Methyl peroxide


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Δfgas-131.0kJ/molEqkKhursan and Martem'yanov, 1991hf from V. P.Komissarov's report; ALS

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
35.8250.Dorofeeva O.V., 1997p=1 bar.; GT
43.12100.
48.61150.
53.14200.
63. ± 3.298.15
62.88300.
73.65400.
83.78500.
92.60600.
100.17700.
106.70800.
112.36900.
117.291000.
121.581100.
125.331200.
128.611300.
131.471400.
133.981500.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Khursan and Martem'yanov, 1991
Khursan, S.L.; Martem'yanov, V.S., Thermochemistry of the recombination of peroxyl radicals, Russ. J. Phys. Chem. (Engl. Transl.), 1991, 65, 321-325. [all data]

Dorofeeva O.V., 1997
Dorofeeva O.V., Unpublished results. Thermocenter of Russian Academy of Science, Moscow, 1997. [all data]


Notes

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