Bicyclo[3.1.0]hex-2-ene, 2-methyl-5-(1-methylethyl)-

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Normal alkane RI, polar column, temperature ramp

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-WaxHP-InnowaxDB-WaxSupelcowax-10DB-Wax
Column length (m) 60.30.30.30.30.
Carrier gas HeliumHeliumHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.220.250.250.200.25
Phase thickness (μm) 0.250.250.250.200.25
Tstart (C) 60.50.40.70.80.
Tend (C) 230.250.230.220.240.
Heat rate (K/min) 2.5.4.3.3.
Initial hold (min)  5.2.  
Final hold (min) 5.10.4.515.2.
I 1011.1035.1023.1030.1029.
ReferenceBendiabdellah, El Amine Dib, et al., 2012Menichini, Tundis, et al., 2011Zeng, Xie, et al., 2011Neves, Rosa, et al., 2010Vahirua-Lechat, Mitermite, et al., 2010
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-WaxHP-InnowaxHP-InnowaxCP-Wax 52CBCarbowax
Column length (m) 60.30.30.60.60.
Carrier gas HeliumNitrogenN2HeHe
Substrate      
Column diameter (mm) 0.220.250.250.250.2
Phase thickness (μm) 0.250.520.250.250.25
Tstart (C) 60.35.50.40.60.
Tend (C) 230.205.240.220.250.
Heat rate (K/min) 2.3.5.3.2.
Initial hold (min)  10.1. 8.
Final hold (min) 30.10.4. 15.
I 1008.1035.1020.1038.1036.
ReferenceMuseli, Pau, et al., 2009Wannes, Mhamdi, et al., 2009Cheraif, Ben Jannet, et al., 2007Chyau, Tsai, et al., 2007Ferhat, Meklati, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP-Wax 52CBSupelcowax-10CP-Wax 52CBSupelcowax-10Carbowax
Column length (m) 30.30.60.30.60.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.20.320.250.25
Phase thickness (μm) 0.250.20.50.250.25
Tstart (C) 40.70.40.50.40.
Tend (C) 220.220.220.250.180.
Heat rate (K/min) 3.3.4.2.5.
Initial hold (min) 1. 8.  
Final hold (min) 2.15.20.  
I 1029.1030.1033.1026.1039.
ReferenceHymete, Rohloff, et al., 2007Pinto, Salgueiro, et al., 2007Povolo, Contarini, et al., 2007Raal, Orav, et al., 2007Singh, Kumar, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10Supelcowax-10InnowaxInnowaxAT-Wax
Column length (m) 30.30.30.30.60.
Carrier gas  HeN2N2He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.40.50.50.60.
Tend (C) 250.250.280.280.200.
Heat rate (K/min) 2.3.9.9.4.
Initial hold (min)  5.3.3. 
Final hold (min) 33.10.3.3.20.
I 1031.1022.1033.1035.1040.
ReferenceSylvestre, Pichette, et al., 2007Vichi, Riu-Aumatell, et al., 2007Abdelwahed, Hayder, et al., 2006Abdelwahed, Hayder, et al., 2006Borges, Rojas, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20Supelcowax 10BP-20CP-Wax 52CBFFAP
Column length (m) 50.30.50.30.20.
Carrier gas  HeliumHeHeHe
Substrate      
Column diameter (mm) 0.220.200.220.320.25
Phase thickness (μm) 0.250.200.250.250.25
Tstart (C) 60.70.60.60.90.
Tend (C) 220.220.220.220.250.
Heat rate (K/min) 2.3.2.3.36.
Initial hold (min)    7. 
Final hold (min) 20.15.20.3. 
I 1026.1030.1022.1028.1052.
ReferenceBoti, Yao, et al., 2006Cavaleiro, Pinto, et al., 2006Fanciullino, Tomi, et al., 2006Hymete, Rohloff, et al., 2006Kitchlu, Bakshi, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SupelcowaxNB-20MSupelcowax-10Supelcowax-10Innowax
Column length (m) 30.30.30.30.50.
Carrier gas N2HeHeHeHe
Substrate      
Column diameter (mm) 0.320.20.250.250.2
Phase thickness (μm) 0.250.250.250.250.5
Tstart (C) 50.50.50.50.60.
Tend (C) 200.250.220.250.250.
Heat rate (K/min) 5.2.4.4.2.
Initial hold (min)   1.1. 
Final hold (min)   10.10.60.
I 1035.1017.1030.1016.1020.
ReferenceMartin, Joseph, et al., 2006Orav, Raal, et al., 2006Wong, Lim, et al., 2006Wong, Sivasothy, et al., 2006Bendimerad and Bendiab, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-20MCarbowax 20MStabilwaxHP-20MHP-20M
Column length (m) 50.50.30.50.50.
Carrier gas Helium H2HeliumHelium
Substrate      
Column diameter (mm) 0.200.20.320.200.20
Phase thickness (μm) 0.200.250.50.200.20
Tstart (C) 70.60.40.70.70.
Tend (C) 250.250.280.180.180.
Heat rate (K/min) 4.2.6.4.4.
Initial hold (min) 4.60.5.4.4.
Final hold (min) 10. 5.10.10.
I 1031.1039.1022.1031.1031.
ReferenceBezic, Skocibusic, et al., 2005Fernandez, Lizzani-Cuvelier, et al., 2005Jirovetz, Buchbauer, et al., 2005Kulisic, Radonic, et al., 2005Kulisic, Radonic, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxCP-Wax 52CBDB-WaxSupelcowax-10Supelcowax-10
Column length (m) 60.30.30.30.30.
Carrier gas N2HeHe  
Substrate      
Column diameter (mm) 0.250.320.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 70.40.40.40.40.
Tend (C) 230.220.250.210.220.
Heat rate (K/min) 2.4.4.2.3.
Initial hold (min) 2.1. 2.5.
Final hold (min) 20. 10.33.10.
I 1014.1028.1018.1017.1022.
