Perfluorotributylamine

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-5583.5kJ/molCcrErastov and Kolesov, 1979The hf_condensed corrected by Kolesov and Kozina, 1986

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-5643.8kJ/molCcrErastov and Kolesov, 1979The hf_condensed corrected by Kolesov and Kozina, 1986
Quantity Value Units Method Reference Comment
Δcliquid-3852. ± 9.2kJ/molCcrErastov and Kolesov, 1979The hf_condensed corrected by Kolesov and Kozina, 1986

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil451.KN/APCR Inc., 1990BS
Tboil452.2KN/AWeast and Grasselli, 1989BS
Tboil451.95KN/AKyle and Tetlow, 1960Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Δvap60.3 ± 0.1kJ/molCVarouchtchenko and Droujinina, 1995AC
Δvap60.4 ± 1.2kJ/molVErastov and Kolesov, 1979The hf_condensed corrected by Kolesov and Kozina, 1986; ALS
Δvap60.4 ± 1.2kJ/molN/AVarushchenko, Ammar, et al., 1977See also Varushchenko, Ammar, et al., 1977, 2.; AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
57.4313.AStephenson and Malanowski, 1987Based on data from 298. - 450. K.; AC
51.1386.AStephenson and Malanowski, 1987Based on data from 371. - 544. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Sadtler Research Labs Under US-EPA Contract
State gas

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-IW-3056
NIST MS number 233906

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Erastov and Kolesov, 1979
Erastov, P.A.; Kolesov, V.P., Thermodynamic properties of nitrogen-containing organofluorine compounds. Enthalpies of formation of perfluorotriethylamine and perfluorotributylamine, J. Gen. Chem. USSR (Engl. Transl.), 1979, 49, 1186-1189. [all data]

Kolesov and Kozina, 1986
Kolesov, V.P.; Kozina, M.P., Thermochemistry of organic and organohalogen compounds, Russ. Chem. Rev., 1986, 55, 912. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Kyle and Tetlow, 1960
Kyle, B.G.; Tetlow, N.J., Perfluorotributylamine as an Extractive Distillation Solvent for a Hydrocarbon Mixture, J. Chem. Eng. Data, 1960, 5, 275. [all data]

Varouchtchenko and Droujinina, 1995
Varouchtchenko, R.M.; Droujinina, A.I., Thermodynamics of vaporization of some perfluorotrialkylamines, J. Chem. Thermodyn., 1995, 27, 355-368. [all data]

Varushchenko, Ammar, et al., 1977
Varushchenko, R.M.; Ammar, M.M.; Bulgakova, L.L., Russ. J. Phys. Chem., 1977, 51, 167. [all data]

Varushchenko, Ammar, et al., 1977, 2
Varushchenko, R.M.; Ammar, M.M.; Bulgakova, L.L., Zh. Fiz. Khim., 1977, 51, 278. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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