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Bromine anion


Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar39.075cal/mol*KReviewChase, 1998Data last reviewed in June, 1982

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

(Bromine anion bullet Water) + Water = (Bromine anion bullet 2Water)

By formula: (Br- bullet H2O) + H2O = (Br- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar11.60 ± 0.30kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar12.20kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Deltar12.3 ± 1.0kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar12.3 ± 1.0kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar18.0cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar22.9cal/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.2 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar5.4 ± 1.4kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar5.40kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Deltar5.7 ± 2.0kcal/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Bromine anion bullet 2Water) + Water = (Bromine anion bullet 3Water)

By formula: (Br- bullet 2H2O) + H2O = (Br- bullet 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar11.40 ± 0.30kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar6.90kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Deltar11.5 ± 1.0kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar11.5 ± 1.0kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.5cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar24.8cal/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.7 ± 1.1kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar4.1 ± 1.4kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar4.10kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Deltar4.4 ± 2.0kcal/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Bromine anion + Water = (Bromine anion bullet Water)

By formula: Br- + H2O = (Br- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar12.70kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Deltar11.70 ± 0.40kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar12.60kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Deltar12.7kcal/molHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar14.7cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar18.4cal/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Deltar19.8cal/mol*KMSBurdett and Hayhurst, 1982gas phase; FLAME SOURCE, 1600 K; M
Quantity Value Units Method Reference Comment
Deltar7.30 ± 0.80kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar7.0 ± 2.8kcal/molTDAsBurdett and Hayhurst, 1982gas phase; B
Deltar7.0 ± 2.0kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B

Bromine anion + Benzaldehyde, 4-hydroxy- = (Bromine anion bullet Benzaldehyde, 4-hydroxy-)

By formula: Br- + C7H6O2 = (Br- bullet C7H6O2)

Quantity Value Units Method Reference Comment
Deltar25.8 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar16.1 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
15.4423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
16.1423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Acetonitrile = (Bromine anion bullet Acetonitrile)

By formula: Br- + C2H3N = (Br- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar14.3 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar12.10 ± 0.40kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar12.90 ± 0.40kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar12.9 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Deltar12.9kcal/molHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar12.2cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar16.5cal/mol*KHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.70 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar8.8 ± 2.0kcal/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B
Deltar9.20 ± 0.70kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar8.0 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

Bromine anion + Benzene, (trifluoromethyl)- = (Bromine anion bullet Benzene, (trifluoromethyl)-)

By formula: Br- + C7H5F3 = (Br- bullet C7H5F3)

Quantity Value Units Method Reference Comment
Deltar12.6 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B
Deltar25.7kcal/molPHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar4.1 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
16.0423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Phenol = (Bromine anion bullet Phenol)

By formula: Br- + C6H6O = (Br- bullet C6H6O)

Quantity Value Units Method Reference Comment
Deltar20.8 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Deltar19.6kcal/molPHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar11.1 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
11.1423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Hydrogen bromide = (Bromine anion bullet Hydrogen bromide)

By formula: Br- + HBr = (Br- bullet HBr)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar20.6 ± 2.0kcal/molTDAsCaldwell and Kebarle, 1985gas phase; B,M
Deltar17.5kcal/molFADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr); DG>, «DELTA»rH>; M
Quantity Value Units Method Reference Comment
Deltar22.3cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M
Deltar22.cal/mol*KFADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr); DG>, «DELTA»rH>; M
Quantity Value Units Method Reference Comment
Deltar13.9 ± 2.6kcal/molTDAsCaldwell and Kebarle, 1985gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
9.4367.FADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr); DG>, «DELTA»rH>; M

(Bromine anion bullet 3Water) + Water = (Bromine anion bullet 4Water)

By formula: (Br- bullet 3H2O) + H2O = (Br- bullet 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar11.00 ± 0.20kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar6.2 ± 2.3kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Deltar10.9 ± 1.0kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar26.2cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar26.8cal/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.10 ± 0.70kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar2.90kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Deltar3.3 ± 2.0kcal/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Bromine anion + Hydrogen cation = Hydrogen bromide

By formula: Br- + H+ = HBr

Quantity Value Units Method Reference Comment
Deltar323.540 ± 0.050kcal/molD-EABlondel, Cacciani, et al., 1989gas phase; reported: 27129.170±0.015 cm-1; B
Deltar323.4 ± 2.1kcal/molG+TSTaft and Bordwell, 1988gas phase; B
Deltar320.60kcal/molN/ACheck, Faust, et al., 2001gas phase; F-; ; «DELTA»S(acid)=19.2; «DELTA»S(EA)=6.4; B
Quantity Value Units Method Reference Comment
Deltar318.30 ± 0.15kcal/molH-TSBlondel, Cacciani, et al., 1989gas phase; reported: 27129.170±0.015 cm-1; B
Deltar318.2 ± 2.0kcal/molIMRETaft and Bordwell, 1988gas phase; B
Deltar315.40kcal/molN/ACheck, Faust, et al., 2001gas phase; F-; ; «DELTA»S(acid)=19.2; «DELTA»S(EA)=6.4; B

Bromine anion + Benzene, 1-methyl-2-nitro- = (Bromine anion bullet Benzene, 1-methyl-2-nitro-)

By formula: Br- + C7H7NO2 = (Br- bullet C7H7NO2)

Quantity Value Units Method Reference Comment
Deltar15.5 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.1 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-methyl-4-nitro- = (Bromine anion bullet Benzene, 1-methyl-4-nitro-)

By formula: Br- + C7H7NO2 = (Br- bullet C7H7NO2)

Quantity Value Units Method Reference Comment
Deltar16.2 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.8 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.8423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + 3,5-Dinitrobenzotrifluoride = (Bromine anion bullet 3,5-Dinitrobenzotrifluoride)

By formula: Br- + C7H3F3N2O4 = (Br- bullet C7H3F3N2O4)

Quantity Value Units Method Reference Comment
Deltar19.8 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; 3,5-dinitrobenzofluoride, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar10.4 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.4423.PHPMSPaul and Kebarle, 1991gas phase; 3,5-dinitrobenzofluoride, Entropy change calculated or estimated; M

Bromine anion + Benzonitrile, 3,5-dinitro- = (Bromine anion bullet Benzonitrile, 3,5-dinitro-)

By formula: Br- + C7H3N3O4 = (Br- bullet C7H3N3O4)

Quantity Value Units Method Reference Comment
Deltar21.6 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; 3,5-dinitrobenzonitrile, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar12.2 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
12.2423.PHPMSPaul and Kebarle, 1991gas phase; 3,5-dinitrobenzonitrile, Entropy change calculated or estimated; M

Bromine anion + 3,5-Bis(trifluoromethyl)nitrobenzene = (Bromine anion bullet 3,5-Bis(trifluoromethyl)nitrobenzene)

By formula: Br- + C8H3F6NO2 = (Br- bullet C8H3F6NO2)

Quantity Value Units Method Reference Comment
Deltar17.6 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; 3,5-(CF3)-nitrobenzene, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar8.2 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
8.2423.PHPMSPaul and Kebarle, 1991gas phase; 3,5-(CF3)-nitrobenzene, Entropy change calculated or estimated; M

Bromine anion + Anisole = (Bromine anion bullet Anisole)

By formula: Br- + C7H8O = (Br- bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar11.8 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar3.3 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.3423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, chloro- = (Bromine anion bullet Benzene, chloro-)

By formula: Br- + C6H5Cl = (Br- bullet C6H5Cl)

Quantity Value Units Method Reference Comment
Deltar11.1 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar2.6 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
2.6423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzenamine, N,N-dimethyl- = (Bromine anion bullet Benzenamine, N,N-dimethyl-)

By formula: Br- + C8H11N = (Br- bullet C8H11N)

Quantity Value Units Method Reference Comment
Deltar11.7 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar3.2 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.2423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, fluoro- = (Bromine anion bullet Benzene, fluoro-)

By formula: Br- + C6H5F = (Br- bullet C6H5F)

Quantity Value Units Method Reference Comment
Deltar10.6 ± 1.6kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar2.1 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
2.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Toluene = (Bromine anion bullet Toluene)

By formula: Br- + C7H8 = (Br- bullet C7H8)

Quantity Value Units Method Reference Comment
Deltar8.6 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar0.1 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
0.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, (trichloromethyl)- = (Bromine anion bullet Benzene, (trichloromethyl)-)

By formula: Br- + C7H5Cl3 = (Br- bullet C7H5Cl3)

Quantity Value Units Method Reference Comment
Deltar12.4 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar3.9 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.9423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Acetophenone = (Bromine anion bullet Acetophenone)

By formula: Br- + C8H8O = (Br- bullet C8H8O)

Quantity Value Units Method Reference Comment
Deltar14.1 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar5.6 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.6423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

(Bromine anion bullet 3Acetonitrile) + Acetonitrile = (Bromine anion bullet 4Acetonitrile)

By formula: (Br- bullet 3C2H3N) + C2H3N = (Br- bullet 4C2H3N)

Quantity Value Units Method Reference Comment
Deltar8.70 ± 0.30kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar8.50 ± 0.80kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar5.50kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.6cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar10.9cal/mol*KHPMSYamdagni and Kebarle, 1972gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar2.8 ± 1.2kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar2.20kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

Bromine anion + Phenol, 4-nitro- = (Bromine anion bullet Phenol, 4-nitro-)

