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Sulfur hexafluoride

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafgas-1220.47kJ/molReviewChase, 1998Data last reviewed in June, 1976
Quantity Value Units Method Reference Comment
gas,1 bar291.52J/mol*KReviewChase, 1998Data last reviewed in June, 1976

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. - 1000.1000. - 6000.
A 58.90319157.1393
B 255.53990.484022
C -252.2747-0.100724
D 88.760630.007127
E -1.608971-8.279635
F -1252.744-1291.990
G 287.9914443.2111
H -1220.473-1220.473
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in June, 1976 Data last reviewed in June, 1976

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil209.3KN/APCR Inc., 1990BS
Quantity Value Units Method Reference Comment
Ttriple223.72KN/AOhta, Yamamuro, et al., 1994Crystal phase 1 phase; Uncertainty assigned by TRC = 0.01 K; TRC
Quantity Value Units Method Reference Comment
Tc568.8KN/AMatzik and Schneider, 1985Uncertainty assigned by TRC = 0.7 K; TRC
Tc318.72KN/AGoloborod'ko and Khodeeva, 1972Vis, as Goloborod'ko and Khodeeva Zh.Fiz.Khim. 1969,43,1340; TRC
Tc318.71KN/AMakarevich, Sokolova, et al., 1968Uncertainty assigned by TRC = 0.005 K; TRC
Tc318.76KN/AKhodeeva, 1966TRC
Tc591.85KN/AAtack and Schneider, 1951Uncertainty assigned by TRC = 0.05 K; By observation of meniscus and plot of density vs. temp. Temperature measured with Pt Res. Therm., calibration at N.B.S., presumably IPTS-48; TRC
Quantity Value Units Method Reference Comment
Pc24.90barN/AMatzik and Schneider, 1985Uncertainty assigned by TRC = 0.30 bar; TRC
Pc37.586barN/AMakarevich, Sokolova, et al., 1968Uncertainty assigned by TRC = 0.005 bar; TRC
Quantity Value Units Method Reference Comment
Vc0.198l/molN/AMakarevich, Sokolova, et al., 1968Uncertainty assigned by TRC = 0.0004 l/mol; Vis, rect; method as Sorina and Efremova Russ. J. Phys. Chem. 1966, 40, 143.; TRC
Vc0.197l/molN/AKhodeeva, 1966Vis, samples thoroughly purified; TRC
Quantity Value Units Method Reference Comment
rhoc5.0581mol/lN/AMakarevich and Sokolova, 1973Uncertainty assigned by TRC = 0.001 mol/l; Vis, volume adjusted by injection of mercury; TRC
rhoc5.147mol/lN/AAtack and Schneider, 1951Uncertainty assigned by TRC = 0.004 mol/l; from plot of density vs temperature, at the Tc; TRC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Reference Comment
23.2 ± 0.01186.Ohta, Yamamuro, et al., 1994, 2AC
23.3191.Klemm and Henkel, 1932Based on data from 175. - 207. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(Fluorine anion bullet Sulfur hexafluoride) + Sulfur hexafluoride = (Fluorine anion bullet 2Sulfur hexafluoride)

By formula: (F- bullet F6S) + F6S = (F- bullet 2F6S)

Quantity Value Units Method Reference Comment
Deltar16.7 ± 1.3kJ/molTDAsHiraoka, Shimizu, et al., 1995gas phase; Entropy estimated. Gaff = +1.4 at 141 K
Quantity Value Units Method Reference Comment
Deltar-5.9 ± 1.3kJ/molTDAsHiraoka, Shimizu, et al., 1995gas phase; Entropy estimated. Gaff = +1.4 at 141 K

F6S- + Sulfur hexafluoride = (F6S- bullet Sulfur hexafluoride)

By formula: F6S- + F6S = (F6S- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar9.6 ± 1.3kJ/molTDAsHiraoka, Shimizu, et al., 1995gas phase; Entropy estimated. Gaff=+0.37 at 141K
Quantity Value Units Method Reference Comment
Deltar-13.0 ± 1.3kJ/molTDAsHiraoka, Shimizu, et al., 1995gas phase; Entropy estimated. Gaff=+0.37 at 141K

Fluorine anion + Sulfur hexafluoride = (Fluorine anion bullet Sulfur hexafluoride)

