Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

HO2NO2


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Td = 30300 T gas 190U 330 Graham, Winer, et al., 1978
Cox and Patrick, 1979
Morel, Simonaitis, et al., 1980
Molina and Molina, 1981
Singer, Crowley, et al., 1989
May and Friedl, 1993
Knight, Ravishankara, et al., 2002

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 OH stretch 3540.1 w m gas IR Niki, Maker, et al., 1977
Graham, Winer, et al., 1978
May and Friedl, 1993
2 NO2 a-stretch 1728.3 vs gas IR Niki, Maker, et al., 1977
Graham, Winer, et al., 1977
Molina and Molina, 1981
May and Friedl, 1993
2 NO2 a-stretch 1726.2 vs Ar IR Koch and Sodeau, 1995
3 OH bend 1396.9 w m gas IR Niki, Maker, et al., 1977
Graham, Winer, et al., 1977
Graham, Winer, et al., 1978
Molina and Molina, 1981
May and Friedl, 1993
Hojer, May, et al., 1996
4 NO2 s-stretch 1304.2 s gas IR Niki, Maker, et al., 1977
Levine, Uselman, et al., 1977
Graham, Winer, et al., 1977
Graham, Winer, et al., 1978
Molina and Molina, 1981
May and Friedl, 1993
4 NO2 s-stretch 1292.7 m Ar IR Koch and Sodeau, 1995
5 O-O stretch 941.0 w gas IR Niki, Maker, et al., 1977
Graham, Winer, et al., 1977
May and Peterson, 1991
922.1 w gas IR Niki, Maker, et al., 1977
Graham, Winer, et al., 1977
919.2 w gas IR Niki, Maker, et al., 1977
Graham, Winer, et al., 1977
May and Peterson, 1991
a' 6 NO2 scissors 802.54 m gas IR DL Niki, Maker, et al., 1977
Levine, Uselman, et al., 1977
Graham, Winer, et al., 1977
Graham, Winer, et al., 1978
Molina and Molina, 1981
May, Molina, et al., 1988
May and Friedl, 1993
Friedl, May, et al., 1994
7 N-O stretch 648 gas IR Friedl, May, et al., 1994
8 NO2 rock 466 gas IR Friedl, May, et al., 1994
a 10 NO2 wag 722 gas IR May and Peterson, 1991
Friedl, May, et al., 1994
12 NO2 torsion 145 ± 6 gas MW Suenram, Lovas, et al., 1986

Additional references: Jacox, 1994, page 341; Jacox, 1998, page 317; Jacox, 2003, page 324

Notes

wWeak
mMedium
sStrong
vsVery strong
TTentative assignment or approximate value
dPhotodissociation threshold

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Graham, Winer, et al., 1978
Graham, R.A.; Winer, A.M.; Pitts, J.N., Jr., Ultraviolet and infrared absorption cross sections of gas phase HO, Geophys. Res. Lett., 1978, 5, 11, 909, https://doi.org/10.1029/GL005i011p00909 . [all data]

Cox and Patrick, 1979
Cox, R.A.; Patrick, K., Kinetics of the reaction HO2 + NO2(+M) = HO2NO2 using molecular modulation spectrometry, Int. J. Chem. Kinet., 1979, 11, 6, 635, https://doi.org/10.1002/kin.550110610 . [all data]

Morel, Simonaitis, et al., 1980
Morel, O.; Simonaitis, R.; Heicklen, J., Ultraviolet absorption spectra of HO2NO2, CCl3O2NO2, CCl2FO2NO2, and CH3O2NO2, Chem. Phys. Lett., 1980, 73, 1, 38, https://doi.org/10.1016/0009-2614(80)85197-9 . [all data]

Molina and Molina, 1981
Molina, L.T.; Molina, M.J., UV absorption cross sections of HO2NO2 vapor, J. Photochem., 1981, 15, 2, 97, https://doi.org/10.1016/0047-2670(81)85002-2 . [all data]