By formula: Br- + C6H5NO3 = (Br- bullet C6H5NO3)

Quantity Value Units Method Reference Comment
Deltar28.4 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar18.7 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
18.7423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Benzaldehyde, 3-hydroxy- = (Bromine anion bullet Benzaldehyde, 3-hydroxy-)

By formula: Br- + C7H6O2 = (Br- bullet C7H6O2)

Quantity Value Units Method Reference Comment
Deltar25.2 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar15.5 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
15.5423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Phenol, 4-chloro- = (Bromine anion bullet Phenol, 4-chloro-)

By formula: Br- + C6H5ClO = (Br- bullet C6H5ClO)

Quantity Value Units Method Reference Comment
Deltar24.4 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar14.7 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
14.7423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Phenol, 3-chloro- = (Bromine anion bullet Phenol, 3-chloro-)

By formula: Br- + C6H5ClO = (Br- bullet C6H5ClO)

Quantity Value Units Method Reference Comment
Deltar24.1 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar14.4 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
14.4423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-fluoro-2-nitro- = (Bromine anion bullet Benzene, 1-fluoro-2-nitro-)

By formula: Br- + C6H4FNO2 = (Br- bullet C6H4FNO2)

Quantity Value Units Method Reference Comment
Deltar17.6 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar8.2 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
8.2423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + 4-(Trifluoromethyl)-phenol = (Bromine anion bullet 4-(Trifluoromethyl)-phenol)

By formula: Br- + CF3C6H4OH = (Br- bullet CF3C6H4OH)

Quantity Value Units Method Reference Comment
Deltar26.6 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar16.9 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
16.9423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Benzene, 1,2-dinitro- = (Bromine anion bullet Benzene, 1,2-dinitro-)

By formula: Br- + C6H4N2O4 = (Br- bullet C6H4N2O4)

Quantity Value Units Method Reference Comment
Deltar21.0 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar11.6 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.6423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 3-nitro- = (Bromine anion bullet Phenol, 3-nitro-)

By formula: Br- + C6H5NO3 = (Br- bullet C6H5NO3)

Quantity Value Units Method Reference Comment
Deltar27.4 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar17.7 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
17.7423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Benzonitrile, 2-hydroxy- = (Bromine anion bullet Benzonitrile, 2-hydroxy-)

By formula: Br- + C7H5NO = (Br- bullet C7H5NO)

Quantity Value Units Method Reference Comment
Deltar27.0 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar17.3 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
17.3423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Benzonitrile, 2-nitro- = (Bromine anion bullet Benzonitrile, 2-nitro-)

By formula: Br- + C7H4N2O2 = (Br- bullet C7H4N2O2)

Quantity Value Units Method Reference Comment
Deltar20.9 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar11.5 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.5423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzonitrile, 3-nitro- = (Bromine anion bullet Benzonitrile, 3-nitro-)

By formula: Br- + C7H4N2O2 = (Br- bullet C7H4N2O2)

Quantity Value Units Method Reference Comment
Deltar20.5 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar11.1 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzonitrile, 4-hydroxy- = (Bromine anion bullet Benzonitrile, 4-hydroxy-)

By formula: Br- + C7H5NO = (Br- bullet C7H5NO)

Quantity Value Units Method Reference Comment
Deltar27.8 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar18.1 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
18.1423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Phenol, pentafluoro- = (Bromine anion bullet Phenol, pentafluoro-)

By formula: Br- + C6HF5O = (Br- bullet C6HF5O)

Quantity Value Units Method Reference Comment
Deltar25.6 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar15.9 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
15.9423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Benzonitrile, 3-hydroxy- = (Bromine anion bullet Benzonitrile, 3-hydroxy-)

By formula: Br- + C7H5NO = (Br- bullet C7H5NO)

Quantity Value Units Method Reference Comment
Deltar27.4 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar17.7 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
17.7423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-chloro-4-nitro- = (Bromine anion bullet Benzene, 1-chloro-4-nitro-)

By formula: Br- + C6H4ClNO2 = (Br- bullet C6H4ClNO2)

Quantity Value Units Method Reference Comment
Deltar16.1 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.7 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.7423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1,4-dinitro- = (Bromine anion bullet Benzene, 1,4-dinitro-)

By formula: Br- + C6H4N2O4 = (Br- bullet C6H4N2O4)

Quantity Value Units Method Reference Comment
Deltar18.6 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar9.2 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
9.2423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-chloro-3-nitro- = (Bromine anion bullet Benzene, 1-chloro-3-nitro-)

By formula: Br- + C6H4ClNO2 = (Br- bullet C6H4ClNO2)

Quantity Value Units Method Reference Comment
Deltar17.5 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar8.1 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
8.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-fluoro-4-nitro- = (Bromine anion bullet Benzene, 1-fluoro-4-nitro-)

By formula: Br- + C6H4FNO2 = (Br- bullet C6H4FNO2)

Quantity Value Units Method Reference Comment
Deltar15.8 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.4 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.4423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + 2-Nitro-α,α,α-trifluorotoluene = (Bromine anion bullet 2-Nitro-α,α,α-trifluorotoluene)

By formula: Br- + C7H4F3NO2 = (Br- bullet C7H4F3NO2)

Quantity Value Units Method Reference Comment
Deltar19.2 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar9.8 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
9.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + 4-Nitro-α,α,α-trifluorotoluene = (Bromine anion bullet 4-Nitro-α,α,α-trifluorotoluene)

By formula: Br- + C7H4F3NO2 = (Br- bullet C7H4F3NO2)

Quantity Value Units Method Reference Comment
Deltar16.4 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar7.0 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
7.0423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-fluoro-3-nitro- = (Bromine anion bullet Benzene, 1-fluoro-3-nitro-)

By formula: Br- + C6H4FNO2 = (Br- bullet C6H4FNO2)

Quantity Value Units Method Reference Comment
Deltar17.3 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar7.9 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
7.9423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzaldehyde, 2-nitro- = (Bromine anion bullet Benzaldehyde, 2-nitro-)

By formula: Br- + C7H5NO3 = (Br- bullet C7H5NO3)

Quantity Value Units Method Reference Comment
Deltar18.5 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar9.1 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
9.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzonitrile, 4-nitro- = (Bromine anion bullet Benzonitrile, 4-nitro-)

By formula: Br- + C7H4N2O2 = (Br- bullet C7H4N2O2)

Quantity Value Units Method Reference Comment
Deltar18.6 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar9.2 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
9.2423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzaldehyde, 3-nitro- = (Bromine anion bullet Benzaldehyde, 3-nitro-)

By formula: Br- + C7H5NO3 = (Br- bullet C7H5NO3)

Quantity Value Units Method Reference Comment
Deltar19.7 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar10.3 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.3423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1,3-dinitro- = (Bromine anion bullet Benzene, 1,3-dinitro-)

By formula: Br- + C6H4N2O4 = (Br- bullet C6H4N2O4)

Quantity Value Units Method Reference Comment
Deltar20.3 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar10.9 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.9423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-chloro-2-nitro- = (Bromine anion bullet Benzene, 1-chloro-2-nitro-)

By formula: Br- + C6H4ClNO2 = (Br- bullet C6H4ClNO2)

Quantity Value Units Method Reference Comment
Deltar17.1 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar7.7 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
7.7423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-methyl-3-nitro- = (Bromine anion bullet Benzene, 1-methyl-3-nitro-)

By formula: Br- + C7H7NO2 = (Br- bullet C7H7NO2)

Quantity Value Units Method Reference Comment
Deltar15.9 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.5 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

Bromine anion + Hydrogen cation = Hydrogen bromide

By formula: Br- + H+ = HBr

Quantity Value Units Method Reference Comment
Deltar323.540 ± 0.050kcal/molD-EABlondel, Cacciani, et al., 1989gas phase; reported: 27129.170±0.015 cm-1
Deltar323.4 ± 2.1kcal/molG+TSTaft and Bordwell, 1988gas phase
Deltar320.60kcal/molN/ACheck, Faust, et al., 2001gas phase; F-; ; «DELTA»S(acid)=19.2; «DELTA»S(EA)=6.4
Quantity Value Units Method Reference Comment
Deltar318.30 ± 0.15kcal/molH-TSBlondel, Cacciani, et al., 1989gas phase; reported: 27129.170±0.015 cm-1
Deltar318.2 ± 2.0kcal/molIMRETaft and Bordwell, 1988gas phase
Deltar315.40kcal/molN/ACheck, Faust, et al., 2001gas phase; F-; ; «DELTA»S(acid)=19.2; «DELTA»S(EA)=6.4

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Bromine anion + Argon = (Bromine anion bullet Argon)

By formula: Br- + Ar = (Br- bullet Ar)

Quantity Value Units Method Reference Comment
Deltar0.80kcal/molTherZhao, Yourshaw, et al., 1994gas phase; B
Deltar1.40kcal/molMoblGatland, 1984gas phase; B,M

Bromine anion + Selenium dibromide = Br3Se-

By formula: Br- + Br2Se = Br3Se-

Quantity Value Units Method Reference Comment
Deltar26.3 ± 1.4kcal/molCIDTLobring, Hao, et al., 2003gas phase; B

Bromine anion + Bromine = (Bromine anion bullet Bromine)

By formula: Br- + Br2 = (Br- bullet Br2)

