Bromine anion
- Formula: Br-
- Molecular weight: 79.905
- IUPAC Standard InChI:
- InChI=1S/BrH/h1H/p-1
- Download the identifier in a file.
- IUPAC Standard InChIKey: CPELXLSAUQHCOX-UHFFFAOYSA-M
- CAS Registry Number: 24959-67-9
- Chemical structure:
This structure is also available as a 2d Mol file - Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Gas phase thermochemistry data
- Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 100, reactions 151 to 185
- Gas phase ion energetics data
- Ion clustering data
- Options:
Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 101 to 150
By formula: Br- + C7H4F3NO2 = (Br- C7H4F3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 77.4 ± 7.5 | kJ/mol | TDAs | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 93.3 | J/mol*K | PHPMS | Paul and Kebarle, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 38. ± 4.2 | kJ/mol | TDAs | Paul and Kebarle, 1991 | gas phase; «DELTA»Gaff at 423 K; B |
By formula: Br- + Br2 = (Br- Br2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 127. ± 7.1 | kJ/mol | CIDT | Nizzi, Pommerening, et al., 1998 | gas phase; B |
![]() | 141.0 | kJ/mol | N/A | Check, Faust, et al., 2001 | gas phase; Fe-; ; «DELTA»S(EA)=5.8; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 94.14 | kJ/mol | N/A | Check, Faust, et al., 2001 | gas phase; Fe-; ; «DELTA»S(EA)=5.8; B |
+
= C2H6BrO-
By formula: Br- + C2H6O = C2H6BrO-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 58.99 ± 0.84 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 34.3 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 37. ± 8.4 | kJ/mol | IMRE | Tanabe, Morgon, et al., 1996 | gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B |
+
= C3H8BrO-
By formula: Br- + C3H8O = C3H8BrO-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 60.25 ± 0.84 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 34.9 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 38. ± 8.4 | kJ/mol | IMRE | Tanabe, Morgon, et al., 1996 | gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B |
By formula: (Br- HCl) + HCl = (Br-
2HCl)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 52.3 | kJ/mol | PHPMS | Caldwell and Kebarle, 1985 | gas phase; switching reaction(Br-)SO2; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 77.0 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; switching reaction(Br-)SO2; M |
By formula: Br- + Kr = (Br- Kr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 4.60 ± 0.42 | kJ/mol | LPES | Yourshaw, Lenzer, et al., 1998 | gas phase; given: 0.0795(.001) eV; B |
![]() | <11.3 | kJ/mol | TDAs | Wada, Kikkawa, et al., 2007 | gas phase; B |
![]() | 8.37 | kJ/mol | Mobl | Gatland, 1984 | gas phase; B,M |
By formula: (Br- CS2) + CS2 = (Br-
2CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 30.5 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 85.4 | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1993 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.0 ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B |
By formula: (Br- 3CH4O) + CH4O = (Br-
4CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 97.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 13. ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (Br- 4CH4O) + CH4O = (Br-
5CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9.6 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (Br- 5CH4O) + CH4O = (Br-
6CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 98.7 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.8 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (Br- 6CH4O) + CH4O = (Br-
7CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.8 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.1 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (Br- 7CH4O) + CH4O = (Br-
8CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 35. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 96.7 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 6.3 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (Br- 2CHN) + CHN = (Br-
3CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.6 ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 91.6 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26.4 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (Br- 3CHN) + CHN = (Br-
4CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.5 ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92.5 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 15.9 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: Br- + O2S = (Br- O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 80.8 ± 8.4 | kJ/mol | TDAs | Caldwell and Kebarle, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92.0 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 53. ± 11. | kJ/mol | TDAs | Caldwell and Kebarle, 1985 | gas phase; B |
By formula: (Br- 4CHN) + CHN = (Br-
5CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 34. ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 77.4 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10.9 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (Br- CHN) + CHN = (Br-
2CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 68.2 ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.0 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 39.7 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: Br- + C6F6 = (Br- C6F6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 58.2 ± 4.2 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 81.2 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 34. ± 6.7 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: Br- + CS2 = (Br- CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 34.7 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 54.4 | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1993 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18. ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B |
By formula: Br- + HF = (Br- HF)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 71.1 ± 8.4 | kJ/mol | Est | Larson and McMahon, 1984 | gas phase; Extrapolated from other bihalide data; B |
![]() | 71.1 | kJ/mol | HPMS | Caldwell, Masucci, et al., 1989 | gas phase; M |
By formula: (Br- HBr) + HBr = (Br-
2HBr)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.0 | kJ/mol | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 71.1 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
