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Bromine anion


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 101 to 150

Bromine anion + Benzene, 1-nitro-3-(trifluoromethyl)- = (Bromine anion bullet Benzene, 1-nitro-3-(trifluoromethyl)-)

By formula: Br- + C7H4F3NO2 = (Br- bullet C7H4F3NO2)

Quantity Value Units Method Reference Comment
Deltar77.4 ± 7.5kJ/molTDAsPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar93.3J/mol*KPHPMSPaul and Kebarle, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar38. ± 4.2kJ/molTDAsPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K; B

Bromine anion + Bromine = (Bromine anion bullet Bromine)

By formula: Br- + Br2 = (Br- bullet Br2)

Quantity Value Units Method Reference Comment
Deltar127. ± 7.1kJ/molCIDTNizzi, Pommerening, et al., 1998gas phase; B
Deltar141.0kJ/molN/ACheck, Faust, et al., 2001gas phase; Fe-; ; «DELTA»S(EA)=5.8; B
Quantity Value Units Method Reference Comment
Deltar94.14kJ/molN/ACheck, Faust, et al., 2001gas phase; Fe-; ; «DELTA»S(EA)=5.8; B

Bromine anion + Ethanol = C2H6BrO-

By formula: Br- + C2H6O = C2H6BrO-

Quantity Value Units Method Reference Comment
Deltar58.99 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar34.3kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar37. ± 8.4kJ/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

Bromine anion + Isopropyl Alcohol = C3H8BrO-

By formula: Br- + C3H8O = C3H8BrO-

Quantity Value Units Method Reference Comment
Deltar60.25 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar34.9kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar38. ± 8.4kJ/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

(Bromine anion bullet Hydrogen chloride) + Hydrogen chloride = (Bromine anion bullet 2Hydrogen chloride)

By formula: (Br- bullet HCl) + HCl = (Br- bullet 2HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar52.3kJ/molPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Br-)SO2; M
Quantity Value Units Method Reference Comment
Deltar77.0J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Br-)SO2; M

Bromine anion + Krypton = (Bromine anion bullet Krypton)

By formula: Br- + Kr = (Br- bullet Kr)

Quantity Value Units Method Reference Comment
Deltar4.60 ± 0.42kJ/molLPESYourshaw, Lenzer, et al., 1998gas phase; given: 0.0795(.001) eV; B
Deltar<11.3kJ/molTDAsWada, Kikkawa, et al., 2007gas phase; B
Deltar8.37kJ/molMoblGatland, 1984gas phase; B,M

(Bromine anion bullet Carbon disulfide) + Carbon disulfide = (Bromine anion bullet 2Carbon disulfide)

By formula: (Br- bullet CS2) + CS2 = (Br- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar30.5 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar85.4J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.0 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Bromine anion bullet 3Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 4Methyl Alcohol)

By formula: (Br- bullet 3CH4O) + CH4O = (Br- bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar97.1J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar13. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 4Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 5Methyl Alcohol)

By formula: (Br- bullet 4CH4O) + CH4O = (Br- bullet 5CH4O)

Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.6 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 5Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 6Methyl Alcohol)

By formula: (Br- bullet 5CH4O) + CH4O = (Br- bullet 6CH4O)

Quantity Value Units Method Reference Comment
Deltar38. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar98.7J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.8 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 6Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 7Methyl Alcohol)

By formula: (Br- bullet 6CH4O) + CH4O = (Br- bullet 7CH4O)

Quantity Value Units Method Reference Comment
Deltar36. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar95.8J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.1 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 7Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 8Methyl Alcohol)

By formula: (Br- bullet 7CH4O) + CH4O = (Br- bullet 8CH4O)

Quantity Value Units Method Reference Comment
Deltar35. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar96.7J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.3 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 2Hydrogen cyanide) + Hydrogen cyanide = (Bromine anion bullet 3Hydrogen cyanide)

By formula: (Br- bullet 2CHN) + CHN = (Br- bullet 3CHN)

Quantity Value Units Method Reference Comment
Deltar53.6 ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar91.6J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.4kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Bromine anion bullet 3Hydrogen cyanide) + Hydrogen cyanide = (Bromine anion bullet 4Hydrogen cyanide)

