Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

NOTICE: Due to scheduled maintenance at our Gaithersburg campus, this site will not be available from 5:00 pm EDT (21:00 UTC) on Friday October 25 until 5:00 pm (21:00 UTC) on Sunday October 27. We apologize for any inconvenience this outage may cause.

titanium(4+) ethanolate


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-328.6 ± 2.4kcal/molReviewMartinho Simões 
Deltafgas-325.9 ± 2.2kcal/molReviewMartinho Simões 
Deltafgas-324.6 ± 2.4kcal/molReviewMartinho Simões 
Deltafgas-325.2 ± 2.2kcal/molReviewMartinho SimõesSelected data. Average of the RSC results Bradley and Hillyer, 1966

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafliquid-352.6 ± 1.2kcal/molReviewMartinho Simões 
Deltafliquid-349.88 ± 0.79kcal/molReviewMartinho Simões 
Deltafliquid-348.6 ± 1.3kcal/molReviewMartinho Simões 
Deltafliquid-349.24 ± 0.74kcal/molReviewMartinho SimõesSelected data. Average of the RSC results Bradley and Hillyer, 1966
Quantity Value Units Method Reference Comment
Deltacliquid-1308.6 ± 1.2kcal/molCC-SBShaulov, Genchel, et al., 1972Please also see Pedley and Rylance, 1977 and Tel'noi and Rabinovich, 1977.

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltavap24.0 ± 2.0kcal/molCC-SBBradley and Hillyer, 1966Please also see Pedley and Rylance, 1977.

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

4Ethanol (l) + Titanium tetrachloride (l) = titanium(4+) ethanolate (l) + 4(Hydrogen chloride bullet 51.3Water) (solution)

By formula: 4C2H6O (l) + Cl4Ti (l) = C8H20O4Ti (l) + 4(HCl bullet 51.3H2O) (solution)

Quantity Value Units Method Reference Comment
Deltar-49.1 ± 1.0kcal/molRSCBradley and Hillyer, 1966Please also see Pedley and Rylance, 1977.

4Ethanol (l) + Titanium tetrachloride (l) = titanium(4+) ethanolate (l) + 4Hydrogen chloride (g)

By formula: 4C2H6O (l) + Cl4Ti (l) = C8H20O4Ti (l) + 4HCl (g)

Quantity Value Units Method Reference Comment
Deltar19.5 ± 0.1kcal/molRSCBradley and Hillyer, 1966Please also see Pedley and Rylance, 1977.

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Bradley and Hillyer, 1966
Bradley, D.C.; Hillyer, M.J., Trans. Faraday Soc., 1966, 62, 2367. [all data]

Shaulov, Genchel, et al., 1972
Shaulov, Yu.Kh.; Genchel, V.G.; Aizatullova, R.M.; Petrova, N.V., Zh. Fiz. Khim., 1972, 46, 2382. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B., Russ. Chem. Rev., 1977, 46, 689. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References