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CH2N(CH3)2


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

View reactions leading to C3H8N+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Deltaf(+) ion158.kcal/molN/AN/A 

Electron affinity determinations

EA (eV) Method Reference Comment
<-0.118 ± 0.066D-EAMacKay and Bohme, 1978Computations put dHacid ca. 412 kcal/mol; B

Ionization energy determinations

IE (eV) Method Reference Comment
5.7DERBurkey, Castelhano, et al., 1983LBLHLM
5.35PILoguinov, Takhistov, et al., 1981LLK
5.7DERGriller and Lossing, 1981LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

MacKay and Bohme, 1978
MacKay, G.I.; Bohme, D.K., Proton-Transfer Reactions in Nitromethane at 297K, Int. J. Mass Spectrom. Ion Phys., 1978, 26, 4, 327, https://doi.org/10.1016/0020-7381(78)80052-7 . [all data]

Burkey, Castelhano, et al., 1983
Burkey, T.J.; Castelhano, A.L.; Griller, D.; Lossing, F.P., Heats of formation and ionization potentials of some «alpha»-aminoalkyl radicals, J. Am. Chem. Soc., 1983, 105, 4701. [all data]

Loguinov, Takhistov, et al., 1981
Loguinov, Y.; Takhistov, V.V.; Vatlina, L.P., Photoionization studies of substituted trimethylamines, Org. Mass Spectrom., 1981, 16, 239. [all data]

Griller and Lossing, 1981
Griller, D.; Lossing, F.P., On the thermochemistry of «alpha»-aminoalkyl radicals, J. Am. Chem. Soc., 1981, 103, 1586. [all data]


Notes

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