By formula: (Br- bullet 3CHN) + CHN = (Br- bullet 4CHN)

Quantity Value Units Method Reference Comment
Deltar43.5 ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar92.5J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar15.9kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

Bromine anion + Sulfur dioxide = (Bromine anion bullet Sulfur dioxide)

By formula: Br- + O2S = (Br- bullet O2S)

Quantity Value Units Method Reference Comment
Deltar80.8 ± 8.4kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar92.0J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar53. ± 11.kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B

(Bromine anion bullet 4Hydrogen cyanide) + Hydrogen cyanide = (Bromine anion bullet 5Hydrogen cyanide)

By formula: (Br- bullet 4CHN) + CHN = (Br- bullet 5CHN)

Quantity Value Units Method Reference Comment
Deltar34. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar77.4J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar10.9kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Bromine anion bullet Hydrogen cyanide) + Hydrogen cyanide = (Bromine anion bullet 2Hydrogen cyanide)

By formula: (Br- bullet CHN) + CHN = (Br- bullet 2CHN)

Quantity Value Units Method Reference Comment
Deltar68.2 ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar95.0J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar39.7kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

Bromine anion + Benzene, hexafluoro- = (Bromine anion bullet Benzene, hexafluoro-)

By formula: Br- + C6F6 = (Br- bullet C6F6)

Quantity Value Units Method Reference Comment
Deltar58.2 ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar81.2J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar34. ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

Bromine anion + Carbon disulfide = (Bromine anion bullet Carbon disulfide)

By formula: Br- + CS2 = (Br- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar34.7 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar54.4J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar18. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

Bromine anion + hydrogen fluoride = (Bromine anion bullet hydrogen fluoride)

By formula: Br- + HF = (Br- bullet HF)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar71.1 ± 8.4kJ/molEstLarson and McMahon, 1984gas phase; Extrapolated from other bihalide data; B
Deltar71.1kJ/molHPMSCaldwell, Masucci, et al., 1989gas phase; M

(Bromine anion bullet Hydrogen bromide) + Hydrogen bromide = (Bromine anion bullet 2Hydrogen bromide)

By formula: (Br- bullet HBr) + HBr = (Br- bullet 2HBr)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar46.0kJ/molPHPMSCaldwell and Kebarle, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar71.1J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M

Bromine anion + Propane, 1-bromo- = (Bromine anion bullet Propane, 1-bromo-)

By formula: Br- + C3H7Br = (Br- bullet C3H7Br)

Quantity Value Units Method Reference Comment
Deltar48.53kJ/molTDAsDougherty, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar82.8J/mol*KHPMSDougherty, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.8kJ/molTDAsDougherty, 1974gas phase; B

Bromine anion + Propane, 1-bromo-2,2-dimethyl- = (Bromine anion bullet Propane, 1-bromo-2,2-dimethyl-)

By formula: Br- + C5H11Br = (Br- bullet C5H11Br)

Quantity Value Units Method Reference Comment
Deltar60.25kJ/molTDAsDougherty, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KHPMSDougherty, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar28.9kJ/molTDAsDougherty, 1974gas phase; B

Bromine anion + Acetophenone, 4'-hydroxy- = (Bromine anion bullet Acetophenone, 4'-hydroxy-)

By formula: Br- + C8H8O2 = (Br- bullet C8H8O2)

Quantity Value Units Method Reference Comment
Deltar105. ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B
Quantity Value Units Method Reference Comment
Deltar64.4 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Bromine anion + Propane, 1-bromo-2-methyl- = (Bromine anion bullet Propane, 1-bromo-2-methyl-)

By formula: Br- + C4H9Br = (Br- bullet C4H9Br)

Quantity Value Units Method Reference Comment
Deltar53.97kJ/molTDAsDougherty, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar91.2J/mol*KHPMSDougherty, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.8kJ/molTDAsDougherty, 1974gas phase; B

(Bromine anion bullet 10Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 11Carbon dioxide)

By formula: (Br- bullet 10CO2) + CO2 = (Br- bullet 11CO2)

