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Carbon monosulfide


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Iron ion (1+) + Carbon monosulfide = (Iron ion (1+) bullet Carbon monosulfide)

By formula: Fe+ + CS = (Fe+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar49.5 ± 3.1kcal/molCIDTRodgers and Armentrout, 2000 
Deltar55.2 ± 2.8kcal/molCIDTSchroeder, Kretzschmar, et al., 1999 

Cobalt ion (1+) + Carbon monosulfide = (Cobalt ion (1+) bullet Carbon monosulfide)

By formula: Co+ + CS = (Co+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar61.7 ± 7.8kcal/molCIDTRue, Armentrout, et al., 2001 
Deltar57.4 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Chromium ion (1+) + Carbon monosulfide = (Chromium ion (1+) bullet Carbon monosulfide)

By formula: Cr+ + CS = (Cr+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar38.9 ± 1.4kcal/molCIDTRue, Armentrout, et al., 2001, 2 
Deltar37.8 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Manganese ion (1+) + Carbon monosulfide = (Manganese ion (1+) bullet Carbon monosulfide)

By formula: Mn+ + CS = (Mn+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar19.1 ± 5.1kcal/molCIDTRue, Armentrout, et al., 2001, 2 
Deltar18.6 ± 3.3kcal/molCIDTRodgers and Armentrout, 2000 

Molybdenum ion (1+) + Carbon monosulfide = (Molybdenum ion (1+) bullet Carbon monosulfide)

By formula: Mo+ + CS = (Mo+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar38.7 ± 3.2kcal/molCIDTSchroeder, Kretzschmar, et al., 2003 
Deltar38.7 ± 4.3kcal/molCIDTRodgers and Armentrout, 2000 

Titanium ion (1+) + Carbon monosulfide = (Titanium ion (1+) bullet Carbon monosulfide)

By formula: Ti+ + CS = (Ti+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar36.8 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000 

Scandium ion (1+) + Carbon monosulfide = (Scandium ion (1+) bullet Carbon monosulfide)

By formula: Sc+ + CS = (Sc+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar31.8 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Zirconium ion (1+) + Carbon monosulfide = (Zirconium ion (1+) bullet Carbon monosulfide)

By formula: Zr+ + CS = (Zr+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar61.7 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000 

Silver ion (1+) + Carbon monosulfide = (Silver ion (1+) bullet Carbon monosulfide)

By formula: Ag+ + CS = (Ag+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar36.3 ± 4.8kcal/molCIDTRodgers and Armentrout, 2000 

Vanadium ion (1+) + Carbon monosulfide = (Vanadium ion (1+) bullet Carbon monosulfide)

By formula: V+ + CS = (V+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar39.2 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Yttrium ion (1+) + Carbon monosulfide = (Yttrium ion (1+) bullet Carbon monosulfide)

By formula: Y+ + CS = (Y+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar32.7 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Nickel ion (1+) + Carbon monosulfide = (Nickel ion (1+) bullet Carbon monosulfide)

By formula: Ni+ + CS = (Ni+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar56.4 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Zinc ion (1+) + Carbon monosulfide = (Zinc ion (1+) bullet Carbon monosulfide)

By formula: Zn+ + CS = (Zn+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar33.7 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Copper ion (1+) + Carbon monosulfide = (Copper ion (1+) bullet Carbon monosulfide)

By formula: Cu+ + CS = (Cu+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar55.9 ± 2.4kcal/molCIDTRodgers and Armentrout, 2000 

Niobium ion (1+) + Carbon monosulfide = (Niobium ion (1+) bullet Carbon monosulfide)

By formula: Nb+ + CS = (Nb+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar57.8 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000 

Ruthenium ion (1+) + Carbon monosulfide = (Ruthenium ion (1+) bullet Carbon monosulfide)

By formula: Ru+ + CS = (Ru+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar60.5 ± 4.8kcal/molCIDTRodgers and Armentrout, 2000 

Palladium ion (1+) + Carbon monosulfide = (Palladium ion (1+) bullet Carbon monosulfide)

By formula: Pd+ + CS = (Pd+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar47.8 ± 3.3kcal/molCIDTRodgers and Armentrout, 2000 

Rh+ + Carbon monosulfide = (Rh+ bullet Carbon monosulfide)

By formula: Rh+ + CS = (Rh+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar55.9 ± 4.5kcal/molCIDTRodgers and Armentrout, 2000 

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Schroeder, Kretzschmar, et al., 1999
Schroeder, D.; Kretzschmar, I.; Schwarz; Rue, C.; Armentrout, P.B., On the Structural Dichotomy of Cationic, Anionic, and Neutral FeS2, Inorg. Chem., 1999, 38, 15, 3474, https://doi.org/10.1021/ic990241b . [all data]

Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of Fe+ and Co+ With CS2 and COS, J. Phys. Chem. A, 2001, 105, 37, 8456, https://doi.org/10.1021/jp0120716 . [all data]

Rue, Armentrout, et al., 2001, 2
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of the State-Specific Reactions of Cr+ and Mn+ with CS2 and COS, Int. J. Mass Spectrom., 2001, 210/211, 283, https://doi.org/10.1016/S1387-3806(01)00400-6 . [all data]

Schroeder, Kretzschmar, et al., 2003
Schroeder, D.; Kretzschmar, I.; Schwarz; Armentrout, P.B., Structure, Thermochemistry, and Reactivityof MSn+ Cations (M=V,Mo; n=1-3) in the Gas Phase, Int. J. Mass Spectrom., 2003, 228, 2-3, 439, https://doi.org/10.1016/S1387-3806(03)00137-4 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References