Quantity Value Units Method Reference Comment
Deltar30.4 ± 1.7kcal/molCIDTNizzi, Pommerening, et al., 1998gas phase; B
Deltar33.70kcal/molN/ACheck, Faust, et al., 2001gas phase; Fe-; ; «DELTA»S(EA)=5.8; B
Quantity Value Units Method Reference Comment
Deltar22.50kcal/molN/ACheck, Faust, et al., 2001gas phase; Fe-; ; «DELTA»S(EA)=5.8; B

Bromine anion + Phosphorus tribromide = Br4P-

By formula: Br- + Br3P = Br4P-

Quantity Value Units Method Reference Comment
Deltar15.5 ± 1.4kcal/molCIDTHeil, Check, et al., 2002gas phase; B

Bromine anion + Bromotrifluoromethane = CBr2F3-

By formula: Br- + CBrF3 = CBr2F3-

Quantity Value Units Method Reference Comment
Deltar13.90 ± 0.20kcal/molTDAsBogdanov and McMahon, 2006gas phase; B
Quantity Value Units Method Reference Comment
Deltar7.28kcal/molTDAsBogdanov and McMahon, 2006gas phase; B

Bromine anion + Trichloromethane = (Bromine anion bullet Trichloromethane)

By formula: Br- + CHCl3 = (Br- bullet CHCl3)

Quantity Value Units Method Reference Comment
Deltar15.80kcal/molMoblGiles and Grimsrud, 1993gas phase; B
Quantity Value Units Method Reference Comment
Deltar9.50kcal/molMoblGiles and Grimsrud, 1993gas phase; B

Bromine anion + Hydrogen cyanide = (Bromine anion bullet Hydrogen cyanide)

By formula: Br- + CHN = (Br- bullet CHN)

Quantity Value Units Method Reference Comment
Deltar19.4 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Deltar16.0 ± 2.0kcal/molEstLarson and McMahon, 1984gas phase; Extrapolated from other halide data; B
Quantity Value Units Method Reference Comment
Deltar19.8cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar13.5 ± 1.6kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Bromine anion bullet Hydrogen cyanide) + Hydrogen cyanide = (Bromine anion bullet 2Hydrogen cyanide)

By formula: (Br- bullet CHN) + CHN = (Br- bullet 2CHN)

Quantity Value Units Method Reference Comment
Deltar16.3 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.7cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Bromine anion bullet 2Hydrogen cyanide) + Hydrogen cyanide = (Bromine anion bullet 3Hydrogen cyanide)

By formula: (Br- bullet 2CHN) + CHN = (Br- bullet 3CHN)

Quantity Value Units Method Reference Comment
Deltar12.8 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.9cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.30kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Bromine anion bullet 3Hydrogen cyanide) + Hydrogen cyanide = (Bromine anion bullet 4Hydrogen cyanide)

By formula: (Br- bullet 3CHN) + CHN = (Br- bullet 4CHN)

Quantity Value Units Method Reference Comment
Deltar10.4 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.1cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.80kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Bromine anion bullet 4Hydrogen cyanide) + Hydrogen cyanide = (Bromine anion bullet 5Hydrogen cyanide)

By formula: (Br- bullet 4CHN) + CHN = (Br- bullet 5CHN)

Quantity Value Units Method Reference Comment
Deltar8.1 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar18.5cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.60kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

Bromine anion + Formic acid = CH2BrO2-

By formula: Br- + CH2O2 = CH2BrO2-

Quantity Value Units Method Reference Comment
Deltar17.2 ± 1.7kcal/molCIDTWalker and Sunderlin, 1999gas phase; B

Bromine anion + Methane, bromo- = (Bromine anion bullet Methane, bromo-)

By formula: Br- + CH3Br = (Br- bullet CH3Br)

Quantity Value Units Method Reference Comment
Deltar11.2 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar9.20 ± 0.50kcal/molTDAsDougherty and Roberts, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar14.0cal/mol*KHPMSDougherty and Roberts, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.60 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar5.00 ± 0.80kcal/molTDAsDougherty and Roberts, 1974gas phase; B

Bromine anion + Chloromethane = (Bromine anion bullet Chloromethane)

By formula: Br- + CH3Cl = (Br- bullet CH3Cl)

Quantity Value Units Method Reference Comment
Deltar10.9 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar4.85 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B

Bromine anion + Methane, nitro- = CH3BrNO2-

By formula: Br- + CH3NO2 = CH3BrNO2-

Quantity Value Units Method Reference Comment
Deltar9.6 ± 2.0kcal/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

Bromine anion + Methyl Alcohol = (Bromine anion bullet Methyl Alcohol)

By formula: Br- + CH4O = (Br- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar14.50 ± 0.10kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar13.9 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar17.6cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.00 ± 0.10kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar8.7 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B
Deltar8.4 ± 2.0kcal/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

(Bromine anion bullet Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 2Methyl Alcohol)

By formula: (Br- bullet CH4O) + CH4O = (Br- bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar12.00 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar12.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.7cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.62kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar6.3 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 2Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 3Methyl Alcohol)

By formula: (Br- bullet 2CH4O) + CH4O = (Br- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar9.50 ± 0.50kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar10.6 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.6cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.25kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar4.2 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 3Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 4Methyl Alcohol)

By formula: (Br- bullet 3CH4O) + CH4O = (Br- bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar9.9 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.2cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.0 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 4Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 5Methyl Alcohol)

By formula: (Br- bullet 4CH4O) + CH4O = (Br- bullet 5CH4O)

Quantity Value Units Method Reference Comment
Deltar9.8 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.2cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.3 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 5Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 6Methyl Alcohol)

By formula: (Br- bullet 5CH4O) + CH4O = (Br- bullet 6CH4O)

Quantity Value Units Method Reference Comment
Deltar9.1 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.6cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.1 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 6Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 7Methyl Alcohol)

By formula: (Br- bullet 6CH4O) + CH4O = (Br- bullet 7CH4O)

Quantity Value Units Method Reference Comment
Deltar8.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.7 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 7Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 8Methyl Alcohol)

By formula: (Br- bullet 7CH4O) + CH4O = (Br- bullet 8CH4O)

Quantity Value Units Method Reference Comment
Deltar8.4 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.1cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.5 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 8Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 9Methyl Alcohol)

By formula: (Br- bullet 8CH4O) + CH4O = (Br- bullet 9CH4O)

Quantity Value Units Method Reference Comment
Deltar8.2 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1.3 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

(Bromine anion bullet 9Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 10Methyl Alcohol)

By formula: (Br- bullet 9CH4O) + CH4O = (Br- bullet 10CH4O)

Quantity Value Units Method Reference Comment
Deltar8.0 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1.1 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

Bromine anion + Methane = CH4Br-

By formula: Br- + CH4 = CH4Br-

Quantity Value Units Method Reference Comment
Deltar3.10kcal/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar-2.27kcal/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

Bromine anion + Carbon dioxide = (Bromine anion bullet Carbon dioxide)

By formula: Br- + CO2 = (Br- bullet CO2)

Quantity Value Units Method Reference Comment
Deltar5.3 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B
Deltar6.7 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar16.5cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.8 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

(Bromine anion bullet Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 2Carbon dioxide)

By formula: (Br- bullet CO2) + CO2 = (Br- bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar5.1 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995, 2gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
Deltar6.0 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.0cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.3 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

(Bromine anion bullet 2Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 3Carbon dioxide)

By formula: (Br- bullet 2CO2) + CO2 = (Br- bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar5.1 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995, 2gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 3Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 4Carbon dioxide)

By formula: (Br- bullet 3CO2) + CO2 = (Br- bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar5.2 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995, 2gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 4Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 5Carbon dioxide)

By formula: (Br- bullet 4CO2) + CO2 = (Br- bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar4.2 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995, 2gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 5Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 6Carbon dioxide)

By formula: (Br- bullet 5CO2) + CO2 = (Br- bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar4.0 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995, 2gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 6Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 7Carbon dioxide)

By formula: (Br- bullet 6CO2) + CO2 = (Br- bullet 7CO2)

Quantity Value Units Method Reference Comment
Deltar3.6 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995, 2gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 7Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 8Carbon dioxide)

By formula: (Br- bullet 7CO2) + CO2 = (Br- bullet 8CO2)

Quantity Value Units Method Reference Comment
Deltar3.7 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995, 2gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 8Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 9Carbon dioxide)

By formula: (Br- bullet 8CO2) + CO2 = (Br- bullet 9CO2)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995, 2gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 9Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 10Carbon dioxide)

By formula: (Br- bullet 9CO2) + CO2 = (Br- bullet 10CO2)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995, 2gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 10Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 11Carbon dioxide)

By formula: (Br- bullet 10CO2) + CO2 = (Br- bullet 11CO2)

Quantity Value Units Method Reference Comment
Deltar0.5 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995, 2gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

Bromine anion + Carbon disulfide = (Bromine anion bullet Carbon disulfide)

By formula: Br- + CS2 = (Br- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar8.30 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar13.0cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.4 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Bromine anion bullet Carbon disulfide) + Carbon disulfide = (Bromine anion bullet 2Carbon disulfide)

By formula: (Br- bullet CS2) + CS2 = (Br- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar7.30 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.4cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.2 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