By formula: Br- + C3H7Br = (Br- C3H7Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 48.53 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 82.8 | J/mol*K | HPMS | Dougherty, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23.8 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B |
By formula: Br- + C5H11Br = (Br- C5H11Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 60.25 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | HPMS | Dougherty, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 28.9 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B |
By formula: Br- + C8H8O2 = (Br- C8H8O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 105. ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 64.4 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
By formula: Br- + C4H9Br = (Br- C4H9Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.97 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 91.2 | J/mol*K | HPMS | Dougherty, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26.8 | kJ/mol | TDAs | Dougherty, 1974 | gas phase; B |
By formula: (Br- 10CO2) + CO2 = (Br-
11CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 2. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 9CO2) + CO2 = (Br-
10CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.5 ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 14H2O) + H2O = (Br-
15H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | -2. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 2CO2) + CO2 = (Br-
3CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 21. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 3CO2) + CO2 = (Br-
4CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 22. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 4CO2) + CO2 = (Br-
5CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 18. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 5CO2) + CO2 = (Br-
6CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 17. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 6CO2) + CO2 = (Br-
7CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 7CO2) + CO2 = (Br-
8CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 8CO2) + CO2 = (Br-
9CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.5 ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (Br- 10H2O) + H2O = (Br-
11H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.7 ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 11H2O) + H2O = (Br-
12H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 12H2O) + H2O = (Br-
13H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.5 ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 13H2O) + H2O = (Br-
14H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 15H2O) + H2O = (Br-
16H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.6 ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 9H2O) + H2O = (Br-
10H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.7 ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 7H2O) + H2O = (Br-
8H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.7 ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (Br- 8H2O) + H2O = (Br-
9H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 3. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: Br- + C4H9Cl = (Br- C4H9Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 58.2 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27.6 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
By formula: Br- + C3H7Cl = (Br- C3H7Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 50.6 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24.9 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
+
= C5BrF8-
By formula: Br- + C5F8 = C5BrF8-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.1 ± 1.3 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 29.5 ± 1.3 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase; B |
By formula: (Br- HBr) + O2S = (Br-
O2S
HBr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 45.6 | kJ/mol | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 79.1 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
By formula: Br- + CH3Cl = (Br- CH3Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 45.6 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.3 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
By formula: Br- + C2H5Cl = (Br- C2H5Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.9 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 22.4 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
By formula: Br- + C3H7Cl = (Br- C3H7Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.9 ± 4.2 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26.2 ± 0.84 | kJ/mol | TDAs | Li, Ross, et al., 1996 | gas phase; B |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Paul and Kebarle, 1991
Paul, G.J.C.; Kebarle, P.,
Stabilities of Complexes of Br- with Substituted Benzenes (SB) Based on Determinations of the Gas-Phase Equilibria Br- + SB = (BrSB)-,
J. Am. Chem. Soc., 1991, 113, 4, 1148, https://doi.org/10.1021/ja00004a014
. [all data]
Nizzi, Pommerening, et al., 1998
Nizzi, K.E.; Pommerening, C.A.; Sunderlin, L.S.,
Gas-phase thermochemistry of polyhalide anions,
J. Phys. Chem. A, 1998, 102, 39, 7674-7679, https://doi.org/10.1021/jp9824508
. [all data]
Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S.,
Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements,
J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l
. [all data]
Bogdanov, Peschke, et al., 1999
Bogdanov, B.; Peschke, M.; Tonner, D.S.; Szulejko, J.E.; McMahon, T.B.,
Stepwise solvation of halides by alcohol molecules in the gas phase,
Int. J. Mass Spectrom., 1999, 187, 707-725, https://doi.org/10.1016/S1387-3806(98)14180-5
. [all data]
Tanabe, Morgon, et al., 1996
Tanabe, F.K.J.; Morgon, N.H.; Riveros, J.M.,
Relative Bromide and Iodide Affinity of Simple Solvent Molecules Determined by FT-ICR,
J. Phys. Chem., 1996, 100, 8, 2862-2866, https://doi.org/10.1021/jp952290p
. [all data]
Hiraoka, Mizure, et al., 1988
Hiraoka, K.; Mizure, S.; Yamabe, S.; Nakatsuji, Y.,
Gas Phase Clustering Reactions of CN- and CH2CN- with MeCN,
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Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
rG°
Free energy of reaction at standard conditions rH°
Enthalpy of reaction at standard conditions rS°
Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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