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Cyclobutanol

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MM - Michael M. Meot-Ner (Mautner)
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to C4H8O+ (ion structure unspecified)

Proton affinity at 298K

Proton affinity (kcal/mol) Reference Comment
189. ± 1.Cao and Holmes, 2001MM

Ionization energy determinations

IE (eV) Method Reference Comment
9.56 ± 0.02PIBouchoux, Alcaraz, et al., 1994LL
9.25PITraeger and McAdoo, 1986LBLHLM
9.3EIMcAdoo and Hudson, 1983LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C2H3O+9.69C2H5PITraeger and McAdoo, 1986LBLHLM
C2H4O+9.96 ± 0.03C2H4PIBouchoux, Alcaraz, et al., 1994LL
C2H4O+9.87C2H4EIHolmes, Terlouw, et al., 1976LLK

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cao and Holmes, 2001
Cao, J.; Holmes, J.L., Determination of the proton affinities of secondary alcohols from the dissocation of proton-bound molecular trios, European J. Mass Spectrom., 2001, 7, 243-247. [all data]

Bouchoux, Alcaraz, et al., 1994
Bouchoux, G.; Alcaraz, C.; Dutuit, O.; Nguyen, M.T., A photoionization and molecular orbital study of cyclobutanol and cyclobutylamine radical cations, Int. J. Mass Spectrom. Ion Processes, 1994, 137, 93. [all data]

Traeger and McAdoo, 1986
Traeger, J.C.; McAdoo, D.J., Decomposition thresholds and associated translational energy releases for eight C4H8O+ isomers, Int. J. Mass Spectrom. Ion Processes, 1986, 68, 35. [all data]

McAdoo and Hudson, 1983
McAdoo, D.J.; Hudson, C.E., The decompositions of metastable [C4H8O]+ ions and the [C4H8O]+ potential surface, Org. Mass Spectrom., 1983, 18, 466. [all data]

Holmes, Terlouw, et al., 1976
Holmes, J.L.; Terlouw, J.K.; Lossing, F.P., The thermochemistry of C2H4O+ ions, J. Phys. Chem., 1976, 80, 2860. [all data]


Notes

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