ReferenceNjoroge, Koaze, et al., 2005Rohloff and Bones, 2005Salehi, Sonboli, et al., 2005Stevanovic, Garneau, et al., 2005Vichi, Riu-Aumatell, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxSupelcowax-10Supelcowax-10Supelcowax-10NB-20M
Column length (m) 30.30.50.50.50.
Carrier gas He HeHeHe
Substrate      
Column diameter (mm) 0.250.250.20.20.2
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 90.40.70.70.50.
Tend (C) 220.210.230.230.250.
Heat rate (K/min) 7.2.2.2.2.
Initial hold (min) 2.2.   
Final hold (min) 5.33.   
I 1052.1031.1028.1029.1021.
ReferenceAgnihotri, Thappa, et al., 2004Lopez Arze, Collin, et al., 2004Orav, Stulova, et al., 2004Orav, Stulova, et al., 2004Raal, Arak, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-WaxHP-20MSupelcowax-10HP-InnowaxInnowax
Column length (m) 30.50.50.50.60.
Carrier gas N2HeHe He
Substrate      
Column diameter (mm) 0.250.20.20.20.25
Phase thickness (μm) 0.250.20.250.2 
Tstart (C) 60.70.70.50.60.
Tend (C) 220.180.230.220.220.
Heat rate (K/min) 5.4.2.4.4.
Initial hold (min) 10.4. 5.10.
Final hold (min)  10.  10.
I 1038.1035.1029.1035.1035.
ReferenceBertoli, Menichini, et al., 2003Juteau, Jerkovic, et al., 2003Orav, Kailas, et al., 2003Stashenko, Jaramillo, et al., 2003Suleimenov, Atazharova, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxCarbowax 20MDB-WaxSupelcowax-10EC-1000
Column length (m) 50.25.60.60.30.
Carrier gas HeN2H2HeHe
Substrate      
Column diameter (mm) 0.20.250.320.20.25
Phase thickness (μm) 0.20.250.250.50.25
Tstart (C) 70.50.40.70.35.
Tend (C) 190.250.245.220.230.
Heat rate (K/min) 5.4.1.52.5.
Initial hold (min)     5.
Final hold (min)  10.20. 15.
I 1038.1030.1021.1029.1045.
ReferenceVelasco-Negueruela, Pérez-Alonso, et al., 2003Zrira, Elamrani, et al., 2003Gancel, Ollé, et al., 2002Orav, Kailas, et al., 2002Bendall, 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxBP-20PEG-20MDB-WaxBP-20
Column length (m) 60.50.50.60.25.
Carrier gas HeHeHe Nitrogen
Substrate      
Column diameter (mm) 0.250.220.20.250.50
Phase thickness (μm) 0.250.25 0.250.25
Tstart (C) 45.60.70.30.60.
Tend (C) 240.230.220.170.200.
Heat rate (K/min) 3.2.2.2.5.
Initial hold (min)    4. 
Final hold (min)  35. 30. 
I 1025.1021.1029.1022.1017.
ReferenceChristoph, 2001Lota, de Rocca Serra, et al., 2001Orav and Kann, 2001Buttery, Light, et al., 2000Mallavarapu, Rao, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-20MDB-WaxInnowaxNB-351BP-20
Column length (m) 50.60.60.25.25.
Carrier gas HeHeHeH2N2
Substrate      
Column diameter (mm) 0.200.250.250.30.5
Phase thickness (μm) 0.200.250.250.5 
Tstart (C) 70.40.60.70.60.
Tend (C) 180.200.220.250.200.
Heat rate (K/min) 4.2. 5.5.
Initial hold (min) 4.2.10.2. 
Final hold (min)      
I 1034.1024.1035.1019.1019.
ReferenceMastelic, Milos, et al., 2000Umano, Hagi, et al., 2000Kaya, Baser, et al., 1999Onocha, Ekundayo, et al., 1999Rao, Bhattacharya, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxHP-InnowaxSupelcowax-10SP-1000
Column length (m) 60.30.60.30.85.
Carrier gas N2N2He He
Substrate      
Column diameter (mm)  0.250.250.250.50
Phase thickness (μm) 0.250.250.25  
Tstart (C) 60.45.50.60.65.
Tend (C) 220.220.220.240.225.
Heat rate (K/min) 5.3.5.4.3.
Initial hold (min)   5.  
Final hold (min)      
I 1033.1021.1020.1033.1025.
ReferenceWeyerstahl, Marschall, et al., 1999Mölleken, Sinnwell, et al., 1998Stashenko, Cervantes, et al., 1998Zunino, Novillo-Newton, et al., 1997Brophy, Goldsack, et al., 1996
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxSupelcowax-10Carbowax 20MCarbowax 20MFFAP
Column length (m) 60.60.60.45.50.
Carrier gas HeHeHeHydrogen 
Substrate      
Column diameter (mm) 0.250.250.250.32 
Phase thickness (μm) 0.250.250.251.0 
Tstart (C) 50.40.50.60.50.
Tend (C) 180.200.150.200.180.
Heat rate (K/min) 2.53.2.2.10.
Initial hold (min) 5.3.10.5.1.
Final hold (min)  30.20.  
I 1022.1033.1025.1037.1039.
ReferenceStashenko, Puertas, et al., 1996Wong and Lai, 1996Tirado, Stashenko, et al., 1995Kollmannsberger, Nitz, et al., 1992Brophy, Davies, et al., 1989
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bendiabdellah, El Amine Dib, et al., 2012
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Museli, A.; Pau, M.; Desjobert, J.-M.; Foddai, M.; Usai, M.; Costa, J., Volatile constituents of Achllea ligustica All. by HS-SPME/GC/GC-MS. Comparison with essential oils obtained by hydrodistillation from Corsica and Sardinia, Chromatographia, 2009, 69, 5/6, 575-585, https://doi.org/10.1365/s10337-008-0939-1 . [all data]