By formula: F- + F6S = (F- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar22.6 ± 1.3kJ/molTDAsHiraoka, Shimizu, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Deltar-3. ± 13.kJ/molTDAsHiraoka, Shimizu, et al., 1995gas phase

C6H4N2O4- + Sulfur hexafluoride = (C6H4N2O4- bullet Sulfur hexafluoride)

By formula: C6H4N2O4- + F6S = (C6H4N2O4- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar<35.6kJ/molIMRBChowdhury and Kebarle, 1986gas phase
Quantity Value Units Method Reference Comment
Deltar<7.95kJ/molIMRBChowdhury and Kebarle, 1986gas phase

C6H4N2O4- + Sulfur hexafluoride = (C6H4N2O4- bullet Sulfur hexafluoride)

By formula: C6H4N2O4- + F6S = (C6H4N2O4- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar<35.1kJ/molIMRBChowdhury and Kebarle, 1986gas phase
Quantity Value Units Method Reference Comment
Deltar<7.11kJ/molIMRBChowdhury and Kebarle, 1986gas phase

F5S- + Sulfur hexafluoride = (F5S- bullet Sulfur hexafluoride)

By formula: F5S- + F6S = (F5S- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar<9.62kJ/molTDAsHiraoka, Shimizu, et al., 1995gas phase; No formation at 141 K

Chlorine anion + Sulfur hexafluoride = (Chlorine anion bullet Sulfur hexafluoride)

By formula: Cl- + F6S = (Cl- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar<7.53kJ/molIMRBChowdhury and Kebarle, 1986gas phase

Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/kg*bar)
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/kg*bar) d(ln(kH))/d(1/T) (K) Method Reference
0.000242400.LN/A

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
MM - Michael M. Meot-Ner (Mautner)
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LL - Sharon G. Lias and Joel F. Liebman
B - John E. Bartmess

Quantity Value Units Method Reference Comment
IE (evaluated)15.32 ± 0.02eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)575.3kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity550.7kJ/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
0.910 ± 0.070N/AMenk, Das, et al., 2014B
1.030 ± 0.050N/ATroe, Miller, et al., 2012W4 theory supports this (12KER/MAR) and lower level calculations have flaws; B
1.070 ± 0.070TDAsChen, Wiley, et al., 1994B
1.15 ± 0.15KineChen, Shuie, et al., 1988From the temperature dependence of the API spectra of SF5-/SF6-; B
1.05 ± 0.10TDEqGrimsrud, Chowdhury, et al., 1985«DELTA»Gea(423 K) = -29.8 kcal/mol; «DELTA»Sea = +13 eu. See also Chowdhury, Heinis, et al., 1986, Bopp, Roscioli, et al., 2007; B
1.39 ± 0.13KineHeneghan and Benson, 1983B
0.799982KineLifshitz, 1983Review: literature consistent with «DELTA»S(act) for detachment = -14 eu; B
1.20 ± 0.30N/AChase Jr., Curnutt, et al., 1982Literature average; B
0.542052LPDDrzaic and Brauman, 1982B
>0.934931R-ARefaey and Franklin, 1978B
2.60 ± 0.10ECDChen and Chen, 2007B
2.60 ± 0.10ECDChen and Chen, 2007B
3.15999LPDDatskos, Carter, et al., 1995Stated electron affinity is the Vertical Detachment Energy; B
>0.698163ECDChen and Wentworth, 1983B
0.46 ± 0.20NBIECompton, Reinhardt, et al., 1978B
0.75 ± 0.10NBIELeffert, Tang, et al., 1974B
0.54 ± 0.17NBIECompton and Cooper, 1973B
0.53 ± 0.10NBIECompton, Cooper, et al., 1973B
>0.60 ± 0.10EndoLifshitz, Tiernan, et al., 1973B
0.95 ± 0.52IMRBFehsenfeld, 1971B
0.43IMRBLifshitz, Hughes, et al., 1970B
>0.698163ECDChen, George, et al., 1968B
1.10002ESCompton, Christophorou, et al., 1966B
0.32 ± 0.15NBIEHubers and Los, 1975B
1.49 ± 0.22SIKay and Page, 1964The Magnetron method, lacking mass analysis, is not considered reliable.; B