Bromine anion + Ethene, tetrafluoro- = C2BrF4-

By formula: Br- + C2F4 = C2BrF4-

Quantity Value Units Method Reference Comment
Deltar7.10 ± 0.50kcal/molTDAsHiraoka, Mochizuki, et al., 2008gas phase; The experimental HOF of C2F4 has been questioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B
Quantity Value Units Method Reference Comment
Deltar2.33 ± 0.50kcal/molTDAsHiraoka, Mochizuki, et al., 2008gas phase; The experimental HOF of C2F4 has been questioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B

Bromine anion + Acetylene = C2H2Br-

By formula: Br- + C2H2 = C2H2Br-

Quantity Value Units Method Reference Comment
Deltar8.60kcal/molLPESWild, Milley, et al., 2000gas phase; Given: 8.635±0.009 kcal/mol(0 K); B

Bromine anion + Acetonitrile = (Bromine anion bullet Acetonitrile)

By formula: Br- + C2H3N = (Br- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar14.3 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar12.10 ± 0.40kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar12.90 ± 0.40kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar12.9 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Deltar12.9kcal/molHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar12.2cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar16.5cal/mol*KHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.70 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar8.8 ± 2.0kcal/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B
Deltar9.20 ± 0.70kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar8.0 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Bromine anion bullet Acetonitrile) + Acetonitrile = (Bromine anion bullet 2Acetonitrile)

By formula: (Br- bullet C2H3N) + C2H3N = (Br- bullet 2C2H3N)

Quantity Value Units Method Reference Comment
Deltar11.70 ± 0.40kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar11.50 ± 0.70kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar11.80kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar17.0cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar20.4cal/mol*KHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.6 ± 1.3kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar5.80kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Bromine anion bullet 2Acetonitrile) + Acetonitrile = (Bromine anion bullet 3Acetonitrile)

By formula: (Br- bullet 2C2H3N) + C2H3N = (Br- bullet 3C2H3N)

Quantity Value Units Method Reference Comment
Deltar9.20 ± 0.40kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar10.40 ± 0.70kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar10.00kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar16.7cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar21.7cal/mol*KHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.2 ± 1.3kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar3.60kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Bromine anion bullet 3Acetonitrile) + Acetonitrile = (Bromine anion bullet 4Acetonitrile)

By formula: (Br- bullet 3C2H3N) + C2H3N = (Br- bullet 4C2H3N)

Quantity Value Units Method Reference Comment
Deltar8.70 ± 0.30kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar8.50 ± 0.80kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar5.50kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.6cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar10.9cal/mol*KHPMSYamdagni and Kebarle, 1972gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar2.8 ± 1.2kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar2.20kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Bromine anion bullet 4Acetonitrile) + Acetonitrile = (Bromine anion bullet 5Acetonitrile)

By formula: (Br- bullet 4C2H3N) + C2H3N = (Br- bullet 5C2H3N)

Quantity Value Units Method Reference Comment
Deltar8.50 ± 0.30kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar5.80 ± 0.90kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar22.2cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.8 ± 1.3kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Bromine anion bullet 5Acetonitrile) + Acetonitrile = (Bromine anion bullet 6Acetonitrile)

By formula: (Br- bullet 5C2H3N) + C2H3N = (Br- bullet 6C2H3N)

Quantity Value Units Method Reference Comment
Deltar8.00 ± 0.20kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar5.5 ± 1.0kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar22.5cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.20 ± 0.90kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Bromine anion bullet 6Acetonitrile) + Acetonitrile = (Bromine anion bullet 7Acetonitrile)

By formula: (Br- bullet 6C2H3N) + C2H3N = (Br- bullet 7C2H3N)

Quantity Value Units Method Reference Comment
Deltar7.70 ± 0.30kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar3.0 ± 1.1kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.8 ± 1.3kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Bromine anion bullet 7Acetonitrile) + Acetonitrile = (Bromine anion bullet 8Acetonitrile)

By formula: (Br- bullet 7C2H3N) + C2H3N = (Br- bullet 8C2H3N)

Quantity Value Units Method Reference Comment
Deltar3.7 ± 1.2kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Bromine anion bullet 8Acetonitrile) + Acetonitrile = (Bromine anion bullet 9Acetonitrile)

By formula: (Br- bullet 8C2H3N) + C2H3N = (Br- bullet 9C2H3N)

Quantity Value Units Method Reference Comment
Deltar2.8 ± 1.4kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Bromine anion bullet 9Acetonitrile) + Acetonitrile = (Bromine anion bullet 10Acetonitrile)

By formula: (Br- bullet 9C2H3N) + C2H3N = (Br- bullet 10C2H3N)

Quantity Value Units Method Reference Comment
Deltar3.5 ± 1.5kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Bromine anion bullet 10Acetonitrile) + Acetonitrile = (Bromine anion bullet 11Acetonitrile)

By formula: (Br- bullet 10C2H3N) + C2H3N = (Br- bullet 11C2H3N)

Quantity Value Units Method Reference Comment
Deltar1.2 ± 1.6kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Bromine anion bullet 11Acetonitrile) + Acetonitrile = (Bromine anion bullet 12Acetonitrile)

By formula: (Br- bullet 11C2H3N) + C2H3N = (Br- bullet 12C2H3N)

Quantity Value Units Method Reference Comment
Deltar1.2 ± 1.7kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Bromine anion bullet 12Acetonitrile) + Acetonitrile = (Bromine anion bullet 13Acetonitrile)

By formula: (Br- bullet 12C2H3N) + C2H3N = (Br- bullet 13C2H3N)

Quantity Value Units Method Reference Comment
Deltar0.5 ± 1.8kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Bromine anion bullet 13Acetonitrile) + Acetonitrile = (Bromine anion bullet 14Acetonitrile)

By formula: (Br- bullet 13C2H3N) + C2H3N = (Br- bullet 14C2H3N)

Quantity Value Units Method Reference Comment
Deltar0.7 ± 1.9kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

Bromine anion + Ethyl bromide = (Bromine anion bullet Ethyl bromide)

By formula: Br- + C2H5Br = (Br- bullet C2H5Br)

Quantity Value Units Method Reference Comment
Deltar12.0 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar11.60kcal/molTDAsDougherty, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.2cal/mol*KHPMSDougherty, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.90 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar5.90kcal/molTDAsDougherty, 1974gas phase; B

Bromine anion + Ethyl Chloride = (Bromine anion bullet Ethyl Chloride)

By formula: Br- + C2H5Cl = (Br- bullet C2H5Cl)

Quantity Value Units Method Reference Comment
Deltar11.2 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar5.36 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B

Bromine anion + Dimethyl Sulfoxide = (Bromine anion bullet Dimethyl Sulfoxide)

By formula: Br- + C2H6OS = (Br- bullet C2H6OS)

Quantity Value Units Method Reference Comment
Deltar17.30kcal/molTDAsMagnera, Caldwell, et al., 1984gas phase; B,M
Deltar17.2kcal/molHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.4cal/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar10.90kcal/molTDAsMagnera, Caldwell, et al., 1984gas phase; B

(Bromine anion bullet Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Bromine anion bullet 2Dimethyl Sulfoxide)

By formula: (Br- bullet C2H6OS) + C2H6OS = (Br- bullet 2C2H6OS)

Quantity Value Units Method Reference Comment
Deltar14.5kcal/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.4cal/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

(Bromine anion bullet 2Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Bromine anion bullet 3Dimethyl Sulfoxide)

By formula: (Br- bullet 2C2H6OS) + C2H6OS = (Br- bullet 3C2H6OS)

Quantity Value Units Method Reference Comment
Deltar13.6kcal/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar27.5cal/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

Bromine anion + Ethanol = C2H6BrO-

By formula: Br- + C2H6O = C2H6BrO-

Quantity Value Units Method Reference Comment
Deltar14.10 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar8.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar8.8 ± 2.0kcal/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

Bromine anion + 2Ethanol = C4H12BrO2-

By formula: Br- + 2C2H6O = C4H12BrO2-

Quantity Value Units Method Reference Comment
Deltar11.50 ± 0.60kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar5.72kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

Bromine anion + 3Ethanol = C6H18BrO3-

By formula: Br- + 3C2H6O = C6H18BrO3-

Quantity Value Units Method Reference Comment
Deltar9.50 ± 0.30kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar4.37kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

Bromine anion + Propene, hexafluoro- = C3BrF6-

By formula: Br- + C3F6 = C3BrF6-

Quantity Value Units Method Reference Comment
Deltar9.90 ± 0.30kcal/molTDAsHiraoka, Takao, et al., 2002gas phase; B
Quantity Value Units Method Reference Comment
Deltar4.24 ± 0.30kcal/molTDAsHiraoka, Takao, et al., 2002gas phase; B

Bromine anion + Propane, 2-bromo- = (Bromine anion bullet Propane, 2-bromo-)

By formula: Br- + C3H7Br = (Br- bullet C3H7Br)

Quantity Value Units Method Reference Comment
Deltar14.2 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar12.20kcal/molTDAsDougherty, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.9cal/mol*KHPMSDougherty, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.30 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar6.30kcal/molTDAsDougherty, 1974gas phase; B

Bromine anion + Propane, 1-bromo- = (Bromine anion bullet Propane, 1-bromo-)

By formula: Br- + C3H7Br = (Br- bullet C3H7Br)

Quantity Value Units Method Reference Comment
Deltar11.60kcal/molTDAsDougherty, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.8cal/mol*KHPMSDougherty, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.70kcal/molTDAsDougherty, 1974gas phase; B

Bromine anion + Propane, 2-chloro- = (Bromine anion bullet Propane, 2-chloro-)

