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Cyanomethyl radical


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 3 CH2 scissor 1432.3 Ar IR Cho and Andrews, 2011
4 C-C stretch 1026.0 Ar IR Cho and Andrews, 2011
b1 5 H2CC OPLA 663.79 gas PE DL Moran, Ellis, et al., 1987
Sumiyoshi, Tanaka, et al., 1996
5 H2CC OPLA 664.6 Ar IR Cho and Andrews, 2011

Additional references: Jacox, 1994, page 250; Jacox, 1998, page 280; Jacox, 2003, page 264; Saito, Yamamoto, et al., 1988; Saito and Yamamoto, 1997; Ozeki, Hirao, et al., 2004


References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cho and Andrews, 2011
Cho, H.-G.; Andrews, L., Matrix Infrared Spectra and Density Functional Calculations of the H, J. Phys. Chem. A, 2011, 115, 31, 8638, https://doi.org/10.1021/jp204887y . [all data]

Moran, Ellis, et al., 1987
Moran, S.; Ellis, H.B., Jr.; DeFrees, D.J.; McLean, A.D.; Ellison, G.B., Carbanion spectroscopy: CH2CN-, J. Am. Chem. Soc., 1987, 109, 5996. [all data]

Sumiyoshi, Tanaka, et al., 1996
Sumiyoshi, Y.; Tanaka, K.; Tanaka, T., Time-resolved infrared diode laser spectroscopy of the «nu»5 band of the cyanomethyl radical (H2CCN), J. Chem. Phys., 1996, 104, 5, 1839, https://doi.org/10.1063/1.471709 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Saito, Yamamoto, et al., 1988
Saito, S.; Yamamoto, S.; Irvine, W.M.; Ziurys, L.M.; Suzuki, H.; Ohishi, M.; Kaifu, N., Laboratory detection of a new interstellar free radical CH2CN(2B1), Astrophys. J., 1988, 334, L113, https://doi.org/10.1086/185324 . [all data]

Saito and Yamamoto, 1997
Saito, S.; Yamamoto, S., The microwave spectrum of the cyanomethyl radical CH[sub 2]CN([sup 2]B[sub 1]), J. Chem. Phys., 1997, 107, 6, 1732, https://doi.org/10.1063/1.475154 . [all data]

Ozeki, Hirao, et al., 2004
Ozeki, H.; Hirao, T.; Saito, S.; Yamamoto, S., Laboratory Microwave Spectroscopy of the Cyanomethyl Radical, CH, Astrophys. J., 2004, 684, 1, 680, https://doi.org/10.1086/425229 . [all data]


Notes

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