Digermane, hexaphenyl-


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas656. ± 12.kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid446. ± 12.kJ/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Δcsolid-20010. ± 11.kJ/molCC-RBCarson, Carson, et al., 1970Please also see Pedley and Rylance, 1977.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub209.2 ± 4.2kJ/molN/APilcher and Skinner, 1983See also Carson, Carson, et al., 1970.; AC
Δsub209.2 ± 4.2kJ/molCC-RBKana'an, 1974MS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Carson, Carson, et al., 1970
Carson, A.S.; Carson, E.M.; Laye, P.G.; Spencer, J.A.; Steele, W.V., Enthalpy of combustion of organo-metallic compounds measured with a vacuum-jacketed, rotating, aneroid calorimeter. The enthalpies of formation of germanium tetrabenzyl and di-germanium hexaphenyl, Trans. Faraday Soc., 1970, 66, 2459, https://doi.org/10.1039/tf9706602459 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Kana'an, 1974
Kana'an, A.S., J. Chem. Thermodyn., 1974, 6, 191. [all data]


Notes

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