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Bromine anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 151 to 185

(Bromine anion bullet Hydrogen chloride) + Sulfur dioxide = (Bromine anion bullet Sulfur dioxide bullet Hydrogen chloride)

By formula: (Br- bullet HCl) + O2S = (Br- bullet O2S bullet HCl)

Quantity Value Units Method Reference Comment
Deltar12.1kcal/molPHPMSCaldwell and Kebarle, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.6cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M

(Bromine anion bullet 4294967295rubidium) + rubidium = Bromine anion

By formula: (Br- bullet 4294967295Rb) + Rb = Br-

Quantity Value Units Method Reference Comment
Deltar26.6 ± 1.0kcal/molTherMiller, Leopold, et al., 1986gas phase; Extrapolated by polarizability and radius from experimental data.; B

(Bromine anion bullet 2Nitrous oxide) + Nitrous oxide = (Bromine anion bullet 3Nitrous oxide)

By formula: (Br- bullet 2N2O) + N2O = (Br- bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar5.0 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Bromine anion + Propene, hexafluoro- = C3BrF6-

By formula: Br- + C3F6 = C3BrF6-

Quantity Value Units Method Reference Comment
Deltar9.90 ± 0.30kcal/molTDAsHiraoka, Takao, et al., 2002gas phase; B
Quantity Value Units Method Reference Comment
Deltar4.24 ± 0.30kcal/molTDAsHiraoka, Takao, et al., 2002gas phase; B

(Bromine anion bullet Nitrous oxide) + Nitrous oxide = (Bromine anion bullet 2Nitrous oxide)

By formula: (Br- bullet N2O) + N2O = (Br- bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar5.4 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.8cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Bromine anion bullet 4294967295Cesium) + Cesium = Bromine anion

By formula: (Br- bullet 4294967295Cs) + Cs = Br-

Quantity Value Units Method Reference Comment
Deltar29.80 ± 0.96kcal/molN/AMiller, Leopold, et al., 1986gas phase; Extrapolated by polarizability and radius from experimental data.; B

Bromine anion + Bromotrifluoromethane = CBr2F3-

By formula: Br- + CBrF3 = CBr2F3-

Quantity Value Units Method Reference Comment
Deltar13.90 ± 0.20kcal/molTDAsBogdanov and McMahon, 2006gas phase; B
Quantity Value Units Method Reference Comment
Deltar7.28kcal/molTDAsBogdanov and McMahon, 2006gas phase; B

(Bromine anion bullet 2Sulfur dioxide) + Sulfur dioxide = (Bromine anion bullet 3Sulfur dioxide)

By formula: (Br- bullet 2O2S) + O2S = (Br- bullet 3O2S)

Quantity Value Units Method Reference Comment
Deltar8.5kcal/molPHPMSCaldwell and Kebarle, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar13.8cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M

(Bromine anion bullet Sulfur dioxide) + Sulfur dioxide = (Bromine anion bullet 2Sulfur dioxide)

By formula: (Br- bullet O2S) + O2S = (Br- bullet 2O2S)

Quantity Value Units Method Reference Comment
Deltar11.2kcal/molPHPMSCaldwell and Kebarle, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.7cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M

Bromine anion + 2Ethanol = C4H12BrO2-

By formula: Br- + 2C2H6O = C4H12BrO2-

Quantity Value Units Method Reference Comment
Deltar11.50 ± 0.60kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar5.72kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

Bromine anion + 2Isopropyl Alcohol = C6H16BrO2-

By formula: Br- + 2C3H8O = C6H16BrO2-

Quantity Value Units Method Reference Comment
Deltar12.30 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar5.44kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

Bromine anion + 22-Propanol, 2-methyl- = C8H20BrO2-

By formula: Br- + 2C4H10O = C8H20BrO2-

Quantity Value Units Method Reference Comment
Deltar12.90 ± 0.40kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar5.65kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

Bromine anion + 32-Propanol, 2-methyl- = C12H30BrO3-

By formula: Br- + 3C4H10O = C12H30BrO3-

Quantity Value Units Method Reference Comment
Deltar11.60 ± 0.50kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar4.33kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

