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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil580.8KN/AWeast and Grasselli, 1989BS
Tboil580.KN/AAmerican Tokyo Kasei, 1988BS
Tboil572.65KN/AJeffreys, 1899Uncertainty assigned by TRC = 5. K; TRC
Quantity Value Units Method Reference Comment
Tfus313.15KN/ARichet, 1946Uncertainty assigned by TRC = 2. K; TRC
Tfus310.15KN/AStaudinger and Roessler, 1936Uncertainty assigned by TRC = 1. K; TRC
Tfus306.65KN/ANaegeli, Gruntuch, et al., 1929Uncertainty assigned by TRC = 2. K; TRC
Tfus309.65KN/AJeffreys, 1899Uncertainty assigned by TRC = 0.5 K; TRC
Tfus309.65KN/AJeffreys, 1897Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Deltavap88.1 ± 0.3kJ/molGSEmel'yanenko, Verevkin, et al., 2005Based on data from 336. - 372. K.; AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
75.5418.AStephenson and Malanowski, 1987Based on data from 403. - 596. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

American Tokyo Kasei, 1988
American Tokyo Kasei, TCI American Organic Chemical 88/89 Catalog, American Tokyo Kasei, Portland, OR, 1988, 1610. [all data]

Jeffreys, 1899
Jeffreys, E., On Undecylamine and Pentadecylamine and the Preparation of the Higher Amines of the Aliphatic Series, Am. Chem. J., 1899, 22, 14. [all data]

Richet, 1946
Richet, H., On the Chlorides, Amides, and AMines of the Fatty Acids, Bull. Soc. Chim. Fr., 1946, 13, 52. [all data]

Staudinger and Roessler, 1936
Staudinger, H.; Roessler, K., Highly Polymerized Compounds. CXXIII. Viscosity Measurements on Long- Chain Aliphatic Amines., Chem. Ber., 1936, 69B, 49-60. [all data]

Naegeli, Gruntuch, et al., 1929
Naegeli, C.; Gruntuch, L.; Lendorff, P., A Modified Curtius Degradation III. The Degradation of Saturated Fatty Acids and Benzoic Acid, Helv. Chim. Acta, 1929, 12, 227. [all data]

Jeffreys, 1897
Jeffreys, E., Chem. Ber., 1897, 30, 898. [all data]

Emel'yanenko, Verevkin, et al., 2005
Emel'yanenko, Vladimir N.; Verevkin, Sergey P.; Koutek, Bohumir; Doubsky, Jan, Vapour pressures and enthalpies of vapourization of a series of the linear aliphatic nitriles, The Journal of Chemical Thermodynamics, 2005, 37, 1, 73-81, https://doi.org/10.1016/j.jct.2004.08.004 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Go To: Top, Phase change data, References