; Dyke, J.M., A photoelectron and ab initio study of the CH3SCH2 radical, Chem. Phys. Lett., 1993, 213, 257. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References