Quantity Value Units Method Reference Comment
Deltar2. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 9Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 10Carbon dioxide)

By formula: (Br- bullet 9CO2) + CO2 = (Br- bullet 10CO2)

Quantity Value Units Method Reference Comment
Deltar7.5 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 14Water) + Water = (Bromine anion bullet 15Water)

By formula: (Br- bullet 14H2O) + H2O = (Br- bullet 15H2O)

Quantity Value Units Method Reference Comment
Deltar-2. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 2Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 3Carbon dioxide)

By formula: (Br- bullet 2CO2) + CO2 = (Br- bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar21. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 3Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 4Carbon dioxide)

By formula: (Br- bullet 3CO2) + CO2 = (Br- bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar22. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 4Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 5Carbon dioxide)

By formula: (Br- bullet 4CO2) + CO2 = (Br- bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar18. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 5Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 6Carbon dioxide)

By formula: (Br- bullet 5CO2) + CO2 = (Br- bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar17. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 6Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 7Carbon dioxide)

By formula: (Br- bullet 6CO2) + CO2 = (Br- bullet 7CO2)

Quantity Value Units Method Reference Comment
Deltar15. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 7Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 8Carbon dioxide)

By formula: (Br- bullet 7CO2) + CO2 = (Br- bullet 8CO2)

Quantity Value Units Method Reference Comment
Deltar15. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 8Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 9Carbon dioxide)

By formula: (Br- bullet 8CO2) + CO2 = (Br- bullet 9CO2)

Quantity Value Units Method Reference Comment
Deltar7.5 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 10Water) + Water = (Bromine anion bullet 11Water)

By formula: (Br- bullet 10H2O) + H2O = (Br- bullet 11H2O)

Quantity Value Units Method Reference Comment
Deltar6.7 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 11Water) + Water = (Bromine anion bullet 12Water)

By formula: (Br- bullet 11H2O) + H2O = (Br- bullet 12H2O)

Quantity Value Units Method Reference Comment
Deltar10. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 12Water) + Water = (Bromine anion bullet 13Water)

By formula: (Br- bullet 12H2O) + H2O = (Br- bullet 13H2O)

Quantity Value Units Method Reference Comment
Deltar7.5 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 13Water) + Water = (Bromine anion bullet 14Water)

By formula: (Br- bullet 13H2O) + H2O = (Br- bullet 14H2O)

Quantity Value Units Method Reference Comment
Deltar13. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 15Water) + Water = (Bromine anion bullet 16Water)

By formula: (Br- bullet 15H2O) + H2O = (Br- bullet 16H2O)

Quantity Value Units Method Reference Comment
Deltar9.6 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 9Water) + Water = (Bromine anion bullet 10Water)

By formula: (Br- bullet 9H2O) + H2O = (Br- bullet 10H2O)

Quantity Value Units Method Reference Comment
Deltar6.7 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 7Water) + Water = (Bromine anion bullet 8Water)

By formula: (Br- bullet 7H2O) + H2O = (Br- bullet 8H2O)

Quantity Value Units Method Reference Comment
Deltar6.7 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 8Water) + Water = (Bromine anion bullet 9Water)

By formula: (Br- bullet 8H2O) + H2O = (Br- bullet 9H2O)

Quantity Value Units Method Reference Comment
Deltar3. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

Bromine anion + Propane, 2-chloro-2-methyl- = (Bromine anion bullet Propane, 2-chloro-2-methyl-)

By formula: Br- + C4H9Cl = (Br- bullet C4H9Cl)

Quantity Value Units Method Reference Comment
Deltar58.2 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar27.6 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Bromine anion + n-Propyl chloride = (Bromine anion bullet n-Propyl chloride)

By formula: Br- + C3H7Cl = (Br- bullet C3H7Cl)

Quantity Value Units Method Reference Comment
Deltar50.6 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar24.9 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Bromine anion + Cyclopentene, octafluoro- = C5BrF8-

By formula: Br- + C5F8 = C5BrF8-

Quantity Value Units Method Reference Comment
Deltar53.1 ± 1.3kJ/molTDAsHiraoka, Fujita, et al., 1905gas phase; B
Quantity Value Units Method Reference Comment
Deltar29.5 ± 1.3kJ/molTDAsHiraoka, Fujita, et al., 1905gas phase; B

