Thiophosphoryl chlorodifluoride


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   Cs     Symmetry Number σ = 1


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a' 1 PF2 s-str 946  B 946 VS gas 939 p liq.
a' 2 PS str 738  B 738 VS gas 727 p liq.
a' 3 PCl str 541  B 541 S gas 536 p liq.
a' 4 PCl bend 395  B 395 M gas 394 p liq.
a' 5 PF2 scis 361  B 361 M gas 359 p liq.
a' 6 PS ip-bend 207  C 198 gas 207 p liq.
a 7 PF2 s-str 920  B 920 VS gas 913 dp liq.
a 8 PF2 rock 317  B 317 M gas 314 dp liq.
a 9 PS op-bend 251  C 251 dp liq.

Source: Shimanouchi, 1972

Notes

VSVery strong
SStrong
MMedium
pPolarized
dpDepolarized
B1~3 cm-1 uncertainty
C3~6 cm-1 uncertainty

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shimanouchi, 1972
Shimanouchi, T., Tables of Molecular Vibrational Frequencies Consolidated Volume II, J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]


Notes

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