Bromine anion + 3Ethanol = C6H18BrO3-

By formula: Br- + 3C2H6O = C6H18BrO3-

Quantity Value Units Method Reference Comment
Deltar9.50 ± 0.30kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar4.37kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

Bromine anion + Trichloromethane = (Bromine anion bullet Trichloromethane)

By formula: Br- + CHCl3 = (Br- bullet CHCl3)

Quantity Value Units Method Reference Comment
Deltar15.80kcal/molMoblGiles and Grimsrud, 1993gas phase; B
Quantity Value Units Method Reference Comment
Deltar9.50kcal/molMoblGiles and Grimsrud, 1993gas phase; B

Bromine anion + 2-Propanol, 2-methyl- = C4H10BrO-

By formula: Br- + C4H10O = C4H10BrO-

Quantity Value Units Method Reference Comment
Deltar15.80 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Deltar8.58kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B

(Bromine anion bullet Benzene, hexafluoro-) + Benzene, hexafluoro- = (Bromine anion bullet 2Benzene, hexafluoro-)

By formula: (Br- bullet C6F6) + C6F6 = (Br- bullet 2C6F6)

Quantity Value Units Method Reference Comment
Deltar12.2kcal/molPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.3cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M

(Bromine anion bullet 2Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Bromine anion bullet 3Dimethyl Sulfoxide)

By formula: (Br- bullet 2C2H6OS) + C2H6OS = (Br- bullet 3C2H6OS)

Quantity Value Units Method Reference Comment
Deltar13.6kcal/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar27.5cal/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

(Bromine anion bullet Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Bromine anion bullet 2Dimethyl Sulfoxide)

By formula: (Br- bullet C2H6OS) + C2H6OS = (Br- bullet 2C2H6OS)

Quantity Value Units Method Reference Comment
Deltar14.5kcal/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.4cal/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

Bromine anion + Nitrous oxide = (Bromine anion bullet Nitrous oxide)

By formula: Br- + N2O = (Br- bullet N2O)

Quantity Value Units Method Reference Comment
Deltar5.6 ± 0.3kcal/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.1cal/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Bromine anion + Methane = CH4Br-

By formula: Br- + CH4 = CH4Br-

Quantity Value Units Method Reference Comment
Deltar3.10kcal/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar-2.27kcal/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

Bromine anion + Argon = (Bromine anion bullet Argon)

By formula: Br- + Ar = (Br- bullet Ar)

Quantity Value Units Method Reference Comment
Deltar0.80kcal/molTherZhao, Yourshaw, et al., 1994gas phase; B
Deltar1.40kcal/molMoblGatland, 1984gas phase; B,M

Bromine anion + Methane, nitro- = CH3BrNO2-

By formula: Br- + CH3NO2 = CH3BrNO2-

Quantity Value Units Method Reference Comment
Deltar9.6 ± 2.0kcal/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

Bromine anion + Acetylene = C2H2Br-

By formula: Br- + C2H2 = C2H2Br-

Quantity Value Units Method Reference Comment
Deltar8.60kcal/molLPESWild, Milley, et al., 2000gas phase; Given: 8.635±0.009 kcal/mol(0 K); B

(Bromine anion bullet 10Acetonitrile) + Acetonitrile = (Bromine anion bullet 11Acetonitrile)

By formula: (Br- bullet 10C2H3N) + C2H3N = (Br- bullet 11C2H3N)

Quantity Value Units Method Reference Comment
Deltar1.2 ± 1.6kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Bromine anion bullet 11Acetonitrile) + Acetonitrile = (Bromine anion bullet 12Acetonitrile)

By formula: (Br- bullet 11C2H3N) + C2H3N = (Br- bullet 12C2H3N)

Quantity Value Units Method Reference Comment
Deltar1.2 ± 1.7kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Bromine anion bullet 12Acetonitrile) + Acetonitrile = (Bromine anion bullet 13Acetonitrile)

By formula: (Br- bullet 12C2H3N) + C2H3N = (Br- bullet 13C2H3N)

