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Sulfur fluoride anion


Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar302.85J/mol*KReviewChase, 1998Data last reviewed in June, 1977

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C6H4N2O4- + F6S- = (C6H4N2O4- bullet F6S-)

By formula: C6H4N2O4- + F6S- = (C6H4N2O4- bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar36.kJ/molPHPMSChowdhury and Kebarle, 1986gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH<; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/AChowdhury and Kebarle, 1986gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH<; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
7.9334.PHPMSChowdhury and Kebarle, 1986gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH<; M

C6H4N2O4- + F6S- = (C6H4N2O4- bullet F6S-)

By formula: C6H4N2O4- + F6S- = (C6H4N2O4- bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar35.kJ/molPHPMSChowdhury and Kebarle, 1986gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH<; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/AChowdhury and Kebarle, 1986gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH<; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
7.1334.PHPMSChowdhury and Kebarle, 1986gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH<; M

(F6S- bullet 4294967295Sulfur pentafluoride) + Sulfur pentafluoride = F6S-

By formula: (F6S- bullet 4294967295F5S) + F5S = F6S-

Quantity Value Units Method Reference Comment
Deltar169. ± 14.kJ/molN/AGrimsrud, Chowdhury, et al., 1985gas phase; «DELTA»Gea(423 K) = -29.8 kcal/mol; «DELTA»Sea = +13 eu. See also Chowdhury, Heinis, et al., 1986, Bopp, Roscioli, et al., 2007; B
Deltar179. ± 12.kJ/molCIDTLobring, Check, et al., 2003gas phase; Affinity: SF5- + F. Barrier to dissociation, but less than barrier to photodissociation; B

(F3S+ bullet 2F6S-) + F6S- = (F3S+ bullet 3F6S-)

By formula: (F3S+ bullet 2F6S-) + F6S- = (F3S+ bullet 3F6S-)

Quantity Value Units Method Reference Comment
Deltar17.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar79.J/mol*KN/AHiraoka, Shimizu, et al., 1995gas phase; Entropy change calculated or estimated; M

(Fluorine anion bullet F6S-) + F6S- = (Fluorine anion bullet 2F6S-)

By formula: (F- bullet F6S-) + F6S- = (F- bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar17.kJ/molPHPMSHiraoka, Shimizu, et al., 1995, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar75.J/mol*KN/AHiraoka, Shimizu, et al., 1995, 2gas phase; Entropy change calculated or estimated; M

F6S- + F6S- = (F6S- bullet F6S-)

By formula: F6S- + F6S- = (F6S- bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar9.6kJ/molPHPMSHiraoka, Shimizu, et al., 1995, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar75.J/mol*KN/AHiraoka, Shimizu, et al., 1995, 2gas phase; Entropy change calculated or estimated; M

(Sulfur cation bullet 2F6S-) + F6S- = (Sulfur cation bullet 3F6S-)

By formula: (S+ bullet 2F6S-) + F6S- = (S+ bullet 3F6S-)

Quantity Value Units Method Reference Comment
Deltar13.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar46.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(FS+ bullet 2F6S-) + F6S- = (FS+ bullet 3F6S-)

By formula: (FS+ bullet 2F6S-) + F6S- = (FS+ bullet 3F6S-)

Quantity Value Units Method Reference Comment
Deltar15.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar71.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(F2S+ bullet 2F6S-) + F6S- = (F2S+ bullet 3F6S-)

By formula: (F2S+ bullet 2F6S-) + F6S- = (F2S+ bullet 3F6S-)

Quantity Value Units Method Reference Comment
Deltar18.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(F4S+ bullet F6S-) + F6S- = (F4S+ bullet 2F6S-)

By formula: (F4S+ bullet F6S-) + F6S- = (F4S+ bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar19.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar59.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(Sulfur cation bullet F6S-) + F6S- = (Sulfur cation bullet 2F6S-)

By formula: (S+ bullet F6S-) + F6S- = (S+ bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar14.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar46.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(F3S+ bullet F6S-) + F6S- = (F3S+ bullet 2F6S-)

By formula: (F3S+ bullet F6S-) + F6S- = (F3S+ bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar19.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar79.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(F5S- bullet F6S-) + F6S- = (F5S- bullet 2F6S-)

By formula: (F5S- bullet F6S-) + F6S- = (F5S- bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar15.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar79.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(FS+ bullet F6S-) + F6S- = (FS+ bullet 2F6S-)

By formula: (FS+ bullet F6S-) + F6S- = (FS+ bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar16.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar67.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(F2S+ bullet F6S-) + F6S- = (F2S+ bullet 2F6S-)

