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CH3CONHCH(CH3)COOCH3


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(MeCO2 anion bullet CH3CONHCH(CH3)COOCH3) + Water = (MeCO2 anion bullet Water bullet CH3CONHCH(CH3)COOCH3)

By formula: (C2H3O2- bullet C6H11NO3) + H2O = (C2H3O2- bullet H2O bullet C6H11NO3)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar55.2kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

CH3CONHCH(CH3)COOCH3 + Methyl Alcohol = (CH3CONHCH(CH3)COOCH3 bullet Methyl Alcohol)

By formula: C6H11NO3 + CH4O = (C6H11NO3 bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar75.kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
28.392.PHPMSMeot-Ner (Mautner), 1988gas phase; M

HS- + CH3CONHCH(CH3)COOCH3 = (HS- bullet CH3CONHCH(CH3)COOCH3)

By formula: HS- + C6H11NO3 = (HS- bullet C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar115. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar80.3 ± 8.4kJ/molTDAsMeot-ner, 1988gas phase; B

Chlorine anion + CH3CONHCH(CH3)COOCH3 = (Chlorine anion bullet CH3CONHCH(CH3)COOCH3)

By formula: Cl- + C6H11NO3 = (Cl- bullet C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar123. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar87.4 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

MeCO2 anion + CH3CONHCH(CH3)COOCH3 = (MeCO2 anion bullet CH3CONHCH(CH3)COOCH3)

By formula: C2H3O2- + C6H11NO3 = (C2H3O2- bullet C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar131. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar86.6 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

CN- + CH3CONHCH(CH3)COOCH3 = (CN- bullet CH3CONHCH(CH3)COOCH3)

By formula: CN- + C6H11NO3 = (CN- bullet C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar110. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar74.5 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

(CH3CONHCH(CH3)COOCH3 bullet Water) + Water = (CH3CONHCH(CH3)COOCH3 bullet 2Water)

By formula: (C6H11NO3 bullet H2O) + H2O = (C6H11NO3 bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar54.4kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar82.8J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

CH3CONHCH(CH3)COOCH3 + L-Alanine, N-acetyl-, methyl ester = (CH3CONHCH(CH3)COOCH3 bullet L-Alanine, N-acetyl-, methyl ester)

By formula: C6H11NO3 + C6H11NO3 = (C6H11NO3 bullet C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar118.kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar169.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

CH3CONHCH(CH3)COOCH3 + Water = (CH3CONHCH(CH3)COOCH3 bullet Water)

By formula: C6H11NO3 + H2O = (C6H11NO3 bullet H2O)

Quantity Value Units Method Reference Comment
Deltar63.6kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar87.4J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

CH3CONHCH(CH3)COOCH3 + Pyrrole = (CH3CONHCH(CH3)COOCH3 bullet Pyrrole)

By formula: C6H11NO3 + C4H5N = (C6H11NO3 bullet C4H5N)

Quantity Value Units Method Reference Comment
Deltar100.kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar134.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated by: Edward P. Hunter and Sharon G. Lias

Quantity Value Units Method Reference Comment
Proton affinity (review)938.6kJ/molN/AHunter and Lias, 1998 
Quantity Value Units Method Reference Comment
Gas basicity888.0kJ/molN/AHunter and Lias, 1998 

Ion clustering data

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CN- + CH3CONHCH(CH3)COOCH3 = (CN- bullet CH3CONHCH(CH3)COOCH3)

By formula: CN- + C6H11NO3 = (CN- bullet C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar110. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar74.5 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase

MeCO2 anion + CH3CONHCH(CH3)COOCH3 = (MeCO2 anion bullet CH3CONHCH(CH3)COOCH3)

By formula: C2H3O2- + C6H11NO3 = (C2H3O2- bullet C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar131. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar86.6 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase

Chlorine anion + CH3CONHCH(CH3)COOCH3 = (Chlorine anion bullet CH3CONHCH(CH3)COOCH3)

By formula: Cl- + C6H11NO3 = (Cl- bullet C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar123. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar87.4 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase

HS- + CH3CONHCH(CH3)COOCH3 = (HS- bullet CH3CONHCH(CH3)COOCH3)

By formula: HS- + C6H11NO3 = (HS- bullet C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar115. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar80.3 ± 8.4kJ/molTDAsMeot-ner, 1988gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner), 1988
Meot-Ner (Mautner), M., Models for Strong Interactions in Proteins and Enzymes. 2. Interactions of Ions with the Peptide Link and Imidazole, J. Am. Chem. Soc., 1988, 110, 10, 3075, https://doi.org/10.1021/ja00218a014 . [all data]

Meot-ner, 1988
Meot-ner, M., Ionic Hydrogen Bond and Ion Solvation. 6. Interaction Energies of the Acetate Ion with Organic Molecules. Comparison of CH3COO- with Cl-, CN-, and SH-, J. Am. Chem. Soc., 1988, 110, 12, 3854, https://doi.org/10.1021/ja00220a022 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References