(Bromine anion bullet Hydrogen bromide) + Sulfur dioxide = (Bromine anion bullet Sulfur dioxide bullet Hydrogen bromide)

By formula: (Br- bullet HBr) + O2S = (Br- bullet O2S bullet HBr)

Quantity Value Units Method Reference Comment
Deltar45.6kJ/molPHPMSCaldwell and Kebarle, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar79.1J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M

Bromine anion + Chloromethane = (Bromine anion bullet Chloromethane)

By formula: Br- + CH3Cl = (Br- bullet CH3Cl)

Quantity Value Units Method Reference Comment
Deltar45.6 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar20.3 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Bromine anion + Ethyl Chloride = (Bromine anion bullet Ethyl Chloride)

By formula: Br- + C2H5Cl = (Br- bullet C2H5Cl)

Quantity Value Units Method Reference Comment
Deltar46.9 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar22.4 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Bromine anion + Propane, 2-chloro- = (Bromine anion bullet Propane, 2-chloro-)

By formula: Br- + C3H7Cl = (Br- bullet C3H7Cl)

Quantity Value Units Method Reference Comment
Deltar51.9 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar26.2 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Paul and Kebarle, 1991
Paul, G.J.C.; Kebarle, P., Stabilities of Complexes of Br- with Substituted Benzenes (SB) Based on Determinations of the Gas-Phase Equilibria Br- + SB = (BrSB)-, J. Am. Chem. Soc., 1991, 113, 4, 1148, https://doi.org/10.1021/ja00004a014 . [all data]

Nizzi, Pommerening, et al., 1998
Nizzi, K.E.; Pommerening, C.A.; Sunderlin, L.S., Gas-phase thermochemistry of polyhalide anions, J. Phys. Chem. A, 1998, 102, 39, 7674-7679, https://doi.org/10.1021/jp9824508 . [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Bogdanov, Peschke, et al., 1999
Bogdanov, B.; Peschke, M.; Tonner, D.S.; Szulejko, J.E.; McMahon, T.B., Stepwise solvation of halides by alcohol molecules in the gas phase, Int. J. Mass Spectrom., 1999, 187, 707-725, https://doi.org/10.1016/S1387-3806(98)14180-5 . [all data]

Tanabe, Morgon, et al., 1996
Tanabe, F.K.J.; Morgon, N.H.; Riveros, J.M., Relative Bromide and Iodide Affinity of Simple Solvent Molecules Determined by FT-ICR, J. Phys. Chem., 1996, 100, 8, 2862-2866, https://doi.org/10.1021/jp952290p . [all data]

Hiraoka, Mizure, et al., 1988
Hiraoka, K.; Mizure, S.; Yamabe, S.; Nakatsuji, Y., Gas Phase Clustering Reactions of CN- and CH2CN- with MeCN, Chem. Phys. Lett., 1988, 148, 6, 497, https://doi.org/10.1016/0009-2614(88)80320-8 . [all data]

Caldwell and Kebarle, 1985
Caldwell, G.; Kebarle, P., The hydrogen bond energies of the bihalide ions XHX- and YHX-, Can. J. Chem., 1985, 63, 1399. [all data]

Yourshaw, Lenzer, et al., 1998
Yourshaw, I.; Lenzer, T.; Reiser, G.; Neumark, D.M., Zero electron kinetic energy spectroscopy of the KrBr-, XeBr-, and KrCl- anions, J. Chem. Phys., 1998, 109, 13, 5247-5256, https://doi.org/10.1063/1.477141 . [all data]

Wada, Kikkawa, et al., 2007
Wada, A.; Kikkawa, A.; Sugiyama, T.; Hiraoka, K., Thermochemical Stabilities of the Gas-phase Cluster Ions of Halide Ions with Rare Gas Atoms, Int. J. Mass Spectrom.., 2007, 267, 1-3, 284-287, https://doi.org/10.1016/j.ijms.2007.02.053 . [all data]