Quantity Value Units Method Reference Comment
Deltar0.5 ± 1.8kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Bromine anion bullet 13Acetonitrile) + Acetonitrile = (Bromine anion bullet 14Acetonitrile)

By formula: (Br- bullet 13C2H3N) + C2H3N = (Br- bullet 14C2H3N)

Quantity Value Units Method Reference Comment
Deltar0.7 ± 1.9kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Bromine anion bullet 9Acetonitrile) + Acetonitrile = (Bromine anion bullet 10Acetonitrile)

By formula: (Br- bullet 9C2H3N) + C2H3N = (Br- bullet 10C2H3N)

Quantity Value Units Method Reference Comment
Deltar3.5 ± 1.5kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Bromine anion bullet 7Acetonitrile) + Acetonitrile = (Bromine anion bullet 8Acetonitrile)

By formula: (Br- bullet 7C2H3N) + C2H3N = (Br- bullet 8C2H3N)

Quantity Value Units Method Reference Comment
Deltar3.7 ± 1.2kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Bromine anion bullet 8Acetonitrile) + Acetonitrile = (Bromine anion bullet 9Acetonitrile)

By formula: (Br- bullet 8C2H3N) + C2H3N = (Br- bullet 9C2H3N)

Quantity Value Units Method Reference Comment
Deltar2.8 ± 1.4kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

Bromine anion + Selenium dibromide = Br3Se-

By formula: Br- + Br2Se = Br3Se-

Quantity Value Units Method Reference Comment
Deltar26.3 ± 1.4kcal/molCIDTLobring, Hao, et al., 2003gas phase; B

Bromine anion + Phosphorus tribromide = Br4P-

By formula: Br- + Br3P = Br4P-

Quantity Value Units Method Reference Comment
Deltar15.5 ± 1.4kcal/molCIDTHeil, Check, et al., 2002gas phase; B

Bromine anion + sulphur trioxide = BrO3S-

By formula: Br- + O3S = BrO3S-

Quantity Value Units Method Reference Comment
Deltar42.8 ± 2.6kcal/molCIDTHao, Gilbert, et al., 2006gas phase; B

Bromine anion + Formic acid = CH2BrO2-

By formula: Br- + CH2O2 = CH2BrO2-

Quantity Value Units Method Reference Comment
Deltar17.2 ± 1.7kcal/molCIDTWalker and Sunderlin, 1999gas phase; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Caldwell and Kebarle, 1985
Caldwell, G.; Kebarle, P., The hydrogen bond energies of the bihalide ions XHX- and YHX-, Can. J. Chem., 1985, 63, 1399. [all data]

Miller, Leopold, et al., 1986
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C., Electron Affinities of the Alkali Halides and the Structure of their Negative Ions, J. Chem. Phys., 1986, 85, 5, 2368, https://doi.org/10.1063/1.451091 . [all data]

Hiraoka, Aruga, et al., 1993
Hiraoka, K.; Aruga, K.; Fujimaki, S.; Yamabe, S., Comparative Study of the Gas Phase Bond Strengths of CO2 and N2O with the Halide Ions, J. Am. Soc. Mass Spectrom., 1993, 4, 1, 58, https://doi.org/10.1016/1044-0305(93)85043-W . [all data]

Hiraoka, Takao, et al., 2002
Hiraoka, K.; Takao, K.; Lino, T.; Nakagawa, F.; Suyama, H.; Mizuno, T.; Yamabe, S., Gas-phase ion-molecule reactions in C3F6, J. Phys. Chem. A, 2002, 106, 4, 603-611, https://doi.org/10.1021/jp0116306 . [all data]

Bogdanov and McMahon, 2006
Bogdanov, B.; McMahon, T.B., Gas phase S(N)2 reactions of halide ions with trifluoromethyl halides: Front- and back-side attack vs. complex formation, J. Phys. Chem. A, 2006, 110, 4, 1350-1363, https://doi.org/10.1021/jp0541011 . [all data]

Bogdanov, Peschke, et al., 1999
Bogdanov, B.; Peschke, M.; Tonner, D.S.; Szulejko, J.E.; McMahon, T.B., Stepwise solvation of halides by alcohol molecules in the gas phase, Int. J. Mass Spectrom., 1999, 187, 707-725, https://doi.org/10.1016/S1387-3806(98)14180-5 . [all data]