Gas basicity at 298K

Gas basicity (review) (kJ/mol) Reference Comment
575.3Pepi, Ricci, et al., 2005T = 298K; PA(SF6) equated to PA(N2O) based on dissociative PT reactions with large entropy changes that may affect the kinetics.; MM

Ionization energy determinations

IE (eV) Method Reference Comment
15.30PEDelwiche, 1969RDSH
15.30PEDelwiche, 1969RDSH
15.35 ± 0.02PEFrost, McDowell, et al., 1967RDSH
15.7PEBieri, Asbrink, et al., 1982Vertical value; LBLHLM
15.7PESell and Kupperman, 1978Vertical value; LLK
15.69PEPotts, Lempka, et al., 1970Vertical value; RDSH
15.81PEDelwiche, 1969Vertical value; RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
F+37.5 ± 1.0?EIPullen and Stockdale, 1976LLK
FS+37.6 ± 3.0?EIPullen and Stockdale, 1976LLK
FS+30.5 ± 0.5?EIHildenbrand, 1973LLK
F2+18.0 ± 1.0?EIPullen and Stockdale, 1976LLK
F2S+27.0 ± 0.3?EIPullen and Stockdale, 1976LLK
F2S+27.5 ± 0.5?EIHildenbrand, 1973LLK
F3S+18.79 ± 0.14?PIMitsuke, Suzuki, et al., 1990LL
F3S+19.4 ± 0.5?PISasanuma, Ishiguro, et al., 1979LLK
F3S+19.6 ± 0.5?EIPullen and Stockdale, 1976LLK
F3S+20.0 ± 0.5?EIHildenbrand, 1973LLK
SF3+19.80 ± 0.10F2+F?EIDelwiche, 1969RDSH
F3S+21.53FPEDelwiche, 1969RDSH
F3S+19.8 ± 0.1F2+FPEDelwiche, 1969RDSH
F4S+19.1 ± 0.52FPISasanuma, Ishiguro, et al., 1979LLK
F4S+19.6 ± 1.02FEIPullen and Stockdale, 1976LLK
F4S+18.44 ± 0.102FEIHildenbrand, 1973LLK
F4S+18.5 ± 0.12FPEDelwiche, 1969RDSH
SF4+18.50 ± 0.102F?EIDelwiche, 1969RDSH
F5S+15.32 ± 0.04FPIMitsuke, Suzuki, et al., 1990LL
F5S+<=13.78FIMBStone and Wytenberg, 1989T = 298K; LL
F5S+13.97 ± 0.04FENDTichy, Javahery, et al., 1987LBLHLM
F5S+<=14.4FIMBShul, Upschulte, et al., 1987LBLHLM
F5S+14.62 ± 0.09FIMBBabcock and Streit, 1981LLK
F5S+15.3 ± 0.2FPISasanuma, Ishiguro, et al., 1979LLK
F5S+16.2 ± 0.2FEIPullen and Stockdale, 1976LLK
F5S+<=14.53 ± 0.05FPIPECOSimm, Danby, et al., 1975LLK
F5S+15.50 ± 0.10FEIHildenbrand, 1973LLK
F5S+15.75 ± 0.05FPEDelwiche, 1969RDSH
SF5+15.75 ± 0.05FEIDelwiche, 1969RDSH
SF5+15.29FPIDibeler and Walker, 1966RDSH
SF5+15.85 ± 0.15FEIFox and Curran, 1961RDSH
F5S+15.9 ± 0.2FEIDibeler and Mohler, 1948RDSH

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Gas Chromatography, Site Links, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C6H4N2O4- + Sulfur hexafluoride = (C6H4N2O4- bullet Sulfur hexafluoride)

By formula: C6H4N2O4- + F6S = (C6H4N2O4- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar<35.6kJ/molIMRBChowdhury and Kebarle, 1986gas phase
Quantity Value Units Method Reference Comment
Deltar<7.95kJ/molIMRBChowdhury and Kebarle, 1986gas phase

C6H4N2O4- + Sulfur hexafluoride = (C6H4N2O4- bullet Sulfur hexafluoride)