Gatland, 1984
Gatland, I.R., Determination of Ion-Atom Potentials from Mobility Experiments. in Swarms of Ions and Electrons In Gases, W. Lindinger, Ed., Springer-Verlag, NY,, 1984, 44. [all data]

Hiraoka, Fujimaki, et al., 1993
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S., Bond Strengths of the Gas-Phase Cluster Ions X-(CS2)n (X = F, Cl, Br and I), Chem. Phys. Lett., 1993, 208, 5-6, 491, https://doi.org/10.1016/0009-2614(93)87178-6 . [all data]

Hiraoka and Yamabe, 1991
Hiraoka, K.; Yamabe, S., Solvation of Halide Ions with CH3OH in the gas Phase, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 133, https://doi.org/10.1016/0168-1176(91)85101-Q . [all data]

Meot-ner, Cybulski, et al., 1988
Meot-ner, M.; Cybulski, S.M.; Scheiner, S.; Liebman, J.F., Is CN- Significantly Anisotropic? Comparison of CN- vs. Cl-: Clustering with HCN and Condensed Phase Thermochemistry, J. Phys. Chem., 1988, 92, 10, 2738, https://doi.org/10.1021/j100321a009 . [all data]

Hiraoka, Mizuse, et al., 1987
Hiraoka, K.; Mizuse, S.; Yamabe, S., High Symmetric Structure of the Gas Phase Ion Cluster X-..C6F6 (X = Cl, Br, I), J. Phys. Chem., 1987, 91, 20, 5294, https://doi.org/10.1021/j100304a032 . [all data]

Larson and McMahon, 1984
Larson, J.W.; McMahon, T.B., Gas phase bihalide and pseudohalide ions. An ICR determination of hydrogen bond energies in XHY- species (X,Y = F, Cl, Br, CN), Inorg. Chem., 1984, 23, 2029. [all data]

Caldwell, Masucci, et al., 1989
Caldwell, G.W.; Masucci, J.A.; Ikonomou, M.G., Negative Ion Chemical Ionization Mass Spectrometry - Binding of Molecules to Bromide and Iodide Anions, Org. Mass Spectrom., 1989, 24, 1, 8, https://doi.org/10.1002/oms.1210240103 . [all data]

Dougherty, 1974
Dougherty, R.C., SN2 reactions in the gas phase. Alkyl group structural effects, Org. Mass Spectrom., 1974, 8, 85. [all data]

Paul and Kebarle, 1990
Paul, G.J.C.; Kebarle, P., Stabilities in the Gas Phase of the Hydrogen Bonded Complexes, YC6H4OH-X-, of Substituted Phenols, YC6H4OH, with the Halide Anions X-(Cl-, Br-), Can. J. Chem., 1990, 68, 11, 2070, https://doi.org/10.1139/v90-316 . [all data]

Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of I-(CO2)n, Br-(CO2)n, and I-(N2O)n clusters by anion photoelectron spectroscopy, J. Chem. Phys., 1995, 102, 9, 3510, https://doi.org/10.1063/1.468576 . [all data]

Markovich, Pollack, et al., 1994
Markovich, G.; Pollack, S.; Giniger, R.; Cheshnovsky, O., Photoelectron spectroscopy of Cl-, Br-, and I- solvated in water clusters, J. Chem. Phys., 1994, 101, 11, 9344, https://doi.org/10.1063/1.467965 . [all data]

Li, Ross, et al., 1996
Li, C.; Ross, P.; Szulejko, J.; McMahon, T.B., High-Pressure Mass Spectrometric Investigations of the Potential Energy Surfaces of Gas-Phase Sn2 Reactions., J. Am. Chem. Soc., 1996, 118, 39, 9360, https://doi.org/10.1021/ja960565o . [all data]

Hiraoka, Fujita, et al., 1905
Hiraoka, K.; Fujita, K.; Ishida, M.; Ichikawa, T.; Okada, H.; Hiizumi, K.; Wada, A.; Takao, K.; Yamabe, S.; Tsuchida, N., Gas-phase Ion/Molecule Reactions in C5F8, J. Phys. Chem. A (2005), 1905, 109, 6, 1049-1056., https://doi.org/10.1021/jp040251k . [all data]


Notes

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