Bromine anion
- Formula: Br-
- Molecular weight: 79.905
- IUPAC Standard InChI:
- InChI=1S/BrH/h1H/p-1
- Download the identifier in a file.
- IUPAC Standard InChIKey: CPELXLSAUQHCOX-UHFFFAOYSA-M
- CAS Registry Number: 24959-67-9
- Chemical structure:
This structure is also available as a 2d Mol file - Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Gas phase thermochemistry data
- Reaction thermochemistry data: reactions 1 to 50, reactions 101 to 150, reactions 151 to 185
- Gas phase ion energetics data
- Ion clustering data
- Options:
Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 51 to 100
By formula: Br- + C6H6 = (Br- C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38. ± 8.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 71.1 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 71. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; B |
![]() | 16. ± 11. | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0 | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H5N = (Br- C7H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 61.5 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
26. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H5F3O = (Br- C7H5F3O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 108. ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
![]() | 52.7 | kJ/mol | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 66.9 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
17. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H7N = (Br- C6H7N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 61.1 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
26. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H6O2 = (Br- C7H6O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 76.6 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 41. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
41. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: (Br- 2C2H3N) + C2H3N = (Br-
3C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38.5 ± 1.7 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 43.5 ± 2.9 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
![]() | 41.84 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 69.9 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
![]() | 90.8 | J/mol*K | HPMS | Yamdagni and Kebarle, 1972 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18. ± 5.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
![]() | 15.1 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
By formula: (Br- C2H3N) + C2H3N = (Br-
2C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.0 ± 1.7 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 48.1 ± 2.9 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
![]() | 49.37 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 71.1 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
![]() | 85.4 | J/mol*K | HPMS | Yamdagni and Kebarle, 1972 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 28. ± 5.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
![]() | 24.3 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
By formula: Br- + CH4O = (Br- CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 60.67 ± 0.42 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 58.2 ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 73.6 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 33.5 ± 0.42 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 36. ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
![]() | 35. ± 8.4 | kJ/mol | IMRE | Tanabe, Morgon, et al., 1996 | gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B |
By formula: Br- + C7H5F3O = (Br- C7H5F3O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 101. | kJ/mol | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
60.2 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M |
By formula: (Br- HNO3) + HNO3 = (Br-
2HNO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 75.7 | kJ/mol | FA | Davidson, Fehsenfeld, et al., 1977 | gas phase; From thermochemical cycle(Br-/NO3- - HNO3/HBr), Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 98.7 | J/mol*K | N/A | Davidson, Fehsenfeld, et al., 1977 | gas phase; From thermochemical cycle(Br-/NO3- - HNO3/HBr), Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 46.4 | kJ/mol | FA | Davidson, Fehsenfeld, et al., 1977 | gas phase; From thermochemical cycle(Br-/NO3- - HNO3/HBr), Entropy change calculated or estimated; M |
By formula: (Br- 4H2O) + H2O = (Br-
5H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 45.2 ± 1.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 26. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 119. | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9.6 ± 5.0 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
By formula: (Br- 5H2O) + H2O = (Br-
6H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.1 ± 2.1 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 25. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 118. | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.5 ± 8.8 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
