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[2.2.2](1,3,5)Cyclophane


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
8.20 ± 0.05PEKovac, Mohraz, et al., 1980Vertical value; LLK
7.88PEClar and Schmidt, 1976Vertical value; LLK
7.70 ± 0.02PEBoschi and Schmidt, 1973Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kovac, Mohraz, et al., 1980
Kovac, B.; Mohraz, M.; Heilbronner, E.; Boekelheide, V.; Hopf, H., Photoelectron spectra of the cyclophanes, J. Am. Chem. Soc., 1980, 102, 4314. [all data]

Clar and Schmidt, 1976
Clar, E.; Schmidt, W., Correlations between photoelectron and phosphorescence spectra of polycyclic hydrocarbons, Tetrahedron, 1976, 32, 2563. [all data]

Boschi and Schmidt, 1973
Boschi, R.; Schmidt, W., Transannular «pi» - «pi» interaction in cyclophanes, Angew. Chem. Int. Ed. Engl., 1973, 12, 402. [all data]


Notes

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