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Sulfur trifluoride


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: J.E. Bartmess

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Individual Reactions

(F4S- bullet 4294967295Sulfur trifluoride) + Sulfur trifluoride = F4S-

By formula: (F4S- bullet 4294967295F3S) + F3S = F4S-

Quantity Value Units Method Reference Comment
Deltar177. ± 13.kJ/molTherMiller, Miller, et al., 1995gas phase
Deltar182. ± 32.kJ/molTherViggiano, MIller, et al., 1991gas phase; Between mCF3-nitrobenzene, C6F5NO2
Deltar264. ± 39.kJ/molTherBabcock and Streit, 1981gas phase; EA: between NO2-, HS-

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Miller, Miller, et al., 1995
Miller, A.E.S.; Miller, T.M.; Viggiano, A.A.; Morris, R.A.; Vandoren, J.M.; Arnold, S.T.; Paulson, J., Negative ion chemistry of SF4, J. Chem. Phys., 1995, 102, 22, 8865, https://doi.org/10.1063/1.468940 . [all data]

Viggiano, MIller, et al., 1991
Viggiano, A.A.; MIller, T.M.; Miller, A.E.S.; Morris, R.A.; Van Doren, J.M.; Paulson, J.F., SF4: Electron Affinity Determination by Charge Transfer Reactions, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 327, https://doi.org/10.1016/0168-1176(91)85112-Y . [all data]

Babcock and Streit, 1981
Babcock, L.M.; Streit, G.E., Negative ion-molecule reactions of SF4, J. Chem. Phys., 1981, 75, 3864. [all data]


Notes

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