Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Tungsten, pentacarbonyl(trimethylphosphine)-


Phase change data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltasub93.8 ± 1.5kJ/molN/ABoxhoorn, Ernsting, et al., 1980MS

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
93.8 ± 1.5305.MEBoxhoorn, Ernsting, et al., 1980, 2Based on data from 283. - 327. K.; AC
162.2 ± 8.3352.MEBoxhoorn, Ernsting, et al., 1980, 2Based on data from 340. - 364. K.; AC

Gas phase ion energetics data

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference
7.9PEYarbrough and Hall, 1978

References

Go To: Top, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Boxhoorn, Ernsting, et al., 1980
Boxhoorn, G.; Ernsting, J.M.; Stufkens, D.J.; Oskam, A., Thermochim. Acta, 1980, 42, 315. [all data]

Boxhoorn, Ernsting, et al., 1980, 2
Boxhoorn, G.; Ernsting, J.M.; Stufkens, D.J.; Oskam, A., Vapour pressure measurements on M(CO)5L complexes (M «58875» Cr, W; L «58875» CO, P(OØ)3, PØ3, PMe3, NMe3 and pyridazine), Thermochimica Acta, 1980, 42, 3, 315-321, https://doi.org/10.1016/0040-6031(80)85092-1 . [all data]

Yarbrough and Hall, 1978
Yarbrough, L.W., II; Hall, M.B., Photoelectron spectra of substituted chromium, molybdenum, and tungsten pentacarbonyls. Relative «pi»-acceptor and «sigma»-donor properties of various phosphorus ligands, Inorg. Chem., 1978, 17, 2269. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, References