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1,3,5-Hexatriene, (Z)-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to C6H8+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference
8.31 ± 0.02PEAllan, Dannacher, et al., 1980
8.32 ± 0.02PEBieri, Burger, et al., 1977
8.3 ± 0.1SGavin and Rice, 1974
8.32PEBeez, Bieri, et al., 1973

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Allan, Dannacher, et al., 1980
Allan, M.; Dannacher, J.; Maier, J.P., Radiative and fragmentation decay of the cations of trans- and cis 1,3,5-hexatriene of all trans-1,3,5-heptatriene in the A(«pi»-1) states, studied by emission photoelectron-photoion coincidence spectroscopy, J. Chem. Phys., 1980, 73, 3114. [all data]

Bieri, Burger, et al., 1977
Bieri, G.; Burger, F.; Heilbronner, E.; Maier, J.P., Valence ionization enrgies of hydrocarbons, Helv. Chim. Acta, 1977, 60, 2213. [all data]

Gavin and Rice, 1974
Gavin, R.M., Jr.; Rice, S.A., Spectroscopic properties of polyenes. II. The vacuum ultraviolet spectra of cis- and trans-1,3,5-hexatriene, J. Chem. Phys., 1974, 60, 3231. [all data]

Beez, Bieri, et al., 1973
Beez, M.; Bieri, G.; Bock, H.; Heilbronner, E., The ionization potentials of butadiene, hexatriene, andtheir methyl derivatives: evidence for through space interaction between double bond «pi»-orbitals and non-bonded pseudo-«pi» orbitals of methyl groups?, Helv. Chim. Acta, 1973, 56, 1028. [all data]


Notes

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