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Phosphorodithioic acid, O,O,S-trimethyl ester


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference
9.0 ± 0.10EISantoro, 1973

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH2PS+14.05 ± 0.30H+HCHO+HSEISantoro, 1973 
CH3+14.50 ± 0.40?EISantoro, 1973 
CH4OP+13.40 ± 0.30?EISantoro, 1973 
CH4O2P+12.75 ± 0.20CH3S+HCHSEISantoro, 1973 
C2H6OPS+11.70 ± 0.20HCHO+HSEISantoro, 1973 
C2H6OPS2+10.20 ± 0.30CH3OEISantoro, 1973 
C2H6O2P+10.40 ± 0.10?EISantoro, 1973 
C2H6O2PS+10.10 ± 0.10CH3SEISantoro, 1973 
C2H6O2PS2+9.65 ± 0.20CH3EISantoro, 1973 
C2H7OPS2+10.00 ± 0.10HCHOEISantoro, 1973 
C2H7O2PS+10.35 ± 0.10HCHSEISantoro, 1973 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Santoro, 1973
Santoro, E., The fragmentation of some alkyl thiophosphate esters by electron-impact, Org. Mass Spectrom., 1973, 7, 589. [all data]


Notes

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