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Cyclotetramethylenetetranitramine

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid75.kJ/molCcbOrnellas, 1974E.J. Prosen unpublished result; ALS
Deltafsolid103. ± 2.8kJ/molCcbKrien, Licht, et al., 1973Author's hf298_condensed=21. kcal/mol; ALS
Deltafsolid74.9kJ/molCcbHandrick, 1956Naval Ordnance Laboratory, 1951; ALS
Quantity Value Units Method Reference Comment
Deltacsolid-2820. ± 2.8kJ/molCcbKrien, Licht, et al., 1973Author's hf298_condensed=21. kcal/mol; ALS
Deltacsolid-2792.kJ/molCcbHandrick, 1956Naval Ordnance Laboratory, 1951; ALS
Deltacsolid-2774.kJ/molCcbHandrick, 1956Stegeman, G. Univ. of Pittsburg 1945; ALS
Deltacsolid-2748.kJ/molCcbHandrick, 1956W. R. Tomlinson 1949; ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
290.2298.Yin, Ziru, et al., 1991T = 290 to 345 K. Cp value reported at 298 K is 0.980 J/kg*K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ornellas, 1974
Ornellas, D.L., The heat and products of detonation in a calorimeter of CNO, HNO, CHNF, CHNO, CHNOF, and CHNOSi explosives, Combust. Flame, 1974, 23, 37-46. [all data]

Krien, Licht, et al., 1973
Krien, G.; Licht, H.H.; Zierath, J., Thermochemical investigation of nitramines, Thermochim. Acta, 1973, 6, 465-472. [all data]

Handrick, 1956
Handrick, G.R., Report of the study of pure explosive compounds. Part IV. Calculation of heat of combustion of organic compounds from structural features and calculation of power of high explosives, Rpt. C-58247 for the Office of the Chief of Ordnance, contract DA-19-020-ORD-47 by the Arthur D. Little, Inc., Cambridge, MA, 1956, 467-573. [all data]

Yin, Ziru, et al., 1991
Yin, C.; Ziru, L.; Ganghe, W.; Chengyun, W., et al., Determination of heat capacity of explosives and related materials by DSC, Proc. Int. Pyrotech. Semin. 17th(Vol. 1), 1991, 515-521. [all data]


Notes

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