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7-Oxabicyclo[4.1.0]heptane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-30.00 ± 0.26kcal/molCcbKozina, Timofeeva, et al., 1988See Timofeeva, Lukyanova, et al., 1984
Deltafgas-29.21 ± 0.53kcal/molCcbAndruzzi, Li, et al., 1987 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-39.67 ± 0.26kcal/molCcbKozina, Timofeeva, et al., 1988See Timofeeva, Lukyanova, et al., 1984; ALS
Deltafliquid-39.51 ± 0.24kcal/molCcbAndruzzi, Li, et al., 1987ALS
Quantity Value Units Method Reference Comment
Deltacliquid-866.20 ± 0.24kcal/molCcbKozina, Timofeeva, et al., 1988See Timofeeva, Lukyanova, et al., 1984; Corresponding «DELTA»fliquid = -39.67 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-866.4 ± 0.1kcal/molCcbAndruzzi, Li, et al., 1987Corresponding «DELTA»fliquid = -39.51 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid53.054cal/mol*KN/ANakamura, Suga, et al., 1980DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
39.704300.Nakamura, Suga, et al., 1980T = 13 to 300 K. Unsmoothed experimental datum for Cp at 296.96 K is 164.98 J/mol*K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kozina, Timofeeva, et al., 1988
Kozina, M.P.; Timofeeva, L.P.; Luk'Yanova, V.A.; Pimenova, S.M.; Kas'yan, L.I., Enthalpies of formation and some alicyclic epoxy compounds, Russ. J. Phys. Chem. (Engl. Transl.), 1988, 62, 609-612. [all data]

Timofeeva, Lukyanova, et al., 1984
Timofeeva, L.P.; Lukyanova, V.A.; Kozina, M.P.; Stepanova, N.V., Enthalpies of combustion and formation of some epoxides of cyclic alkenes, Probl. Kalorim. Khim. Termodin., Dokl. Vses. Konf., 10th, 1984, 1, 193-195. [all data]

Andruzzi, Li, et al., 1987
Andruzzi, F.; Li, S.; Pilcher, G.; Heatley, F., Enthalpy of polymerisation of 7-oxabicyclo[4.1.0]heptane, Makromol. Chem., 1987, 188, 2643-2650. [all data]

Nakamura, Suga, et al., 1980
Nakamura, N.; Suga, H.; Seki, S., Calorimetric study on orientationally disordered crystals. Cyclohexene oxide and cyclohexanone, Bull. Chem. Soc. Japan, 1980, 53(10), 2755-2761. [all data]


Notes

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