By formula: Br- + C3H7Cl = (Br- bullet C3H7Cl)

Quantity Value Units Method Reference Comment
Deltar12.4 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar6.26 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B

Bromine anion + n-Propyl chloride = (Bromine anion bullet n-Propyl chloride)

By formula: Br- + C3H7Cl = (Br- bullet C3H7Cl)

Quantity Value Units Method Reference Comment
Deltar12.1 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar5.96 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B

Bromine anion + Isopropyl Alcohol = C3H8BrO-

By formula: Br- + C3H8O = C3H8BrO-

Quantity Value Units Method Reference Comment
Deltar14.40 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar8.35kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar9.2 ± 2.0kcal/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

Bromine anion + 2Isopropyl Alcohol = C6H16BrO2-

By formula: Br- + 2C3H8O = C6H16BrO2-

Quantity Value Units Method Reference Comment
Deltar12.30 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar5.44kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

Bromine anion + Propane, 1-bromo-2-methyl- = (Bromine anion bullet Propane, 1-bromo-2-methyl-)

By formula: Br- + C4H9Br = (Br- bullet C4H9Br)

Quantity Value Units Method Reference Comment
Deltar12.90kcal/molTDAsDougherty, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.8cal/mol*KHPMSDougherty, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.40kcal/molTDAsDougherty, 1974gas phase; B

Bromine anion + Propane, 2-bromo-2-methyl- = (Bromine anion bullet Propane, 2-bromo-2-methyl-)

By formula: Br- + C4H9Br = (Br- bullet C4H9Br)

Quantity Value Units Method Reference Comment
Deltar15.6 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar12.40kcal/molTDAsDougherty, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.3cal/mol*KHPMSDougherty, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.30 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar6.70kcal/molTDAsDougherty, 1974gas phase; B

Bromine anion + Propane, 2-chloro-2-methyl- = (Bromine anion bullet Propane, 2-chloro-2-methyl-)

By formula: Br- + C4H9Cl = (Br- bullet C4H9Cl)

Quantity Value Units Method Reference Comment
Deltar13.9 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar6.60 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B

Bromine anion + 2-Propanol, 2-methyl- = C4H10BrO-

By formula: Br- + C4H10O = C4H10BrO-

Quantity Value Units Method Reference Comment
Deltar15.80 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar8.58kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

Bromine anion + 22-Propanol, 2-methyl- = C8H20BrO2-

By formula: Br- + 2C4H10O = C8H20BrO2-

Quantity Value Units Method Reference Comment
Deltar12.90 ± 0.40kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar5.65kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

Bromine anion + 32-Propanol, 2-methyl- = C12H30BrO3-

By formula: Br- + 3C4H10O = C12H30BrO3-

Quantity Value Units Method Reference Comment
Deltar11.60 ± 0.50kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar4.33kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

Bromine anion + Cyclopentene, octafluoro- = C5BrF8-

By formula: Br- + C5F8 = C5BrF8-

Quantity Value Units Method Reference Comment
Deltar12.70 ± 0.30kcal/molTDAsHiraoka, Fujita, et al., 1905gas phase; B
Quantity Value Units Method Reference Comment
Deltar7.04 ± 0.30kcal/molTDAsHiraoka, Fujita, et al., 1905gas phase; B

Bromine anion + Propane, 1-bromo-2,2-dimethyl- = (Bromine anion bullet Propane, 1-bromo-2,2-dimethyl-)

By formula: Br- + C5H11Br = (Br- bullet C5H11Br)

Quantity Value Units Method Reference Comment
Deltar14.40kcal/molTDAsDougherty, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.2cal/mol*KHPMSDougherty, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.90kcal/molTDAsDougherty, 1974gas phase; B

Bromine anion + Benzene, hexafluoro- = (Bromine anion bullet Benzene, hexafluoro-)

By formula: Br- + C6F6 = (Br- bullet C6F6)

Quantity Value Units Method Reference Comment
Deltar13.9 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.4cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.1 ± 1.6kcal/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B

(Bromine anion bullet Benzene, hexafluoro-) + Benzene, hexafluoro- = (Bromine anion bullet 2Benzene, hexafluoro-)

By formula: (Br- bullet C6F6) + C6F6 = (Br- bullet 2C6F6)

Quantity Value Units Method Reference Comment
Deltar12.2kcal/molPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.3cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M

Bromine anion + Phenol, pentafluoro- = (Bromine anion bullet Phenol, pentafluoro-)

By formula: Br- + C6HF5O = (Br- bullet C6HF5O)

Quantity Value Units Method Reference Comment
Deltar25.6 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar15.9 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
15.9423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + 1,3,5-Trinitrobenzene = (Bromine anion bullet 1,3,5-Trinitrobenzene)

By formula: Br- + C6H3N3O6 = (Br- bullet C6H3N3O6)

Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; 1,3,5-trinitrobenzene, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar13.1 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
13.1423.PHPMSPaul and Kebarle, 1991gas phase; 1,3,5-trinitrobenzene, Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-chloro-2-nitro- = (Bromine anion bullet Benzene, 1-chloro-2-nitro-)

By formula: Br- + C6H4ClNO2 = (Br- bullet C6H4ClNO2)

Quantity Value Units Method Reference Comment
Deltar17.1 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar7.7 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
7.7423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-chloro-4-nitro- = (Bromine anion bullet Benzene, 1-chloro-4-nitro-)

By formula: Br- + C6H4ClNO2 = (Br- bullet C6H4ClNO2)

Quantity Value Units Method Reference Comment
Deltar16.1 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.7 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.7423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-chloro-3-nitro- = (Bromine anion bullet Benzene, 1-chloro-3-nitro-)

By formula: Br- + C6H4ClNO2 = (Br- bullet C6H4ClNO2)

Quantity Value Units Method Reference Comment
Deltar17.5 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar8.1 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
8.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-fluoro-4-nitro- = (Bromine anion bullet Benzene, 1-fluoro-4-nitro-)

By formula: Br- + C6H4FNO2 = (Br- bullet C6H4FNO2)

Quantity Value Units Method Reference Comment
Deltar15.8 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.4 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.4423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-fluoro-3-nitro- = (Bromine anion bullet Benzene, 1-fluoro-3-nitro-)

By formula: Br- + C6H4FNO2 = (Br- bullet C6H4FNO2)

Quantity Value Units Method Reference Comment
Deltar17.3 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar7.9 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
7.9423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-fluoro-2-nitro- = (Bromine anion bullet Benzene, 1-fluoro-2-nitro-)

By formula: Br- + C6H4FNO2 = (Br- bullet C6H4FNO2)

Quantity Value Units Method Reference Comment
Deltar17.6 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar8.2 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
8.2423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1,3-dinitro- = (Bromine anion bullet Benzene, 1,3-dinitro-)

By formula: Br- + C6H4N2O4 = (Br- bullet C6H4N2O4)

Quantity Value Units Method Reference Comment
Deltar20.3 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar10.9 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.9423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1,4-dinitro- = (Bromine anion bullet Benzene, 1,4-dinitro-)

By formula: Br- + C6H4N2O4 = (Br- bullet C6H4N2O4)

Quantity Value Units Method Reference Comment
Deltar18.6 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar9.2 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
9.2423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1,2-dinitro- = (Bromine anion bullet Benzene, 1,2-dinitro-)

By formula: Br- + C6H4N2O4 = (Br- bullet C6H4N2O4)

Quantity Value Units Method Reference Comment
Deltar21.0 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar11.6 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.6423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 2-chloro- = (Bromine anion bullet Phenol, 2-chloro-)

By formula: Br- + C6H5ClO = (Br- bullet C6H5ClO)

Quantity Value Units Method Reference Comment
Deltar21.2 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar11.5 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.5423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 4-chloro- = (Bromine anion bullet Phenol, 4-chloro-)

By formula: Br- + C6H5ClO = (Br- bullet C6H5ClO)

Quantity Value Units Method Reference Comment
Deltar24.4 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar14.7 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
14.7423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Phenol, 3-chloro- = (Bromine anion bullet Phenol, 3-chloro-)

By formula: Br- + C6H5ClO = (Br- bullet C6H5ClO)

Quantity Value Units Method Reference Comment
Deltar24.1 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar14.4 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
14.4423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Benzene, chloro- = (Bromine anion bullet Benzene, chloro-)

By formula: Br- + C6H5Cl = (Br- bullet C6H5Cl)

Quantity Value Units Method Reference Comment
Deltar11.1 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar2.6 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
2.6423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 2-fluoro- = (Bromine anion bullet Phenol, 2-fluoro-)

By formula: Br- + C6H5FO = (Br- bullet C6H5FO)

Quantity Value Units Method Reference Comment
Deltar20.9 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar11.2 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.2423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 4-fluoro- = (Bromine anion bullet Phenol, 4-fluoro-)

By formula: Br- + C6H5FO = (Br- bullet C6H5FO)

Quantity Value Units Method Reference Comment
Deltar23.3 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar13.6 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
13.6423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 3-fluoro- = (Bromine anion bullet Phenol, 3-fluoro-)

By formula: Br- + C6H5FO = (Br- bullet C6H5FO)

Quantity Value Units Method Reference Comment
Deltar23.4 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar13.7 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
13.7423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, fluoro- = (Bromine anion bullet Benzene, fluoro-)

By formula: Br- + C6H5F = (Br- bullet C6H5F)