By formula: (F2S+ bullet F6S-) + F6S- = (F2S+ bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar21.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

F4S+ + F6S- = (F4S+ bullet F6S-)

By formula: F4S+ + F6S- = (F4S+ bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar30.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

Sulfur cation + F6S- = (Sulfur cation bullet F6S-)

By formula: S+ + F6S- = (S+ bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar39.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

F3S+ + F6S- = (F3S+ bullet F6S-)

By formula: F3S+ + F6S- = (F3S+ bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar31.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

FS+ + F6S- = (FS+ bullet F6S-)

By formula: FS+ + F6S- = (FS+ bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar38.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

F2S+ + F6S- = (F2S+ bullet F6S-)

By formula: F2S+ + F6S- = (F2S+ bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar33.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar75.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

F6S- + Benzene, 1-fluoro-3-nitro- = (F6S- bullet Benzene, 1-fluoro-3-nitro-)

By formula: F6S- + C6H4FNO2 = (F6S- bullet C6H4FNO2)

Quantity Value Units Method Reference Comment
Deltar65.7kJ/molPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar109.J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M

Fluorine anion + F6S- = (Fluorine anion bullet F6S-)

By formula: F- + F6S- = (F- bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar23.kJ/molPHPMSHiraoka, Shimizu, et al., 1995, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995, 2gas phase; M

F6S- + Benzene, 1-nitro-3-(trifluoromethyl)- = (F6S- bullet Benzene, 1-nitro-3-(trifluoromethyl)-)

By formula: F6S- + C7H4F3NO2 = (F6S- bullet C7H4F3NO2)

Quantity Value Units Method Reference Comment
Deltar71.1kJ/molPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar112.J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M

F6S- + Benzene, nitro- = (F6S- bullet Benzene, nitro-)

By formula: F6S- + C6H5NO2 = (F6S- bullet C6H5NO2)

Quantity Value Units Method Reference Comment
Deltar62.3kJ/molPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M

Chlorine anion + F6S- = (Chlorine anion bullet F6S-)

By formula: Cl- + F6S- = (Cl- bullet F6S-)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
7.5300.PHPMSChowdhury and Kebarle, 1986gas phase; DG<; M

F5S- + F6S- = (F5S- bullet F6S-)

By formula: F5S- + F6S- = (F5S- bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar88.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

F6S- + Methyl Alcohol = (F6S- bullet Methyl Alcohol)

By formula: F6S- + CH4O = (F6S- bullet CH4O)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
19.308.PHPMSKnighton, Zook, et al., 1990gas phase; M

F6S- + Dimethyl Sulfoxide = (F6S- bullet Dimethyl Sulfoxide)

By formula: F6S- + C2H6OS = (F6S- bullet C2H6OS)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
30.308.PHPMSKnighton, Zook, et al., 1990gas phase; M

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C6H4N2O4- + F6S- = (C6H4N2O4- bullet F6S-)

By formula: C6H4N2O4- + F6S- = (C6H4N2O4- bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar36.kJ/molPHPMSChowdhury and Kebarle, 1986gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH<; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/AChowdhury and Kebarle, 1986gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH<; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
7.9334.PHPMSChowdhury and Kebarle, 1986gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH<; M

C6H4N2O4- + F6S- = (C6H4N2O4- bullet F6S-)

By formula: C6H4N2O4- + F6S- = (C6H4N2O4- bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar35.kJ/molPHPMSChowdhury and Kebarle, 1986gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH<; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/AChowdhury and Kebarle, 1986gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH<; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
7.1334.PHPMSChowdhury and Kebarle, 1986gas phase; Entropy change calculated or estimated, DG<, «DELTA»rH<; M

Chlorine anion + F6S- = (Chlorine anion bullet F6S-)

By formula: Cl- + F6S- = (Cl- bullet F6S-)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
7.5300.PHPMSChowdhury and Kebarle, 1986gas phase; DG<; M

Fluorine anion + F6S- = (Fluorine anion bullet F6S-)

By formula: F- + F6S- = (F- bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar23.kJ/molPHPMSHiraoka, Shimizu, et al., 1995, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995, 2gas phase; M

(Fluorine anion bullet F6S-) + F6S- = (Fluorine anion bullet 2F6S-)

By formula: (F- bullet F6S-) + F6S- = (F- bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar17.kJ/molPHPMSHiraoka, Shimizu, et al., 1995, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar75.J/mol*KN/AHiraoka, Shimizu, et al., 1995, 2gas phase; Entropy change calculated or estimated; M

FS+ + F6S- = (FS+ bullet F6S-)

