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Diamantan-1-ol

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-310.9 ± 1.2kJ/molCcbClark, Knox, et al., 1980 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafsolid-428.8 ± 1.0kJ/molCcbClark, Knox, et al., 1980 
Quantity Value Units Method Reference Comment
Deltacsolid-7938.6 ± 1.0kJ/molCcbClark, Knox, et al., 1980Corresponding «DELTA»fsolid = -428.82 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltasub117.9kJ/molN/AClark, Knox, et al., 1980DRB

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
118. ± 0.6334.N/AClark, Knox, et al., 1980, 2Based on data from 319. - 349. K. See also Clark, Knox, et al., 1975.; AC
117.9 ± 0.59334.CClark, Knox, et al., 1980ALS

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference Comment
9.6573.DSCClark, McKervey, et al., 1974AC

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Clark, Knox, et al., 1980
Clark, T.; Knox, T.M.; McKervey, M.A.; Mackle, H., Thermochemistry of bridged-ring substances. Enthalpies of formation of diamantan-1-, -3-, and -4-ol and of diamantanone, J. Chem. Soc. Perkin Trans. 2, 1980, 1686-1689. [all data]

Clark, Knox, et al., 1980, 2
Clark, Timothy; Knox, McO.; McKervey, M. Anthony; Mackle, Henry, Thermochemistry of bridged-ring substances. Enthalpies of formation of diamantan-1-, -3-, and -4-ol and of diamantanone, J. Chem. Soc., Perkin Trans. 2, 1980, 11, 1686, https://doi.org/10.1039/p29800001686 . [all data]

Clark, Knox, et al., 1975
Clark, Timothy; Knox, Trevor; Mackle, Henry; McKervey, M. Anthony; Rooney, John J., Heats of sublimation of some cage hydrocarbons by a temperature scanning technique, J. Chem. Soc., Faraday Trans. 1, 1975, 71, 0, 2107, https://doi.org/10.1039/f19757102107 . [all data]

Clark, McKervey, et al., 1974
Clark, Timothy; McKervey, M. Anthony; Mackle, Henry; Rooney, John J., Pre-melting transitions in caged hydrocarbons, a general theory of disorder in plastic crystals, J. Chem. Soc., Faraday Trans. 1, 1974, 70, 0, 1279, https://doi.org/10.1039/f19747001279 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References