By formula: (Br- 6H2O) + H2O = (Br-
7H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41.84 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; Entropy estimated; B,M |
![]() | 10. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 120. | J/mol*K | N/A | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.44 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; Entropy estimated; B |
By formula: Br- + C7H8O = (Br- C7H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 84.9 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 44.4 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
44.4 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H8O = (Br- C7H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 86.2 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 45.6 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
45.6 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H8O2 = (Br- C7H8O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 92.5 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 51.9 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
51.9 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H8O2 = (Br- C7H8O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 87.9 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 47.3 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
47.3 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H5FO = (Br- C6H5FO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 87.4 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 46.9 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
46.9 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H5FO = (Br- C6H5FO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 97.5 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 56.9 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
56.9 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H5FO = (Br- C6H5FO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 97.9 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 57.3 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
57.3 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H7NO = (Br- C6H7NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 84.9 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 44.4 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
44.4 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H7NO = (Br- C6H7NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 81.6 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 41. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
41. | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C7H8O = (Br- C7H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 86.2 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 45.6 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
45.6 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H5ClO = (Br- C6H5ClO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 88.7 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 48.1 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
48.1 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + C6H5NO2 = (Br- C6H5NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 62.8 ± 7.5 | kJ/mol | TDAs | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84.5 | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27. ± 4.2 | kJ/mol | TDAs | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
27. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: Br- + HNO3 = (Br- HNO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 83.7 | kJ/mol | FA | Davidson, Fehsenfeld, et al., 1977 | gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr), «DELTA»rH>; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 77.4 | J/mol*K | FA | Davidson, Fehsenfeld, et al., 1977 | gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr), «DELTA»rH>; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
56.1 | 367. | FA | Davidson, Fehsenfeld, et al., 1977 | gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr), «DELTA»rH>; M |
By formula: Br- + C6H3N3O6 = (Br- C6H3N3O6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 92. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; 1,3,5-trinitrobenzene, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 54.8 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
54.8 | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; 1,3,5-trinitrobenzene, Entropy change calculated or estimated; M |
By formula: (Br- CO2) + CO2 = (Br-
2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 21. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
![]() | 25. ± 4.2 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 79.5 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 1. ± 8.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: Br- + CO2 = (Br- CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995, 2 | gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B |