By formula: FS+ + F6S- = (FS+ bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar38.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(FS+ bullet F6S-) + F6S- = (FS+ bullet 2F6S-)

By formula: (FS+ bullet F6S-) + F6S- = (FS+ bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar16.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar67.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(FS+ bullet 2F6S-) + F6S- = (FS+ bullet 3F6S-)

By formula: (FS+ bullet 2F6S-) + F6S- = (FS+ bullet 3F6S-)

Quantity Value Units Method Reference Comment
Deltar15.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar71.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

F2S+ + F6S- = (F2S+ bullet F6S-)

By formula: F2S+ + F6S- = (F2S+ bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar33.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar75.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(F2S+ bullet F6S-) + F6S- = (F2S+ bullet 2F6S-)

By formula: (F2S+ bullet F6S-) + F6S- = (F2S+ bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar21.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(F2S+ bullet 2F6S-) + F6S- = (F2S+ bullet 3F6S-)

By formula: (F2S+ bullet 2F6S-) + F6S- = (F2S+ bullet 3F6S-)

Quantity Value Units Method Reference Comment
Deltar18.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

F3S+ + F6S- = (F3S+ bullet F6S-)

By formula: F3S+ + F6S- = (F3S+ bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar31.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(F3S+ bullet F6S-) + F6S- = (F3S+ bullet 2F6S-)

By formula: (F3S+ bullet F6S-) + F6S- = (F3S+ bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar19.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar79.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(F3S+ bullet 2F6S-) + F6S- = (F3S+ bullet 3F6S-)

By formula: (F3S+ bullet 2F6S-) + F6S- = (F3S+ bullet 3F6S-)

Quantity Value Units Method Reference Comment
Deltar17.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar79.J/mol*KN/AHiraoka, Shimizu, et al., 1995gas phase; Entropy change calculated or estimated; M

F4S+ + F6S- = (F4S+ bullet F6S-)

By formula: F4S+ + F6S- = (F4S+ bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar30.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(F4S+ bullet F6S-) + F6S- = (F4S+ bullet 2F6S-)

By formula: (F4S+ bullet F6S-) + F6S- = (F4S+ bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar19.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar59.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

F5S- + F6S- = (F5S- bullet F6S-)

By formula: F5S- + F6S- = (F5S- bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar88.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(F5S- bullet F6S-) + F6S- = (F5S- bullet 2F6S-)

By formula: (F5S- bullet F6S-) + F6S- = (F5S- bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar15.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar79.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

F6S- + Methyl Alcohol = (F6S- bullet Methyl Alcohol)

By formula: F6S- + CH4O = (F6S- bullet CH4O)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
19.308.PHPMSKnighton, Zook, et al., 1990gas phase; M

F6S- + Dimethyl Sulfoxide = (F6S- bullet Dimethyl Sulfoxide)

By formula: F6S- + C2H6OS = (F6S- bullet C2H6OS)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
30.308.PHPMSKnighton, Zook, et al., 1990gas phase; M

F6S- + Benzene, 1-fluoro-3-nitro- = (F6S- bullet Benzene, 1-fluoro-3-nitro-)

By formula: F6S- + C6H4FNO2 = (F6S- bullet C6H4FNO2)

Quantity Value Units Method Reference Comment
Deltar65.7kJ/molPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar109.J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M

F6S- + Benzene, nitro- = (F6S- bullet Benzene, nitro-)

By formula: F6S- + C6H5NO2 = (F6S- bullet C6H5NO2)

Quantity Value Units Method Reference Comment
Deltar62.3kJ/molPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M

F6S- + Benzene, 1-nitro-3-(trifluoromethyl)- = (F6S- bullet Benzene, 1-nitro-3-(trifluoromethyl)-)

By formula: F6S- + C7H4F3NO2 = (F6S- bullet C7H4F3NO2)

Quantity Value Units Method Reference Comment
Deltar71.1kJ/molPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar112.J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M

(F6S- bullet 4294967295Sulfur pentafluoride) + Sulfur pentafluoride = F6S-

By formula: (F6S- bullet 4294967295F5S) + F5S = F6S-

Quantity Value Units Method Reference Comment
Deltar169. ± 14.kJ/molN/AGrimsrud, Chowdhury, et al., 1985gas phase; «DELTA»Gea(423 K) = -29.8 kcal/mol; «DELTA»Sea = +13 eu. See also Chowdhury, Heinis, et al., 1986, Bopp, Roscioli, et al., 2007; B
Deltar179. ± 12.kJ/molCIDTLobring, Check, et al., 2003gas phase; Affinity: SF5- + F. Barrier to dissociation, but less than barrier to photodissociation; B