Quantity Value Units Method Reference Comment
Deltar10.6 ± 1.6kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar2.1 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
2.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, nitroso- = (Bromine anion bullet Benzene, nitroso-)

By formula: Br- + C6H5NO = (Br- bullet C6H5NO)

Quantity Value Units Method Reference Comment
Deltar13.7 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B
Quantity Value Units Method Reference Comment
Deltar5.2 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Bromine anion + Benzene, nitro- = (Bromine anion bullet Benzene, nitro-)

By formula: Br- + C6H5NO2 = (Br- bullet C6H5NO2)

Quantity Value Units Method Reference Comment
Deltar15.0 ± 1.8kcal/molTDAsPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar20.2cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.5 ± 1.0kcal/molTDAsPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.5423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 4-nitro- = (Bromine anion bullet Phenol, 4-nitro-)

By formula: Br- + C6H5NO3 = (Br- bullet C6H5NO3)

Quantity Value Units Method Reference Comment
Deltar28.4 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar18.7 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
18.7423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Phenol, 3-nitro- = (Bromine anion bullet Phenol, 3-nitro-)

By formula: Br- + C6H5NO3 = (Br- bullet C6H5NO3)

Quantity Value Units Method Reference Comment
Deltar27.4 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar17.7 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
17.7423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Phenol = (Bromine anion bullet Phenol)

By formula: Br- + C6H6O = (Br- bullet C6H6O)

Quantity Value Units Method Reference Comment
Deltar20.8 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Deltar19.6kcal/molPHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar11.1 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
11.1423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene = (Bromine anion bullet Benzene)

By formula: Br- + C6H6 = (Br- bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar9.0 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar17.0cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Deltar17.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar2.5 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; B
Deltar3.9 ± 2.6kcal/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
0.0423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 4-amino- = (Bromine anion bullet Phenol, 4-amino-)

By formula: Br- + C6H7NO = (Br- bullet C6H7NO)

Quantity Value Units Method Reference Comment
Deltar19.5 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar9.8 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
9.8423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 3-amino- = (Bromine anion bullet Phenol, 3-amino-)

By formula: Br- + C6H7NO = (Br- bullet C6H7NO)

Quantity Value Units Method Reference Comment
Deltar20.3 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar10.6 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.6423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Aniline = (Bromine anion bullet Aniline)

By formula: Br- + C6H7N = (Br- bullet C6H7N)

Quantity Value Units Method Reference Comment
Deltar14.6 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.1 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + 3,5-Dinitrobenzotrifluoride = (Bromine anion bullet 3,5-Dinitrobenzotrifluoride)

By formula: Br- + C7H3F3N2O4 = (Br- bullet C7H3F3N2O4)

Quantity Value Units Method Reference Comment
Deltar19.8 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; 3,5-dinitrobenzofluoride, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar10.4 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.4423.PHPMSPaul and Kebarle, 1991gas phase; 3,5-dinitrobenzofluoride, Entropy change calculated or estimated; M

Bromine anion + Benzonitrile, 3,5-dinitro- = (Bromine anion bullet Benzonitrile, 3,5-dinitro-)

By formula: Br- + C7H3N3O4 = (Br- bullet C7H3N3O4)

Quantity Value Units Method Reference Comment
Deltar21.6 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; 3,5-dinitrobenzonitrile, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar12.2 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
12.2423.PHPMSPaul and Kebarle, 1991gas phase; 3,5-dinitrobenzonitrile, Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-nitro-3-(trifluoromethyl)- = (Bromine anion bullet Benzene, 1-nitro-3-(trifluoromethyl)-)

By formula: Br- + C7H4F3NO2 = (Br- bullet C7H4F3NO2)

Quantity Value Units Method Reference Comment
Deltar18.5 ± 1.8kcal/molTDAsPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar22.3cal/mol*KPHPMSPaul and Kebarle, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.1 ± 1.0kcal/molTDAsPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K; B

Bromine anion + 2-Nitro-α,α,α-trifluorotoluene = (Bromine anion bullet 2-Nitro-α,α,α-trifluorotoluene)

By formula: Br- + C7H4F3NO2 = (Br- bullet C7H4F3NO2)

Quantity Value Units Method Reference Comment
Deltar19.2 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar9.8 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
9.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + 4-Nitro-α,α,α-trifluorotoluene = (Bromine anion bullet 4-Nitro-α,α,α-trifluorotoluene)

By formula: Br- + C7H4F3NO2 = (Br- bullet C7H4F3NO2)

Quantity Value Units Method Reference Comment
Deltar16.4 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar7.0 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
7.0423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzonitrile, 2-nitro- = (Bromine anion bullet Benzonitrile, 2-nitro-)

By formula: Br- + C7H4N2O2 = (Br- bullet C7H4N2O2)

Quantity Value Units Method Reference Comment
Deltar20.9 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar11.5 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.5423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzonitrile, 3-nitro- = (Bromine anion bullet Benzonitrile, 3-nitro-)

By formula: Br- + C7H4N2O2 = (Br- bullet C7H4N2O2)

Quantity Value Units Method Reference Comment
Deltar20.5 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar11.1 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzonitrile, 4-nitro- = (Bromine anion bullet Benzonitrile, 4-nitro-)

By formula: Br- + C7H4N2O2 = (Br- bullet C7H4N2O2)

Quantity Value Units Method Reference Comment
Deltar18.6 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar9.2 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
9.2423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, (trichloromethyl)- = (Bromine anion bullet Benzene, (trichloromethyl)-)

By formula: Br- + C7H5Cl3 = (Br- bullet C7H5Cl3)

Quantity Value Units Method Reference Comment
Deltar12.4 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar3.9 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.9423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 3-(trifluoromethyl)- = (Bromine anion bullet Phenol, 3-(trifluoromethyl)-)

By formula: Br- + C7H5F3O = (Br- bullet C7H5F3O)

Quantity Value Units Method Reference Comment
Deltar25.7 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B
Deltar12.6kcal/molPHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar16.0 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + 4-(Trifluoromethyl)-phenol = (Bromine anion bullet 4-(Trifluoromethyl)-phenol)

By formula: Br- + CF3C6H4OH = (Br- bullet CF3C6H4OH)

Quantity Value Units Method Reference Comment
Deltar26.6 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar16.9 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
16.9423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Phenol, 2-(trifluoromethyl)- = (Bromine anion bullet Phenol, 2-(trifluoromethyl)-)

By formula: Br- + C7H5F3O = (Br- bullet C7H5F3O)

Quantity Value Units Method Reference Comment
Deltar24.1kcal/molPHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
14.4423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Benzene, (trifluoromethyl)- = (Bromine anion bullet Benzene, (trifluoromethyl)-)

By formula: Br- + C7H5F3 = (Br- bullet C7H5F3)

Quantity Value Units Method Reference Comment
Deltar12.6 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B
Deltar25.7kcal/molPHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar4.1 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
16.0423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Benzonitrile, 2-hydroxy- = (Bromine anion bullet Benzonitrile, 2-hydroxy-)

By formula: Br- + C7H5NO = (Br- bullet C7H5NO)

Quantity Value Units Method Reference Comment
Deltar27.0 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar17.3 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
17.3423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Benzonitrile, 4-hydroxy- = (Bromine anion bullet Benzonitrile, 4-hydroxy-)

By formula: Br- + C7H5NO = (Br- bullet C7H5NO)

Quantity Value Units Method Reference Comment
Deltar27.8 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar18.1 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
18.1423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Benzonitrile, 3-hydroxy- = (Bromine anion bullet Benzonitrile, 3-hydroxy-)

By formula: Br- + C7H5NO = (Br- bullet C7H5NO)

Quantity Value Units Method Reference Comment
Deltar27.4 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar17.7 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
17.7423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Benzaldehyde, 3-nitro- = (Bromine anion bullet Benzaldehyde, 3-nitro-)

By formula: Br- + C7H5NO3 = (Br- bullet C7H5NO3)

Quantity Value Units Method Reference Comment
Deltar19.7 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar10.3 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.3423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzaldehyde, 2-nitro- = (Bromine anion bullet Benzaldehyde, 2-nitro-)

By formula: Br- + C7H5NO3 = (Br- bullet C7H5NO3)

Quantity Value Units Method Reference Comment
Deltar18.5 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar9.1 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
9.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzonitrile = (Bromine anion bullet Benzonitrile)

By formula: Br- + C7H5N = (Br- bullet C7H5N)

Quantity Value Units Method Reference Comment
Deltar14.7 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.2 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.2423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzaldehyde = (Bromine anion bullet Benzaldehyde)

By formula: Br- + C7H6O = (Br- bullet C7H6O)

Quantity Value Units Method Reference Comment
Deltar13.2kcal/molPHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.7423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzoic acid = (Bromine anion bullet Benzoic acid)

By formula: Br- + C7H6O2 = (Br- bullet C7H6O2)

Quantity Value Units Method Reference Comment
Deltar18.3 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar9.8 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
9.8423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzaldehyde, 3-hydroxy- = (Bromine anion bullet Benzaldehyde, 3-hydroxy-)

By formula: Br- + C7H6O2 = (Br- bullet C7H6O2)

Quantity Value Units Method Reference Comment
Deltar25.2 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar15.5 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
15.5423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Benzaldehyde, 4-hydroxy- = (Bromine anion bullet Benzaldehyde, 4-hydroxy-)

By formula: Br- + C7H6O2 = (Br- bullet C7H6O2)

