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Methylenecycloheptane

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director

Quantity Value Units Method Reference Comment
Tboil408.KN/ATurner and Garner, 1958Uncertainty assigned by TRC = 2. K
Tboil412.KN/ATraynham and Pascual, 1956Uncertainty assigned by TRC = 3. K
Tboil406.KN/ASorm and Beranek, 1953Uncertainty assigned by TRC = 1. K

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen + Methylenecycloheptane = Cycloheptane, methyl-

By formula: H2 + C8H14 = C8H16

Quantity Value Units Method Reference Comment
Deltar-109.9 ± 0.59kJ/molChydTurner and Garner, 1958, 2liquid phase; solvent: Acetic acid
Deltar-109.9 ± 0.59kJ/molChydTurner and Garner, 1957liquid phase; solvent: Acetic acid

References

Go To: Top, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Turner and Garner, 1958
Turner, R.B.; Garner, R.H., Heats of Hydrogenation V. Relative Stabilities in Certain Exocyclic- Endocyclic Olefin Pairs, J. Am. Chem. Soc., 1958, 80, 1424. [all data]

Traynham and Pascual, 1956
Traynham, J.G.; Pascual, O.S., J. Org. Chem., 1956, 21, 1362. [all data]

Sorm and Beranek, 1953
Sorm, F.; Beranek, J., Synthesis of methylenecycloalkanes, Chem. Listy, 1953, 47, 708. [all data]

Turner and Garner, 1958, 2
Turner, R.B.; Garner, R.H., Heats of hydrogenation. V. Relative stabilities in certain exocyclic-endocyclic olefin pairs, J. Am. Chem. Soc., 1958, 80, 1424-1430. [all data]

Turner and Garner, 1957
Turner, R.B.; Garner, R.H., Heats of hydrogenation. V. Relative stabilities in certain exocyclic-endocyclic olefin pairs, J. Am. Chem. Soc., 1957, 80, 1424-1430. [all data]


Notes

Go To: Top, Phase change data, Reaction thermochemistry data, References