![]() | 28. ± 4.2 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 69.0 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.5 ± 8.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: (Br- 2CH4O) + CH4O = (Br-
3CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 39.7 ± 2.1 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 44.4 ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.4 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17.8 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 18. ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (Br- CH4O) + CH4O = (Br-
2CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 50.21 ± 0.84 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 52.3 ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 86.6 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.5 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 26. ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: Br- + CH3Br = (Br- CH3Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.9 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 38.5 ± 2.1 | kJ/mol | TDAs | Dougherty and Roberts, 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 58.6 | J/mol*K | HPMS | Dougherty and Roberts, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.2 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 20.9 ± 3.3 | kJ/mol | TDAs | Dougherty and Roberts, 1974 | gas phase; B |
+
= C2BrF4-
By formula: Br- + C2F4 = C2BrF4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 29.7 ± 2.1 | kJ/mol | TDAs | Hiraoka, Mochizuki, et al., 2008 | gas phase; The experimental HOF of C2F4 has been questioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9.7 ± 2.1 | kJ/mol | TDAs | Hiraoka, Mochizuki, et al., 2008 | gas phase; The experimental HOF of C2F4 has been questioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B |
By formula: Br- + C4H9Br = (Br- C4H9Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 65.3 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 51.88 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 80.8 | J/mol*K | HPMS | Dougherty, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 30.5 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 28.0 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B |
By formula: Br- + C2H5Br = (Br- C2H5Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 50.2 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 48.53 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 80.3 | J/mol*K | HPMS | Dougherty, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24.7 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 24.7 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B |
By formula: Br- + C3H7Br = (Br- C3H7Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 59.4 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 51.04 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 83.3 | J/mol*K | HPMS | Dougherty, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26.4 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
![]() | 26.4 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B |
By formula: Br- + C6H5NO = (Br- C6H5NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 57.3 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B |
By formula: Br- + Xe = (Br- Xe)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15.1 ± 1.3 | kJ/mol | TDAs | Wada, Kikkawa, et al., 2007 | gas phase; B |
![]() | 12.1 ± 0.42 | kJ/mol | LPES | Yourshaw, Lenzer, et al., 1998 | gas phase; Given: 0.12692(.0005) eV; B |
![]() | 14.2 | kJ/mol | Mobl | Gatland, 1984 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | -4.9 ± 1.3 | kJ/mol | TDAs | Wada, Kikkawa, et al., 2007 | gas phase; B |
By formula: Br- + CHN = (Br- CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 81.2 ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
![]() | 66.9 ± 8.4 | kJ/mol | Est | Larson and McMahon, 1984 | gas phase; Extrapolated from other halide data; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 82.8 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 56.5 ± 6.7 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: Br- + C7H6O = (Br- C7H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 55.2 | kJ/mol | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84. | J/mol*K | N/A | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
20. | 423. | PHPMS | Paul and Kebarle, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: (Br- O2S) + HBr = (Br-
HBr
O2S)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.0 | kJ/mol | PHPMS | Caldwell and Kebarle, 1985 | gas phase; From thermochemical cycle,switching reaction(Br- HBr)SO2; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 80.3 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; From thermochemical cycle,switching reaction(Br- HBr)SO2; M |
By formula: (Br- O2S) + HCl = (Br-
HCl
O2S)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 93.7 | kJ/mol | PHPMS | Caldwell and Kebarle, 1985 | gas phase; From thermochemical cycle,switching reaction(Br-)SO2; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 77.8 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; From thermochemical cycle,switching reaction(Br-)SO2; M |