Quantity Value Units Method Reference Comment
Deltar25.8 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar16.1 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
15.4423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M
16.1423.PHPMSPaul and Kebarle, 1990gas phase; switching reaction,Thermochemical ladder(Br-)C6H5OH, Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-methyl-2-nitro- = (Bromine anion bullet Benzene, 1-methyl-2-nitro-)

By formula: Br- + C7H7NO2 = (Br- bullet C7H7NO2)

Quantity Value Units Method Reference Comment
Deltar15.5 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.1 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-methyl-3-nitro- = (Bromine anion bullet Benzene, 1-methyl-3-nitro-)

By formula: Br- + C7H7NO2 = (Br- bullet C7H7NO2)

Quantity Value Units Method Reference Comment
Deltar15.9 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.5 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Benzene, 1-methyl-4-nitro- = (Bromine anion bullet Benzene, 1-methyl-4-nitro-)

By formula: Br- + C7H7NO2 = (Br- bullet C7H7NO2)

Quantity Value Units Method Reference Comment
Deltar16.2 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.8 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.8423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 2-methyl- = (Bromine anion bullet Phenol, 2-methyl-)

By formula: Br- + C7H8O = (Br- bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar20.6 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar10.9 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.9423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Anisole = (Bromine anion bullet Anisole)

By formula: Br- + C7H8O = (Br- bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar11.8 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar3.3 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.3423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + p-Cresol = (Bromine anion bullet p-Cresol)

By formula: Br- + C7H8O = (Br- bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar20.3 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar10.6 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.6423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Phenol, 3-methyl- = (Bromine anion bullet Phenol, 3-methyl-)

By formula: Br- + C7H8O = (Br- bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar20.6 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar10.9 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.9423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + m-Guaiacol = (Bromine anion bullet m-Guaiacol)

By formula: Br- + C7H8O2 = (Br- bullet C7H8O2)

Quantity Value Units Method Reference Comment
Deltar22.1 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar12.4 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
12.4423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Mequinol = (Bromine anion bullet Mequinol)

By formula: Br- + C7H8O2 = (Br- bullet C7H8O2)

Quantity Value Units Method Reference Comment
Deltar21.0 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar11.3 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.3423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Bromine anion + Toluene = (Bromine anion bullet Toluene)

By formula: Br- + C7H8 = (Br- bullet C7H8)

Quantity Value Units Method Reference Comment
Deltar8.6 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar0.1 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
0.1423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + 3,5-Bis(trifluoromethyl)nitrobenzene = (Bromine anion bullet 3,5-Bis(trifluoromethyl)nitrobenzene)

By formula: Br- + C8H3F6NO2 = (Br- bullet C8H3F6NO2)

Quantity Value Units Method Reference Comment
Deltar17.6 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/APaul and Kebarle, 1991gas phase; 3,5-(CF3)-nitrobenzene, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar8.2 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff at 423 K, «DELTA»Saff taken as that of mCF3-nitrobenzene..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
8.2423.PHPMSPaul and Kebarle, 1991gas phase; 3,5-(CF3)-nitrobenzene, Entropy change calculated or estimated; M

Bromine anion + Acetophenone = (Bromine anion bullet Acetophenone)

By formula: Br- + C8H8O = (Br- bullet C8H8O)

Quantity Value Units Method Reference Comment
Deltar14.1 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar5.6 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.6423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

Bromine anion + Acetophenone, 4'-hydroxy- = (Bromine anion bullet Acetophenone, 4'-hydroxy-)

By formula: Br- + C8H8O2 = (Br- bullet C8H8O2)

Quantity Value Units Method Reference Comment
Deltar25.1 ± 1.8kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B
Quantity Value Units Method Reference Comment
Deltar15.4 ± 1.0kcal/molIMREPaul and Kebarle, 1990gas phase; «DELTA»Gaff at 423 K; B

Bromine anion + Benzenamine, N,N-dimethyl- = (Bromine anion bullet Benzenamine, N,N-dimethyl-)

By formula: Br- + C8H11N = (Br- bullet C8H11N)

Quantity Value Units Method Reference Comment
Deltar11.7 ± 1.8kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar3.2 ± 1.0kcal/molIMREPaul and Kebarle, 1991gas phase; «DELTA»Gaff measured at 303 K, corrected to 423 K, «DELTA»Saff taken as that of PhNO2..Br-; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.2423.PHPMSPaul and Kebarle, 1991gas phase; Entropy change calculated or estimated; M

(Bromine anion bullet 4294967295Cesium) + Cesium = Bromine anion

By formula: (Br- bullet 4294967295Cs) + Cs = Br-

Quantity Value Units Method Reference Comment
Deltar29.80 ± 0.96kcal/molN/AMiller, Leopold, et al., 1986gas phase; Extrapolated by polarizability and radius from experimental data.; B

Bromine anion + Hydrogen bromide = (Bromine anion bullet Hydrogen bromide)

By formula: Br- + HBr = (Br- bullet HBr)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar20.6 ± 2.0kcal/molTDAsCaldwell and Kebarle, 1985gas phase; B,M
Deltar17.5kcal/molFADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr); DG>, «DELTA»rH>; M
Quantity Value Units Method Reference Comment
Deltar22.3cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M
Deltar22.cal/mol*KFADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr); DG>, «DELTA»rH>; M
Quantity Value Units Method Reference Comment
Deltar13.9 ± 2.6kcal/molTDAsCaldwell and Kebarle, 1985gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
9.4367.FADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr); DG>, «DELTA»rH>; M

(Bromine anion bullet Hydrogen bromide) + Hydrogen bromide = (Bromine anion bullet 2Hydrogen bromide)

By formula: (Br- bullet HBr) + HBr = (Br- bullet 2HBr)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar11.0kcal/molPHPMSCaldwell and Kebarle, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar17.0cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M

(Bromine anion bullet Hydrogen bromide) + Sulfur dioxide = (Bromine anion bullet Sulfur dioxide bullet Hydrogen bromide)

By formula: (Br- bullet HBr) + O2S = (Br- bullet O2S bullet HBr)

Quantity Value Units Method Reference Comment
Deltar10.9kcal/molPHPMSCaldwell and Kebarle, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.9cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M

Bromine anion + Hydrogen chloride = (Bromine anion bullet Hydrogen chloride)

By formula: Br- + HCl = (Br- bullet HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar19.6 ± 2.0kcal/molTDEqCaldwell and Kebarle, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.0cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Br-)SO2; M
Quantity Value Units Method Reference Comment
Deltar13.0 ± 2.6kcal/molTDEqCaldwell and Kebarle, 1985gas phase; B

(Bromine anion bullet Hydrogen chloride) + Hydrogen chloride = (Bromine anion bullet 2Hydrogen chloride)

By formula: (Br- bullet HCl) + HCl = (Br- bullet 2HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar12.5kcal/molPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Br-)SO2; M
Quantity Value Units Method Reference Comment
Deltar18.4cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Br-)SO2; M

(Bromine anion bullet Hydrogen chloride) + Sulfur dioxide = (Bromine anion bullet Sulfur dioxide bullet Hydrogen chloride)

By formula: (Br- bullet HCl) + O2S = (Br- bullet O2S bullet HCl)

Quantity Value Units Method Reference Comment
Deltar12.1kcal/molPHPMSCaldwell and Kebarle, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.6cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M

Bromine anion + hydrogen fluoride = (Bromine anion bullet hydrogen fluoride)

By formula: Br- + HF = (Br- bullet HF)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar17.0 ± 2.0kcal/molEstLarson and McMahon, 1984gas phase; Extrapolated from other bihalide data; B
Deltar17.0kcal/molHPMSCaldwell, Masucci, et al., 1989gas phase; M

Bromine anion + Nitric acid = (Bromine anion bullet Nitric acid)

By formula: Br- + HNO3 = (Br- bullet HNO3)

Quantity Value Units Method Reference Comment
Deltar20.0kcal/molFADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr), «DELTA»rH>; M
Quantity Value Units Method Reference Comment
Deltar18.5cal/mol*KFADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr), «DELTA»rH>; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
13.4367.FADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle,switching reaction(Br-/NO3-HNO3/HBr), «DELTA»rH>; M

(Bromine anion bullet Nitric acid) + Nitric acid = (Bromine anion bullet 2Nitric acid)

By formula: (Br- bullet HNO3) + HNO3 = (Br- bullet 2HNO3)

Quantity Value Units Method Reference Comment
Deltar18.1kcal/molFADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle(Br-/NO3- - HNO3/HBr), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar23.6cal/mol*KN/ADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle(Br-/NO3- - HNO3/HBr), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar11.1kcal/molFADavidson, Fehsenfeld, et al., 1977gas phase; From thermochemical cycle(Br-/NO3- - HNO3/HBr), Entropy change calculated or estimated; M

Bromine anion + Water = (Bromine anion bullet Water)

By formula: Br- + H2O = (Br- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar12.70kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Deltar11.70 ± 0.40kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar12.60kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Deltar12.7kcal/molHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar14.7cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar18.4cal/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Deltar19.8cal/mol*KMSBurdett and Hayhurst, 1982gas phase; FLAME SOURCE, 1600 K; M
Quantity Value Units Method Reference Comment
Deltar7.30 ± 0.80kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar7.0 ± 2.8kcal/molTDAsBurdett and Hayhurst, 1982gas phase; B
Deltar7.0 ± 2.0kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B

