Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Butane, 1-isocyano-


Gas phase ion energetics data

Go To: Top, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C5H9N+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
11.71 ± 0.05EIDistefano, Innorta, et al., 1968RDSH
11.1PEYoung and Cheng, 1976Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C2H3N+12.75?EIHeerma and deRidder, 1970RDSH
C3H4N+12.80?EIHeerma and deRidder, 1970RDSH
C3H5+13.35?EIHeerma and deRidder, 1970RDSH
C3H5N+11.80?EIHeerma and deRidder, 1970RDSH
C3H7+12.80?EIHeerma and deRidder, 1970RDSH
C4H7+13.00?EIHeerma and deRidder, 1970RDSH
C4H8+12.00?PERowland, 1971Unpublished result of J.H.D. Eland; LLK

Mass spectrum (electron ionization)

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

Mass spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

View spectrum image in SVG format.

Download spectrum in JCAMP-DX format.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin W HEERMA
NIST MS number 36736

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Distefano, Innorta, et al., 1968
Distefano, G.; Innorta, G.; Pignataro, S.; Foffani, A., Correlation between the ionization potentials of transition metal complexes and of the corresponding ligands, J. Organometal. Chem., 1968, 14, 165. [all data]

Young and Cheng, 1976
Young, V.Y.; Cheng, K.L., The ultraviolet photoelectron spectra of aliphatic aromatic isonitriles, J. Electron Spectrosc. Relat. Phenom., 1976, 9, 317. [all data]

Heerma and deRidder, 1970
Heerma, W.; deRidder, J.J., The electron-impact induced fragmentation of some alkyl isocyanides and alpha-branched alkyl cyanides, Org. Mass Spectrom., 1970, 3, 1439. [all data]

Rowland, 1971
Rowland, C.G., Kinetic energy distributions of C12H8 fragment ions in the mass spectra of anthracene, phenanthrene and diphenylacetylene, Intern. J. Mass Spectrom. Ion Phys., 1971, 7, 79. [all data]


Notes

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References