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Bromotrimethylsilane


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
10.0PEFlamini, Semprini, et al., 1976LLK
9.8 ± 0.1EIBand, Davidson, et al., 1968RDSH
10.24 ± 0.02EIHess, Lampe, et al., 1965RDSH
10.23PEFlamini, Semprini, et al., 1976Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C2H6BrSi+10.79 ± 0.01CH3PIPECOSzepes and Baer, 1984T = 0K; LBLHLM
C2H6BrSi+10.60 ± 0.01CH3PIPECOSzepes and Baer, 1984T = 298K; LBLHLM
C2H6BrSi+10.79 ± 0.01CH3PIPECOSzepes and Baer, 1984, 2T = 0K; LBLHLM
C2H6SiBr+10.7 ± 0.1CH3EIBand, Davidson, et al., 1968RDSH
C2H6SiBr+10.97 ± 0.02CH3EIHess, Lampe, et al., 1965RDSH
C3H9Si+10.51 ± 0.01BrPIPECOSzepes and Baer, 1984T = 298K; LBLHLM
C3H9Si+10.70 ± 0.01BrPIPECOSzepes and Baer, 1984T = 0K; LBLHLM
C3H9Si+10.70 ± 0.01BrPIPECOSzepes and Baer, 1984, 2LBLHLM
C3H9Si+10.5 ± 0.1BrEIBand, Davidson, et al., Commun. 1967RDSH
C3H9Si+10.69 ± 0.06BrEIHess, Lampe, et al., 1965RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Flamini, Semprini, et al., 1976
Flamini, A.; Semprini, E.; Stefani, F.; Sorriso, S.; Cardaci, G., He(I) photoelectron spectra and semiempirical molecular-orbital calculations on methylmetal halides of group 4A elements, J. Chem. Soc. Dalton Trans., 1976, 731. [all data]

Band, Davidson, et al., 1968
Band, S.J.; Davidson, I.M.T.; Lambert, C.A., Bond dissociation energies: electron impact studies on some trimethylsilyl compounds, J. Chem. Soc. A, 1968, 2068. [all data]

Hess, Lampe, et al., 1965
Hess, G.G.; Lampe, F.W.; Sommer, L.H., An electron impact study of ionization and dissociation of trimethylsilanes, J. Am. Chem. Soc., 1965, 87, 5327. [all data]

Szepes and Baer, 1984
Szepes, L.; Baer, T., Dissociation dynamics of energy selected hexamethyldisilane ions and the heats of formation of (CH3)3Si+ and (CH3)3Si, J. Am. Chem. Soc., 1984, 106, 273. [all data]

Szepes and Baer, 1984, 2
Szepes, L.; Baer, T., (CH3)3SiX tipusu vegyuletek vizsgalata fotoelectron-fotoion koincidenciaval,I. Meghatarozott belso energiaju hexametil-diszilan-ionok disszociaciojanak dinamikaja, Magy. Kem. Foly., 1984, 90, 104. [all data]

Band, Davidson, et al., Commun. 1967
Band, S.J.; Davidson, I.M.T.; Lambert, C.A.; Stephenson, I.L., Bond dissociation energies and heats of formation of trimethylsilyl compounds, Chem., Commun. 1967, 723. [all data]


Notes

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