F6S- + F6S- = (F6S- bullet F6S-)

By formula: F6S- + F6S- = (F6S- bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar9.6kJ/molPHPMSHiraoka, Shimizu, et al., 1995, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar75.J/mol*KN/AHiraoka, Shimizu, et al., 1995, 2gas phase; Entropy change calculated or estimated; M

Sulfur cation + F6S- = (Sulfur cation bullet F6S-)

By formula: S+ + F6S- = (S+ bullet F6S-)

Quantity Value Units Method Reference Comment
Deltar39.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(Sulfur cation bullet F6S-) + F6S- = (Sulfur cation bullet 2F6S-)

By formula: (S+ bullet F6S-) + F6S- = (S+ bullet 2F6S-)

Quantity Value Units Method Reference Comment
Deltar14.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar46.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

(Sulfur cation bullet 2F6S-) + F6S- = (Sulfur cation bullet 3F6S-)

By formula: (S+ bullet 2F6S-) + F6S- = (S+ bullet 3F6S-)

Quantity Value Units Method Reference Comment
Deltar13.kJ/molPHPMSHiraoka, Shimizu, et al., 1995gas phase; M
Quantity Value Units Method Reference Comment
Deltar46.J/mol*KPHPMSHiraoka, Shimizu, et al., 1995gas phase; M

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Chowdhury and Kebarle, 1986
Chowdhury, S.; Kebarle, P., Role of Binding Energies in A-.B and A.B- Complexes in the Kinetics of Gas Phase Electron Transfer Reactions:A- + B = A + B- Involving Perfluoro Compounds: SF6, C6F11CF3, J. Chem. Phys., 1986, 85, 9, 4989, https://doi.org/10.1063/1.451687 . [all data]

Grimsrud, Chowdhury, et al., 1985
Grimsrud, E.P.; Chowdhury, S.; Kebarle, P., Electron affinity of SF6 and perfluoromethylcyclohexane. The unusual kinetics of electron transfer reactions A- + B- + A, where A = SF6 or perfluorinated cycloalkanes, J. Chem. Phys., 1985, 83, 1059. [all data]

Chowdhury, Heinis, et al., 1986
Chowdhury, S.; Heinis, T.; Grimsrud, E.P.; Kebarle, P., Entropy Changes and Electron Affinities from Gas-Phase Electron Transfer Equilibria: A- + B = A + B-, J. Phys. Chem., 1986, 90, 12, 2747, https://doi.org/10.1021/j100403a037 . [all data]

Bopp, Roscioli, et al., 2007
Bopp, J.C.; Roscioli, J.R.; Johnson, M.A.; Miller, T.M.; Viggiano, A.A.; Villano, S.M.; Wren, S.W.; Lineberger, Spectroscopic characterization of the isolated SF6- and C4F8- anions: Observation of very long harmonic progressions in symmetric deformation modes upon photodetachment, J. Phys. Chem. A, 2007, 111, 7, 1214-1221, https://doi.org/10.1021/jp0665372 . [all data]

Lobring, Check, et al., 2003
Lobring, K.C.; Check, C.E.; Gilbert, T.M.; Sunderlin, L.S., New measurements of the thermochemistry of SF5- and SF6-, Int. J. Mass Spectrom., 2003, 227, 3, 361-372, https://doi.org/10.1016/S1387-3806(03)00105-2 . [all data]

Hiraoka, Shimizu, et al., 1995
Hiraoka, K.; Shimizu, A.; Minamitsu, A.; Nasu, M. Fujimaki, Gas-Phase Stability of Cluster Ions SFm+(SF6)n with m = 0-5 and n = 1-3, J. Am. Soc. Mass Spectrom., 1995, 6, 12, 1137, https://doi.org/10.1016/1044-0305(95)00583-8 . [all data]

Hiraoka, Shimizu, et al., 1995, 2
Hiraoka, K.; Shimizu, A.; Minamitsu, A.; Nasu, M.; Fujimaki, S.; Yamabe, S., The small binding energies of the negative cluster ions: SF5-(SF6)1, SF6-(SF6)1 and F-(SF6)n (n=1 and 2), in the gas phase, Chem. Phys. Lett., 1995, 241, 5-6, 623, https://doi.org/10.1016/0009-2614(95)00676-U . [all data]

Knighton, Zook, et al., 1990
Knighton, W.B.; Zook, D.R.; Grimsrud, E.P., Cluster-Assisted Decomposition Reactions of the Molecular Anions of SF6 and C7F14, J. Am. Soc. Mass Spectrom., 1990, 1, 5, 372, https://doi.org/10.1016/1044-0305(90)85017-G . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References