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Carbon monosulfide


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafgas280.33kJ/molReviewChase, 1998Data last reviewed in December, 1976
Quantity Value Units Method Reference Comment
gas,1 bar210.55J/mol*KReviewChase, 1998Data last reviewed in December, 1976

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. - 600.600. - 6000.
A 21.7638734.47721
B 24.998902.966255
C -8.095581-0.950722
D -4.5639490.113718
E 0.126372-0.997482
F 273.2328267.0275
G 230.5497247.0731
H 280.3284280.3284
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1976 Data last reviewed in December, 1976

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Iron ion (1+) + Carbon monosulfide = (Iron ion (1+) bullet Carbon monosulfide)

By formula: Fe+ + CS = (Fe+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar207. ± 13.kJ/molCIDTRodgers and Armentrout, 2000 
Deltar231. ± 12.kJ/molCIDTSchroeder, Kretzschmar, et al., 1999 

Cobalt ion (1+) + Carbon monosulfide = (Cobalt ion (1+) bullet Carbon monosulfide)

By formula: Co+ + CS = (Co+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar258. ± 33.kJ/molCIDTRue, Armentrout, et al., 2001 
Deltar240. ± 9.2kJ/molCIDTRodgers and Armentrout, 2000 

Chromium ion (1+) + Carbon monosulfide = (Chromium ion (1+) bullet Carbon monosulfide)

By formula: Cr+ + CS = (Cr+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar163. ± 5.9kJ/molCIDTRue, Armentrout, et al., 2001, 2 
Deltar158. ± 9.2kJ/molCIDTRodgers and Armentrout, 2000 

Manganese ion (1+) + Carbon monosulfide = (Manganese ion (1+) bullet Carbon monosulfide)

By formula: Mn+ + CS = (Mn+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar80. ± 21.kJ/molCIDTRue, Armentrout, et al., 2001, 2 
Deltar78. ± 14.kJ/molCIDTRodgers and Armentrout, 2000 

Molybdenum ion (1+) + Carbon monosulfide = (Molybdenum ion (1+) bullet Carbon monosulfide)

By formula: Mo+ + CS = (Mo+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar162. ± 13.kJ/molCIDTSchroeder, Kretzschmar, et al., 2003 
Deltar162. ± 18.kJ/molCIDTRodgers and Armentrout, 2000 

Titanium ion (1+) + Carbon monosulfide = (Titanium ion (1+) bullet Carbon monosulfide)

By formula: Ti+ + CS = (Ti+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar154. ± 5.9kJ/molCIDTRodgers and Armentrout, 2000 

Scandium ion (1+) + Carbon monosulfide = (Scandium ion (1+) bullet Carbon monosulfide)

By formula: Sc+ + CS = (Sc+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar133. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000 

Zirconium ion (1+) + Carbon monosulfide = (Zirconium ion (1+) bullet Carbon monosulfide)

By formula: Zr+ + CS = (Zr+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar258. ± 11.kJ/molCIDTRodgers and Armentrout, 2000 

Silver ion (1+) + Carbon monosulfide = (Silver ion (1+) bullet Carbon monosulfide)

By formula: Ag+ + CS = (Ag+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar152. ± 20.kJ/molCIDTRodgers and Armentrout, 2000 

Vanadium ion (1+) + Carbon monosulfide = (Vanadium ion (1+) bullet Carbon monosulfide)

By formula: V+ + CS = (V+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar164. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000 

Yttrium ion (1+) + Carbon monosulfide = (Yttrium ion (1+) bullet Carbon monosulfide)

By formula: Y+ + CS = (Y+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar137. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000 

Nickel ion (1+) + Carbon monosulfide = (Nickel ion (1+) bullet Carbon monosulfide)

By formula: Ni+ + CS = (Ni+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar236. ± 9.2kJ/molCIDTRodgers and Armentrout, 2000 

Zinc ion (1+) + Carbon monosulfide = (Zinc ion (1+) bullet Carbon monosulfide)

By formula: Zn+ + CS = (Zn+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar141. ± 9.2kJ/molCIDTRodgers and Armentrout, 2000 

Copper ion (1+) + Carbon monosulfide = (Copper ion (1+) bullet Carbon monosulfide)

By formula: Cu+ + CS = (Cu+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar234. ± 10.kJ/molCIDTRodgers and Armentrout, 2000 

Niobium ion (1+) + Carbon monosulfide = (Niobium ion (1+) bullet Carbon monosulfide)

By formula: Nb+ + CS = (Nb+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar242. ± 11.kJ/molCIDTRodgers and Armentrout, 2000 

Ruthenium ion (1+) + Carbon monosulfide = (Ruthenium ion (1+) bullet Carbon monosulfide)

By formula: Ru+ + CS = (Ru+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar253. ± 20.kJ/molCIDTRodgers and Armentrout, 2000 

Palladium ion (1+) + Carbon monosulfide = (Palladium ion (1+) bullet Carbon monosulfide)

By formula: Pd+ + CS = (Pd+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar200. ± 14.kJ/molCIDTRodgers and Armentrout, 2000 

Rh+ + Carbon monosulfide = (Rh+ bullet Carbon monosulfide)

By formula: Rh+ + CS = (Rh+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar234. ± 19.kJ/molCIDTRodgers and Armentrout, 2000 

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Schroeder, Kretzschmar, et al., 1999
Schroeder, D.; Kretzschmar, I.; Schwarz; Rue, C.; Armentrout, P.B., On the Structural Dichotomy of Cationic, Anionic, and Neutral FeS2, Inorg. Chem., 1999, 38, 15, 3474, https://doi.org/10.1021/ic990241b . [all data]

Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of Fe+ and Co+ With CS2 and COS, J. Phys. Chem. A, 2001, 105, 37, 8456, https://doi.org/10.1021/jp0120716 . [all data]

Rue, Armentrout, et al., 2001, 2
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of the State-Specific Reactions of Cr+ and Mn+ with CS2 and COS, Int. J. Mass Spectrom., 2001, 210/211, 283, https://doi.org/10.1016/S1387-3806(01)00400-6 . [all data]

Schroeder, Kretzschmar, et al., 2003
Schroeder, D.; Kretzschmar, I.; Schwarz; Armentrout, P.B., Structure, Thermochemistry, and Reactivityof MSn+ Cations (M=V,Mo; n=1-3) in the Gas Phase, Int. J. Mass Spectrom., 2003, 228, 2-3, 439, https://doi.org/10.1016/S1387-3806(03)00137-4 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References