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1H-Cyclopropa[b]naphthalene


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

C11H7- + Hydrogen cation = 1H-Cyclopropa[b]naphthalene

By formula: C11H7- + H+ = C11H8

Quantity Value Units Method Reference Comment
Deltar1527. ± 9.2kJ/molG+TSAntol, Glasovac, et al., 2003gas phase; B
Quantity Value Units Method Reference Comment
Deltar1496. ± 8.8kJ/molIMREAntol, Glasovac, et al., 2003gas phase; B

1H-Cyclopropa[b]naphthalene + Methyl Alcohol = Naphthalene, 2-(methoxymethyl)-

By formula: C11H8 + CH4O = C12H12O

Quantity Value Units Method Reference Comment
Deltar-198.4 ± 0.50kJ/molCmBillups, Chow, et al., 1973liquid phase; solvent: Methanol; ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Antol, Glasovac, et al., 2003
Antol, I.; Glasovac, Z.; Hare, M.C.; Eckert-Maksic, M.; Kass, S.R., On the acidity of cyclopropanaphthalenes - Gas phase and computational studies, Int. J. Mass Spectrom., 2003, 222, 1-3, 11-26, https://doi.org/10.1016/S1387-3806(02)00953-3 . [all data]

Billups, Chow, et al., 1973
Billups, W.E.; Chow, W.Y.; Leavell, K.H.; Lewis, E.S.; Margrave, J.L.; Sass, R.L.; Shieh, J.J.; Werness, P.G.; Wood, J.L., Structure and thermochemistry of benzocyclopropenes. Bond fixation and strain energy, J. Am. Chem. Soc., 1973, 95, 7878-7880. [all data]


Notes

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