Carbon monosulfide
- Formula: CS
- Molecular weight: 44.076
- IUPAC Standard InChI: InChI=1S/CS/c1-2
- IUPAC Standard InChIKey: DXHPZXWIPWDXHJ-UHFFFAOYSA-N
- CAS Registry Number: 2944-05-0
- Chemical structure:
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Robert C. Dunbar
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
+
= (
•
)
By formula: Fe+ + CS = (Fe+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 49.5 ± 3.1 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | |
| ΔrH° | 55.2 ± 2.8 | kcal/mol | CIDT | Schroeder, Kretzschmar, et al., 1999 |
+
= (
•
)
By formula: Co+ + CS = (Co+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 61.7 ± 7.8 | kcal/mol | CIDT | Rue, Armentrout, et al., 2001 | |
| ΔrH° | 57.4 ± 2.2 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
+
= (
•
)
By formula: Cr+ + CS = (Cr+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 38.9 ± 1.4 | kcal/mol | CIDT | Rue, Armentrout, et al., 2001, 2 | |
| ΔrH° | 37.8 ± 2.2 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
+
= (
•
)
By formula: Mn+ + CS = (Mn+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 19.1 ± 5.1 | kcal/mol | CIDT | Rue, Armentrout, et al., 2001, 2 | |
| ΔrH° | 18.6 ± 3.3 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
+
= (
•
)
By formula: Mo+ + CS = (Mo+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 38.7 ± 3.2 | kcal/mol | CIDT | Schroeder, Kretzschmar, et al., 2003 | |
| ΔrH° | 38.7 ± 4.3 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
+
= (
•
)
By formula: Ti+ + CS = (Ti+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 36.8 ± 1.4 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
+
= (
•
)
By formula: Sc+ + CS = (Sc+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 31.8 ± 1.9 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
+
= (
•
)
By formula: Zr+ + CS = (Zr+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 61.7 ± 2.6 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
+
= (
•
)
By formula: Ag+ + CS = (Ag+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 36.3 ± 4.8 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
+
= (
•
)
By formula: V+ + CS = (V+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 39.2 ± 1.9 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
+
= (
•
)
By formula: Y+ + CS = (Y+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 32.7 ± 1.9 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
+
= (
•
)
By formula: Ni+ + CS = (Ni+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 56.4 ± 2.2 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
+
= (
•
)
By formula: Zn+ + CS = (Zn+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 33.7 ± 2.2 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
+
= (
•
)
By formula: Cu+ + CS = (Cu+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 55.9 ± 2.4 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
+
= (
•
)
By formula: Nb+ + CS = (Nb+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 57.8 ± 2.6 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
+
= (
•
)
By formula: Ru+ + CS = (Ru+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 60.5 ± 4.8 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
+
= (
•
)
By formula: Pd+ + CS = (Pd+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 47.8 ± 3.3 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
By formula: Rh+ + CS = (Rh+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 55.9 ± 4.5 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B.,
Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation,
Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X
. [all data]
Schroeder, Kretzschmar, et al., 1999
Schroeder, D.; Kretzschmar, I.; Schwarz; Rue, C.; Armentrout, P.B.,
On the Structural Dichotomy of Cationic, Anionic, and Neutral FeS2,
Inorg. Chem., 1999, 38, 15, 3474, https://doi.org/10.1021/ic990241b
. [all data]
Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H.,
Guided Ion Beam Studies of the Reactions of Fe+ and Co+ With CS2 and COS,
J. Phys. Chem. A, 2001, 105, 37, 8456, https://doi.org/10.1021/jp0120716
. [all data]
Rue, Armentrout, et al., 2001, 2
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H.,
Guided Ion Beam Studies of the Reactions of the State-Specific Reactions of Cr+ and Mn+ with CS2 and COS,
Int. J. Mass Spectrom., 2001, 210/211, 283, https://doi.org/10.1016/S1387-3806(01)00400-6
. [all data]
Schroeder, Kretzschmar, et al., 2003
Schroeder, D.; Kretzschmar, I.; Schwarz; Armentrout, P.B.,
Structure, Thermochemistry, and Reactivityof MSn+ Cations (M=V,Mo; n=1-3) in the Gas Phase,
Int. J. Mass Spectrom., 2003, 228, 2-3, 439, https://doi.org/10.1016/S1387-3806(03)00137-4
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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