Singer, Crowley, et al., 1989
Singer, R.J.; Crowley, J.N.; Burrows, J.P.; Schneider, W.; Moortgat, G.K., Measurement of the absorption cross-section of peroxynitric acid between 210 and 330 nm in the range 253 -- 298 K, J. Photochem. Photobiol. A: Chem., 1989, 48, 1, 17, https://doi.org/10.1016/1010-6030(89)87086-8 . [all data]

May and Friedl, 1993
May, R.D.; Friedl, R.R., Integrated band intensities of HO2NO2 at 220 K, J. Quant. Spectrosc. Radiat. Transfer, 1993, 50, 3, 257, https://doi.org/10.1016/0022-4073(93)90076-T . [all data]

Knight, Ravishankara, et al., 2002
Knight, G.; Ravishankara, A.R.; Burkholder, J.B., UV absorption cross sections of HO2NO2 between 343 and 273 K, Phys. Chem. Chem. Phys., 2002, 4, 8, 1432, https://doi.org/10.1039/b108904h . [all data]

Niki, Maker, et al., 1977
Niki, H.; Maker, P.D.; Savage, C.M.; Breitenbach, L.P., Fourier transform IR spectroscopic observation of pernitric acid formed via HOO + NO2 --> HOONO2, Chem. Phys. Lett., 1977, 45, 3, 564, https://doi.org/10.1016/0009-2614(77)80090-0 . [all data]

Graham, Winer, et al., 1977
Graham, R.A.; Winer, A.M.; Pitts, J.N., Jr., Temperature dependence of the unimolecular decomposition of pernitric acid and its atmospheric implications, Chem. Phys. Lett., 1977, 51, 2, 215, https://doi.org/10.1016/0009-2614(77)80387-4 . [all data]

Koch and Sodeau, 1995
Koch, T.G.; Sodeau, J.R., Photochemistry of Nitric Acid in Low-Temperature Matrixes, J. Phys. Chem., 1995, 99, 27, 10824, https://doi.org/10.1021/j100027a023 . [all data]

Hojer, May, et al., 1996
Hojer, S.; May, R.D.; Miller, C.E., Intensities of the 1397 cm-1 (v3) band of HO2NO2 and feasibility of atmospheric detection, J. Quant. Spectrosc. Radiat. Transfer, 1996, 55, 2, 273, https://doi.org/10.1016/0022-4073(95)00132-8 . [all data]

Levine, Uselman, et al., 1977
Levine, S.Z.; Uselman, W.M.; Chan, W.H.; Calvert, J.G.; Shaw, J.H., The kinetics and mechanisms of the HO2-NO2 reactions; the significance of peroxynitric acid formation in photochemical smog, Chem. Phys. Lett., 1977, 48, 3, 528, https://doi.org/10.1016/0009-2614(77)85086-0 . [all data]

May and Peterson, 1991
May, R.D.; Peterson, D.B., Observation of the O«58872»O stretch fundamental band of HO2NO2, J. Mol. Spectrosc., 1991, 150, 2, 647, https://doi.org/10.1016/0022-2852(91)90256-A . [all data]

May, Molina, et al., 1988
May, R.D.; Molina, L.T.; Webster, C.R., Tunable diode laser measurements of peroxynitric acid absorption coefficients near 12.5 .mu.m, J. Phys. Chem., 1988, 92, 16, 4667, https://doi.org/10.1021/j100327a022 . [all data]

Friedl, May, et al., 1994
Friedl, R.R.; May, R.D.; Duxbury, G., The «nu»6, «nu»7, «nu»8, and «nu»10 Bands of HO2NO2, J. Mol. Spectrosc., 1994, 165, 2, 481, https://doi.org/10.1006/jmsp.1994.1151 . [all data]

Suenram, Lovas, et al., 1986
Suenram, R.D.; Lovas, F.J.; Pickett, H.M., The microwave spectrum and molecular conformation of peroxynitric acid (HOONO2), J. Mol. Spectrosc., 1986, 116, 2, 406, https://doi.org/10.1016/0022-2852(86)90136-0 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References