(Bromine anion bullet Water) + Water = (Bromine anion bullet 2Water)

By formula: (Br- bullet H2O) + H2O = (Br- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar11.60 ± 0.30kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar12.20kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Deltar12.3 ± 1.0kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar12.3 ± 1.0kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar18.0cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar22.9cal/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.2 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar5.4 ± 1.4kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar5.40kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Deltar5.7 ± 2.0kcal/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Bromine anion bullet 2Water) + Water = (Bromine anion bullet 3Water)

By formula: (Br- bullet 2H2O) + H2O = (Br- bullet 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar11.40 ± 0.30kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar6.90kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Deltar11.5 ± 1.0kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar11.5 ± 1.0kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.5cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar24.8cal/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.7 ± 1.1kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar4.1 ± 1.4kcal/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar4.10kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Deltar4.4 ± 2.0kcal/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Bromine anion bullet 3Water) + Water = (Bromine anion bullet 4Water)

By formula: (Br- bullet 3H2O) + H2O = (Br- bullet 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar11.00 ± 0.20kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar6.2 ± 2.3kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Deltar10.9 ± 1.0kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar26.2cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar26.8cal/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.10 ± 0.70kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar2.90kcal/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Deltar3.3 ± 2.0kcal/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Bromine anion bullet 4Water) + Water = (Bromine anion bullet 5Water)

By formula: (Br- bullet 4H2O) + H2O = (Br- bullet 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar10.80 ± 0.30kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar6.2 ± 2.3kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
Deltar28.4cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.3 ± 1.2kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Bromine anion bullet 5Water) + Water = (Bromine anion bullet 6Water)

By formula: (Br- bullet 5H2O) + H2O = (Br- bullet 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar10.30 ± 0.50kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar6.0 ± 2.3kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
Deltar28.2cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.8 ± 2.1kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Bromine anion bullet 6Water) + Water = (Bromine anion bullet 7Water)

By formula: (Br- bullet 6H2O) + H2O = (Br- bullet 7H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar10.00kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B,M
Deltar2.5 ± 2.3kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar29.cal/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1.30kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B

(Bromine anion bullet 7Water) + Water = (Bromine anion bullet 8Water)

By formula: (Br- bullet 7H2O) + H2O = (Br- bullet 8H2O)

Quantity Value Units Method Reference Comment
Deltar1.6 ± 2.3kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 8Water) + Water = (Bromine anion bullet 9Water)

By formula: (Br- bullet 8H2O) + H2O = (Br- bullet 9H2O)

Quantity Value Units Method Reference Comment
Deltar0.7 ± 2.3kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 9Water) + Water = (Bromine anion bullet 10Water)

By formula: (Br- bullet 9H2O) + H2O = (Br- bullet 10H2O)

Quantity Value Units Method Reference Comment
Deltar1.6 ± 2.3kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 10Water) + Water = (Bromine anion bullet 11Water)

By formula: (Br- bullet 10H2O) + H2O = (Br- bullet 11H2O)

Quantity Value Units Method Reference Comment
Deltar1.6 ± 2.3kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 11Water) + Water = (Bromine anion bullet 12Water)

By formula: (Br- bullet 11H2O) + H2O = (Br- bullet 12H2O)

Quantity Value Units Method Reference Comment
Deltar2.5 ± 2.3kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 12Water) + Water = (Bromine anion bullet 13Water)

By formula: (Br- bullet 12H2O) + H2O = (Br- bullet 13H2O)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 2.3kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 13Water) + Water = (Bromine anion bullet 14Water)

By formula: (Br- bullet 13H2O) + H2O = (Br- bullet 14H2O)

Quantity Value Units Method Reference Comment
Deltar3.2 ± 2.3kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 14Water) + Water = (Bromine anion bullet 15Water)

By formula: (Br- bullet 14H2O) + H2O = (Br- bullet 15H2O)

Quantity Value Units Method Reference Comment
Deltar-0.5 ± 2.3kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 15Water) + Water = (Bromine anion bullet 16Water)

By formula: (Br- bullet 15H2O) + H2O = (Br- bullet 16H2O)

Quantity Value Units Method Reference Comment
Deltar2.3 ± 2.3kcal/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

Bromine anion + Ammonia = (Bromine anion bullet Ammonia)

By formula: Br- + H3N = (Br- bullet H3N)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar7.70 ± 0.10kcal/molTDAsEvans, Keesee, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.1cal/mol*KHPMSEvans, Keesee, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.00 ± 0.20kcal/molTDAsEvans, Keesee, et al., 1987gas phase; B

Bromine anion + Krypton = (Bromine anion bullet Krypton)

By formula: Br- + Kr = (Br- bullet Kr)

Quantity Value Units Method Reference Comment
Deltar1.10 ± 0.10kcal/molLPESYourshaw, Lenzer, et al., 1998gas phase; given: 0.0795(.001) eV; B
Deltar<2.70kcal/molTDAsWada, Kikkawa, et al., 2007gas phase; B
Deltar2.00kcal/molMoblGatland, 1984gas phase; B,M

Bromine anion + Nitrous oxide = (Bromine anion bullet Nitrous oxide)

By formula: Br- + N2O = (Br- bullet N2O)

Quantity Value Units Method Reference Comment
Deltar5.6 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.1cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Bromine anion bullet Nitrous oxide) + Nitrous oxide = (Bromine anion bullet 2Nitrous oxide)

By formula: (Br- bullet N2O) + N2O = (Br- bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar5.4 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.8cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Bromine anion bullet 2Nitrous oxide) + Nitrous oxide = (Bromine anion bullet 3Nitrous oxide)

By formula: (Br- bullet 2N2O) + N2O = (Br- bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar5.0 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Bromine anion + Sulfur dioxide = (Bromine anion bullet Sulfur dioxide)

By formula: Br- + O2S = (Br- bullet O2S)

Quantity Value Units Method Reference Comment
Deltar19.3 ± 2.0kcal/molTDAsCaldwell and Kebarle, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.0cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar12.7 ± 2.6kcal/molTDAsCaldwell and Kebarle, 1985gas phase; B

(Bromine anion bullet Sulfur dioxide) + Hydrogen bromide = (Bromine anion bullet Hydrogen bromide bullet Sulfur dioxide)

By formula: (Br- bullet O2S) + HBr = (Br- bullet HBr bullet O2S)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar12.2kcal/molPHPMSCaldwell and Kebarle, 1985gas phase; From thermochemical cycle,switching reaction(Br- HBr)SO2; M
Quantity Value Units Method Reference Comment
Deltar19.2cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; From thermochemical cycle,switching reaction(Br- HBr)SO2; M

(Bromine anion bullet Sulfur dioxide) + Hydrogen chloride = (Bromine anion bullet Hydrogen chloride bullet Sulfur dioxide)

By formula: (Br- bullet O2S) + HCl = (Br- bullet HCl bullet O2S)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar22.4kcal/molPHPMSCaldwell and Kebarle, 1985gas phase; From thermochemical cycle,switching reaction(Br-)SO2; M
Quantity Value Units Method Reference Comment
Deltar18.6cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; From thermochemical cycle,switching reaction(Br-)SO2; M

(Bromine anion bullet Sulfur dioxide) + Sulfur dioxide = (Bromine anion bullet 2Sulfur dioxide)

By formula: (Br- bullet O2S) + O2S = (Br- bullet 2O2S)

Quantity Value Units Method Reference Comment
Deltar11.2kcal/molPHPMSCaldwell and Kebarle, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.7cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M

(Bromine anion bullet 2Sulfur dioxide) + Sulfur dioxide = (Bromine anion bullet 3Sulfur dioxide)

By formula: (Br- bullet 2O2S) + O2S = (Br- bullet 3O2S)

Quantity Value Units Method Reference Comment
Deltar8.5kcal/molPHPMSCaldwell and Kebarle, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar13.8cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M

Bromine anion + sulphur trioxide = BrO3S-

By formula: Br- + O3S = BrO3S-

Quantity Value Units Method Reference Comment
Deltar42.8 ± 2.6kcal/molCIDTHao, Gilbert, et al., 2006gas phase; B

(Bromine anion bullet 4294967295rubidium) + rubidium = Bromine anion

By formula: (Br- bullet 4294967295Rb) + Rb = Br-

Quantity Value Units Method Reference Comment
Deltar26.6 ± 1.0kcal/molTherMiller, Leopold, et al., 1986gas phase; Extrapolated by polarizability and radius from experimental data.; B

Bromine anion + Xenon = (Bromine anion bullet Xenon)

By formula: Br- + Xe = (Br- bullet Xe)

Quantity Value Units Method Reference Comment
Deltar3.60 ± 0.30kcal/molTDAsWada, Kikkawa, et al., 2007gas phase; B
Deltar2.90 ± 0.10kcal/molLPESYourshaw, Lenzer, et al., 1998gas phase; Given: 0.12692(.0005) eV; B
Deltar3.40kcal/molMoblGatland, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar-1.17 ± 0.30kcal/molTDAsWada, Kikkawa, et al., 2007gas phase; B

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S., Solvation of Halide Ions with H2O and CH3CN in the Gas Phase, J. Phys. Chem., 1988, 92, 13, 3943, https://doi.org/10.1021/j100324a051 . [all data]

Markovich, Pollack, et al., 1994
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Payzant, Yamdagni, et al., 1971
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