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Cheraif, Ben Jannet, et al., 2007
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Chyau, C.-C.; Tsai, S.-Y.; Yang, J.-H.; Weng, C.-C.; Han, C.-M.; Shih, C.-C.; Mau, J.-L., The essential oil of Glossogyne tenuifolia, Food Chem., 2007, 100, 2, 808-812, https://doi.org/10.1016/j.foodchem.2005.10.044 . [all data]

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Raal, Orav, et al., 2007
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Kitchlu, Bakshi, et al., 2006
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Martin, Joseph, et al., 2006
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Orav, Raal, et al., 2006
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Wong, Lim, et al., 2006
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Wong, Sivasothy, et al., 2006
Wong, K.C.; Sivasothy, Y.; Boey, P.L., Essential oil of Elettariopsis elan C.K. Lim, Flavour Fragr. J., 2006, 21, 3, 562-564, https://doi.org/10.1002/ffj.1654 . [all data]

Bendimerad and Bendiab, 2005
Bendimerad, N.; Bendiab, S.A.T., Composition and antibacterial activity of Pseudocytisus integrifolius (Salisb.) essential oil from Algeria, J. Agric. Food Chem., 2005, 53, 8, 2947-2952, https://doi.org/10.1021/jf047937u . [all data]

Bezic, Skocibusic, et al., 2005
Bezic, N.; Skocibusic, M.; Dunkic, V., Phytochemical Composition and Antimicrobial Activityof Satureja montana L. and Satureja cunefolia Ten. Essential Oils, Acta Bot. Croat., 2005, 64, 2, 313-322. [all data]

Fernandez, Lizzani-Cuvelier, et al., 2005
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Notes

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