By formula: C6H4N2O4- + F6S = (C6H4N2O4- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar<35.1kJ/molIMRBChowdhury and Kebarle, 1986gas phase
Quantity Value Units Method Reference Comment
Deltar<7.11kJ/molIMRBChowdhury and Kebarle, 1986gas phase

Chlorine anion + Sulfur hexafluoride = (Chlorine anion bullet Sulfur hexafluoride)

By formula: Cl- + F6S = (Cl- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar<7.53kJ/molIMRBChowdhury and Kebarle, 1986gas phase

Fluorine anion + Sulfur hexafluoride = (Fluorine anion bullet Sulfur hexafluoride)

By formula: F- + F6S = (F- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar22.6 ± 1.3kJ/molTDAsHiraoka, Shimizu, et al., 1995gas phase
Quantity Value Units Method Reference Comment
Deltar-3. ± 13.kJ/molTDAsHiraoka, Shimizu, et al., 1995gas phase

(Fluorine anion bullet Sulfur hexafluoride) + Sulfur hexafluoride = (Fluorine anion bullet 2Sulfur hexafluoride)

By formula: (F- bullet F6S) + F6S = (F- bullet 2F6S)

Quantity Value Units Method Reference Comment
Deltar16.7 ± 1.3kJ/molTDAsHiraoka, Shimizu, et al., 1995gas phase; Entropy estimated. Gaff = +1.4 at 141 K
Quantity Value Units Method Reference Comment
Deltar-5.9 ± 1.3kJ/molTDAsHiraoka, Shimizu, et al., 1995gas phase; Entropy estimated. Gaff = +1.4 at 141 K

F5S- + Sulfur hexafluoride = (F5S- bullet Sulfur hexafluoride)

By formula: F5S- + F6S = (F5S- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar<9.62kJ/molTDAsHiraoka, Shimizu, et al., 1995gas phase; No formation at 141 K

F6S- + Sulfur hexafluoride = (F6S- bullet Sulfur hexafluoride)

By formula: F6S- + F6S = (F6S- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar9.6 ± 1.3kJ/molTDAsHiraoka, Shimizu, et al., 1995gas phase; Entropy estimated. Gaff=+0.37 at 141K
Quantity Value Units Method Reference Comment
Deltar-13.0 ± 1.3kJ/molTDAsHiraoka, Shimizu, et al., 1995gas phase; Entropy estimated. Gaff=+0.37 at 141K

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, Gas Chromatography, Site Links, NIST Free Links, References, Notes

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Data compiled by: Pamela M. Chu, Franklin R. Guenther, George C. Rhoderick, and Walter J. Lafferty


Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Site Links, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillarySPB-1135.Flanagan, Streete, et al., 199760. m/0.53 mm/5. «mu»m, He; Program: 40C(6min) => 5C/min => 80C => 10C/min => 200C
CapillarySPB-1135.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 «mu»m, Helium; Program: 40 0C (6 min) 5 0C/min -> 80 0C 10 0C/min -> 200 0C

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Gas Chromatography, Site Links, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Ohta, Yamamuro, et al., 1994
Ohta, T.; Yamamuro, O.; Suga, H., Heat capacity and enthalpy of sublimation of sulful hexafluoride, J. Chem. Thermodyn., 1994, 26, 319-31. [all data]

Matzik and Schneider, 1985
Matzik, I.; Schneider, G.M., Fluid phase equilibria of binary mixtures of sulfur hexafluoride with octane, nonane, hendecane, and cis-decahydronaphthalene at temperature between 280 K and 440 K and at pressures up to 140 MPa, Ber. Bunsen-Ges. Phys. Chem., 1985, 89, 551. [all data]

Goloborod'ko and Khodeeva, 1972
Goloborod'ko, N.P.; Khodeeva, S.M., Russ. J. Phys. Chem. (Engl. Transl.), 1972, 46, 235-7. [all data]

Makarevich, Sokolova, et al., 1968
Makarevich, L.A.; Sokolova, E.S.; Sorina, G.A., Critical Parameters pf Sulfur Hexafluoride, Zh. Fiz. Khim., 1968, 42, 22-3. [all data]

Khodeeva, 1966
Khodeeva, S.M., Visual Observation of Gas-Gas Mixture, Russ. J. Phys. Chem. (Engl. Transl.), 1966, 40, 1061-3. [all data]