By formula: (Br- 9CH4O) + CH4O = (Br-
10CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 33. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; Entropy estimated.; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Hiraoka and Yamabe, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 4.6 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; Entropy estimated.; B |
By formula: Br- + HCl = (Br- HCl)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 82.0 ± 8.4 | kJ/mol | TDEq | Caldwell and Kebarle, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92.0 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; switching reaction(Br-)SO2; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 54. ± 11. | kJ/mol | TDEq | Caldwell and Kebarle, 1985 | gas phase; B |
By formula: (Br- 8CH4O) + CH4O = (Br-
9CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 34. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; Entropy estimated.; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96. | J/mol*K | N/A | Hiraoka and Yamabe, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.4 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; Entropy estimated.; B |
By formula: (Br- 4C2H3N) + C2H3N = (Br-
5C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 35.6 ± 1.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 24.3 ± 3.8 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92.9 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.5 ± 5.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
By formula: (Br- 5C2H3N) + C2H3N = (Br-
6C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 33.5 ± 0.84 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 23. ± 4.2 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 94.1 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.0 ± 3.8 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
By formula: (Br- 6C2H3N) + C2H3N = (Br-
7C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 32.2 ± 1.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 13. ± 4.6 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.8 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3. ± 5.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
By formula: Br- + H3N = (Br- H3N)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 32.2 ± 0.42 | kJ/mol | TDAs | Evans, Keesee, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 79.9 | J/mol*K | HPMS | Evans, Keesee, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.37 ± 0.84 | kJ/mol | TDAs | Evans, Keesee, et al., 1987 | gas phase; B |
By formula: Br- + C2H6OS = (Br- C2H6OS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 72.38 | kJ/mol | TDAs | Magnera, Caldwell, et al., 1984 | gas phase; B,M |
![]() | 72.0 | kJ/mol | HPMS | Caldwell, Masucci, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 89.5 | J/mol*K | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 45.61 | kJ/mol | TDAs | Magnera, Caldwell, et al., 1984 | gas phase; B |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S.,
Determination of the Stabilities and Structures of X-(C6H6) Clusters (X = Cl, Br, and I),
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. [all data]
Paul and Kebarle, 1991
Paul, G.J.C.; Kebarle, P.,
Stabilities of Complexes of Br- with Substituted Benzenes (SB) Based on Determinations of the Gas-Phase Equilibria Br- + SB = (BrSB)-,
J. Am. Chem. Soc., 1991, 113, 4, 1148, https://doi.org/10.1021/ja00004a014
. [all data]
Paul and Kebarle, 1990
Paul, G.J.C.; Kebarle, P.,
Stabilities in the Gas Phase of the Hydrogen Bonded Complexes, YC6H4OH-X-, of Substituted Phenols, YC6H4OH, with the Halide Anions X-(Cl-, Br-),
Can. J. Chem., 1990, 68, 11, 2070, https://doi.org/10.1139/v90-316
. [all data]
Hiraoka, Mizuse, et al., 1988, 2
Hiraoka, K.; Mizuse, S.; Yamabe, S.,
Solvation of Halide Ions with H2O and CH3CN in the Gas Phase,
J. Phys. Chem., 1988, 92, 13, 3943, https://doi.org/10.1021/j100324a051
. [all data]
Markovich, Perera, et al., 1996
Markovich, G.; Perera, L.; Berkowitz, M.L.; Cheshnovsky, O.,
The Solvation of Cl-, Br-, and I- in Acetonitrile Cluster: Photoelectron Spectroscopy and Molecular Dynamics Simulations.,
J. Chem. Phys., 1996, 105, 7, 2675, https://doi.org/10.1063/1.472131
. [all data]
Yamdagni and Kebarle, 1972
Yamdagni, R.; Kebarle, P.,
Solvation of negative ions by protic and aprotic solvents. Gas phase solvation of halide ions by acetonitrile and water molecules,
J. Am. Chem. Soc., 1972, 94, 2940. [all data]
Bogdanov, Peschke, et al., 1999
Bogdanov, B.; Peschke, M.; Tonner, D.S.; Szulejko, J.E.; McMahon, T.B.,
Stepwise solvation of halides by alcohol molecules in the gas phase,
Int. J. Mass Spectrom., 1999, 187, 707-725, https://doi.org/10.1016/S1387-3806(98)14180-5
. [all data]
Hiraoka and Yamabe, 1991
Hiraoka, K.; Yamabe, S.,
Solvation of Halide Ions with CH3OH in the gas Phase,
Int. J. Mass Spectrom. Ion Proc., 1991, 109, 133, https://doi.org/10.1016/0168-1176(91)85101-Q
. [all data]
Tanabe, Morgon, et al., 1996
Tanabe, F.K.J.; Morgon, N.H.; Riveros, J.M.,
