Neodymium dichloride


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Cl2Nd = (Chlorine anion • Cl2Nd)

By formula: Cl- + Cl2Nd = (Cl- • Cl2Nd)

Quantity Value Units Method Reference Comment
Δr274. ± 15.kJ/molTDAsKudin, Pogrebnoi, et al., 1993gas phase; value altered from reference due to conversion from electron convention to ion convention

Cl3Nd- + Cl2Nd = Cl5Nd2-

By formula: Cl3Nd- + Cl2Nd = Cl5Nd2-

Quantity Value Units Method Reference Comment
Δr369. ± 22.kJ/molTDAsKudin, Pogrebnoi, et al., 1993gas phase; value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

View reactions leading to Cl2Nd+ (ion structure unspecified)

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Nd+15.13 ± 0.072ClEISapegin, Baluev, et al., 1984 

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + Cl2Nd = (Chlorine anion • Cl2Nd)

By formula: Cl- + Cl2Nd = (Cl- • Cl2Nd)

Quantity Value Units Method Reference Comment
Δr274. ± 15.kJ/molTDAsKudin, Pogrebnoi, et al., 1993gas phase; value altered from reference due to conversion from electron convention to ion convention

Cl3Nd- + Cl2Nd = Cl5Nd2-

By formula: Cl3Nd- + Cl2Nd = Cl5Nd2-

Quantity Value Units Method Reference Comment
Δr369. ± 22.kJ/molTDAsKudin, Pogrebnoi, et al., 1993gas phase; value altered from reference due to conversion from electron convention to ion convention

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kudin, Pogrebnoi, et al., 1993
Kudin, L.S.; Pogrebnoi, A.M.; Burdukovskaya, G.G., Mass-Spectrometric Study of Saturated Vapor Composition over Neodymium Chlorides .2. Ion-Molecular Equilibrium and Enthalpies of Formation of Formation of Positive and Negative Ions., Zh. Fiz. Khim. SSSR, 1993, 67, 908. [all data]

Sapegin, Baluev, et al., 1984
Sapegin, A.M.; Baluev, A.V.; Evdokimov, V.I., Mass-spectrometric investigation of the thermochemistry of the chlorides of the lanthanides, Russ. J. Phys. Chem., 1984, 58, 1792. [all data]


Notes

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