Atack and Schneider, 1951
Atack, D.; Schneider, W.G., The Coexistence Curve of Sulfur Hexafluoride in the Critical Region., J. Phys. Colloid Chem., 1951, 55, 532. [all data]

Makarevich and Sokolova, 1973
Makarevich, L.A.; Sokolova, O.N., Russ. J. Phys. Chem. (Engl. Transl.), 1973, 47, 436-7. [all data]

Ohta, Yamamuro, et al., 1994, 2
Ohta, Tomoko; Yamamuro, Osamu; Suga, Hiroshi, Heat capacity and enthalpy of sublimation of sulfur hexafluoride, The Journal of Chemical Thermodynamics, 1994, 26, 3, 319-331, https://doi.org/10.1016/0021-9614(94)90009-4 . [all data]

Klemm and Henkel, 1932
Klemm, Wilhelm; Henkel, Paul, «65533»ber einige physikalische Eigenschaften von SF6, SeF6, TeF6 und CF4, Z. Anorg. Allg. Chem., 1932, 207, 1, 73-86, https://doi.org/10.1002/zaac.19322070107 . [all data]

Hiraoka, Shimizu, et al., 1995
Hiraoka, K.; Shimizu, A.; Minamitsu, A.; Nasu, M.; Fujimaki, S.; Yamabe, S., The small binding energies of the negative cluster ions: SF5-(SF6)1, SF6-(SF6)1 and F-(SF6)n (n=1 and 2), in the gas phase, Chem. Phys. Lett., 1995, 241, 5-6, 623, https://doi.org/10.1016/0009-2614(95)00676-U . [all data]

Chowdhury and Kebarle, 1986
Chowdhury, S.; Kebarle, P., Role of Binding Energies in A-.B and A.B- Complexes in the Kinetics of Gas Phase Electron Transfer Reactions:A- + B = A + B- Involving Perfluoro Compounds: SF6, C6F11CF3, J. Chem. Phys., 1986, 85, 9, 4989, https://doi.org/10.1063/1.451687 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Menk, Das, et al., 2014
Menk, S.; Das, S.; Blaum, K.; Froese, M.W.; Lange, M.; Mukherjee, M.; Repnow, R.; Schwalm, D.; von Hahn, R.; Wolf, A., Vibrational autodetachment of sulfur hexafluoride anions at its long-lifetime limit, Phys. Rev. A, 2014, 89, 2, 022502, https://doi.org/10.1103/PhysRevA.89.022502 . [all data]

Troe, Miller, et al., 2012
Troe, J.; Miller, T.M.; Viggiano, A.A., Communication: Revised electron affinity of SF6 from kinetic data, J. Chem. Phys., 2012, 136, 12, 121102, https://doi.org/10.1063/1.3698170 . [all data]

Chen, Wiley, et al., 1994
Chen, E.C.M.; Wiley, J.R.; Batten, C.F.; Wentworth, W.E., Determination of the Electron Affinities of Molecules Using Negative Ion Mass Spectrometry, J. Phys. Chem., 1994, 98, 1, 88, https://doi.org/10.1021/j100052a016 . [all data]

Chen, Shuie, et al., 1988
Chen, E.C.M.; Shuie, L.-R.; DSa, E.D.; Batten, C.F.; Wentworth, W.E., The Negative Ion States of SF6, J. Chem. Phys., 1988, 88, 8, 4711, https://doi.org/10.1063/1.454710 . [all data]

Grimsrud, Chowdhury, et al., 1985
Grimsrud, E.P.; Chowdhury, S.; Kebarle, P., Electron affinity of SF6 and perfluoromethylcyclohexane. The unusual kinetics of electron transfer reactions A- + B- + A, where A = SF6 or perfluorinated cycloalkanes, J. Chem. Phys., 1985, 83, 1059. [all data]

Chowdhury, Heinis, et al., 1986
Chowdhury, S.; Heinis, T.; Grimsrud, E.P.; Kebarle, P., Entropy Changes and Electron Affinities from Gas-Phase Electron Transfer Equilibria: A- + B = A + B-, J. Phys. Chem., 1986, 90, 12, 2747, https://doi.org/10.1021/j100403a037 . [all data]

Bopp, Roscioli, et al., 2007
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Notes

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