Relative Bromide and Iodide Affinity of Simple Solvent Molecules Determined by FT-ICR,
J. Phys. Chem., 1996, 100, 8, 2862-2866, https://doi.org/10.1021/jp952290p
. [all data]
Hiraoka, Mizure, et al., 1988
Hiraoka, K.; Mizure, S.; Yamabe, S.; Nakatsuji, Y.,
Gas Phase Clustering Reactions of CN- and CH2CN- with MeCN,
Chem. Phys. Lett., 1988, 148, 6, 497, https://doi.org/10.1016/0009-2614(88)80320-8
. [all data]
Davidson, Fehsenfeld, et al., 1977
Davidson, J.A.; Fehsenfeld, F.C.; Howard, C.J.,
The heats of formation of NO3- and NO3- association complexes with HNO3 and HBr,
Int. J. Chem. Kinet., 1977, 9, 17. [all data]
Markovich, Pollack, et al., 1994
Markovich, G.; Pollack, S.; Giniger, R.; Cheshnovsky, O.,
Photoelectron spectroscopy of Cl-, Br-, and I- solvated in water clusters,
J. Chem. Phys., 1994, 101, 11, 9344, https://doi.org/10.1063/1.467965
. [all data]
Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M.,
Study of I-(CO2)n, Br-(CO2)n, and I-(N2O)n clusters by anion photoelectron spectroscopy,
J. Chem. Phys., 1995, 102, 9, 3510, https://doi.org/10.1063/1.468576
. [all data]
Hiraoka, Mizuse, et al., 1987
Hiraoka, K.; Mizuse, S.; Yamabe, S.,
Stability and Structure of Cluster Ions: Halide Ions with CO2,
J. Chem. Phys., 1987, 87, 6, 3647, https://doi.org/10.1063/1.452962
. [all data]
Arnold, Bradforth, et al., 1995, 2
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M.,
Study of halogen carbon dioxide clusters and the fluoroformyloxyl radical by photodetachment of X(-)(CO2) (X=I,Cl,Br) and FCO2-,
J. Chem. Phys., 1995, 102, 9, 3493, https://doi.org/10.1063/1.468575
. [all data]
Li, Ross, et al., 1996
Li, C.; Ross, P.; Szulejko, J.; McMahon, T.B.,
High-Pressure Mass Spectrometric Investigations of the Potential Energy Surfaces of Gas-Phase Sn2 Reactions.,
J. Am. Chem. Soc., 1996, 118, 39, 9360, https://doi.org/10.1021/ja960565o
. [all data]
Dougherty and Roberts, 1974
Dougherty, R.C.; Roberts, J.D.,
SN2 reactions in the gas phase. Nucleophilicity effects,
Org. Mass Spectrom., 1974, 8, 81. [all data]
Hiraoka, Mochizuki, et al., 2008
Hiraoka, K.; Mochizuki, N.; Wada, A.; Okada, H.; Ichikawa, T.; Asakawa, D.; Yazawa, I.,
Gas-phase ion/molecule reactions in C2F4,
Int. J. Mass Spectrom., 2008, 272, 1, 22-28, https://doi.org/10.1016/j.ijms.2007.12.013
. [all data]
Curtiss, Raghavachari, et al., 7374
Curtiss, L.A.; Raghavachari, K.; Redfern, P.C.; Pople, J.A.,
Assesment of Gaussian-3 and density Functional Theories for a larger experimental test set, J. Chem. Phys. 112 (2000), 7374. [all data]
Dougherty, 1974
Dougherty, R.C.,
SN2 reactions in the gas phase. Alkyl group structural effects,
Org. Mass Spectrom., 1974, 8, 85. [all data]
Wada, Kikkawa, et al., 2007
Wada, A.; Kikkawa, A.; Sugiyama, T.; Hiraoka, K.,
Thermochemical Stabilities of the Gas-phase Cluster Ions of Halide Ions with Rare Gas Atoms,
Int. J. Mass Spectrom.., 2007, 267, 1-3, 284-287, https://doi.org/10.1016/j.ijms.2007.02.053
. [all data]
Yourshaw, Lenzer, et al., 1998
Yourshaw, I.; Lenzer, T.; Reiser, G.; Neumark, D.M.,
Zero electron kinetic energy spectroscopy of the KrBr-, XeBr-, and KrCl- anions,
J. Chem. Phys., 1998, 109, 13, 5247-5256, https://doi.org/10.1063/1.477141
. [all data]
Gatland, 1984
Gatland, I.R.,
Determination of Ion-Atom Potentials from Mobility Experiments.
in Swarms of Ions and Electrons In Gases, W. Lindinger, Ed., Springer-Verlag, NY,, 1984, 44. [all data]
Meot-ner, Cybulski, et al., 1988
Meot-ner, M.; Cybulski, S.M.; Scheiner, S.; Liebman, J.F.,
Is CN- Significantly Anisotropic? Comparison of CN- vs. Cl-: Clustering with HCN and Condensed Phase Thermochemistry,
J. Phys. Chem., 1988, 92, 10, 2738, https://doi.org/10.1021/j100321a009
. [all data]
Larson and McMahon, 1984
Larson, J.W.; McMahon, T.B.,
Gas phase bihalide and pseudohalide ions. An ICR determination of hydrogen bond energies in XHY- species (X,Y = F, Cl, Br, CN),
Inorg. Chem., 1984, 23, 2029. [all data]
Caldwell and Kebarle, 1985
Caldwell, G.; Kebarle, P.,
The hydrogen bond energies of the bihalide ions XHX- and YHX-,
Can. J. Chem., 1985, 63, 1399. [all data]
Evans, Keesee, et al., 1987
Evans, D.H.; Keesee, R.G.; Castleman Jr.,
The Association of Ammonia with Halide Ions in the Gas Phase,
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. [all data]
Magnera, Caldwell, et al., 1984
Magnera, T.F.; Caldwell, G.; Sumner, J.; Ikuta, S.; Kebarle, P.,
Solvation of the halide anions in dimethyl sulfoxide. Factors involved in enhanced reactivity of negative ions in dipolar aprotic solvents,
J. Am. Chem. Soc., 1984, 106, 6140. [all data]
Caldwell, Masucci, et al., 1989
Caldwell, G.W.; Masucci, J.A.; Ikonomou, M.G.,
Negative Ion Chemical Ionization Mass Spectrometry - Binding of Molecules to Bromide and Iodide Anions,
Org. Mass Spectrom., 1989, 24, 1, 8, https://doi.org/10.1002/oms.1210240103
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
T Temperature rG°
Free energy of reaction at standard conditions rH°
Enthalpy of reaction at standard conditions rS°
Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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