Giles and Grimsrud, 1993
Giles, K.; Grimsrud, E.P., Measurements of Equilibria and Reactivity of Cluster Ions at Atmospheric Pressure - Reactions of Cl-(CHCl3)0-2 with CH3Br and CH3I, J. Phys. Chem., 1993, 97, 7, 1318, https://doi.org/10.1021/j100109a012 . [all data]

Hiraoka, Mizuse, et al., 1987
Hiraoka, K.; Mizuse, S.; Yamabe, S., High Symmetric Structure of the Gas Phase Ion Cluster X-..C6F6 (X = Cl, Br, I), J. Phys. Chem., 1987, 91, 20, 5294, https://doi.org/10.1021/j100304a032 . [all data]

Magnera, Caldwell, et al., 1984
Magnera, T.F.; Caldwell, G.; Sumner, J.; Ikuta, S.; Kebarle, P., Solvation of the halide anions in dimethyl sulfoxide. Factors involved in enhanced reactivity of negative ions in dipolar aprotic solvents, J. Am. Chem. Soc., 1984, 106, 6140. [all data]

Hiraoka, Mizuno, et al., 2001
Hiraoka, K.; Mizuno, T.; Iino, T.; Eguchi, D.; Yamabe, S., Characteristic changes of bond energies for gas-phase cluster ions of halide ions with methane and chloromethanes, J. Phys. Chem. A, 2001, 105, 20, 4887-4893, https://doi.org/10.1021/jp010143n . [all data]

Zhao, Yourshaw, et al., 1994
Zhao, Y.X.; Yourshaw, I.; Reiser, G.; Arnold, C.C.; Neumark, D.M., Study of the ArBr(-), ArI(-), and KrI(-) anions and the corresponding neutral van der Waals complexes by anion zero electron kinetic energy, J. Chem. Phys., 1994, 101, 8, 6538, https://doi.org/10.1063/1.468500 . [all data]

Gatland, 1984
Gatland, I.R., Determination of Ion-Atom Potentials from Mobility Experiments. in Swarms of Ions and Electrons In Gases, W. Lindinger, Ed., Springer-Verlag, NY,, 1984, 44. [all data]

Tanabe, Morgon, et al., 1996
Tanabe, F.K.J.; Morgon, N.H.; Riveros, J.M., Relative Bromide and Iodide Affinity of Simple Solvent Molecules Determined by FT-ICR, J. Phys. Chem., 1996, 100, 8, 2862-2866, https://doi.org/10.1021/jp952290p . [all data]

Hiraoka, Mizure, et al., 1988
Hiraoka, K.; Mizure, S.; Yamabe, S.; Nakatsuji, Y., Gas Phase Clustering Reactions of CN- and CH2CN- with MeCN, Chem. Phys. Lett., 1988, 148, 6, 497, https://doi.org/10.1016/0009-2614(88)80320-8 . [all data]

Wild, Milley, et al., 2000
Wild, D.A.; Milley, P.J.; Loh, Z.M.; Wolynec, P.P.; Weiser, P.S.; Bieske, E.J., Structural and Energetic Properties of the Br--C2H2 Anion Complex from Rotationally Resolved Mid-infrared Spectra And ab initio Calculations, J. Chem. Phys., 2000, 113, 3, 1075, https://doi.org/10.1063/1.481919 . [all data]

Markovich, Perera, et al., 1996
Markovich, G.; Perera, L.; Berkowitz, M.L.; Cheshnovsky, O., The Solvation of Cl-, Br-, and I- in Acetonitrile Cluster: Photoelectron Spectroscopy and Molecular Dynamics Simulations., J. Chem. Phys., 1996, 105, 7, 2675, https://doi.org/10.1063/1.472131 . [all data]

Lobring, Hao, et al., 2003
Lobring, K.C.; Hao, C.T.; Forbes, J.K.; Ivanov, M.R.J.; Bachrach, S.M.; Sunderlin, L.S., Bond strengths in ChCl(3)(-) and ChOCl(3)(-) (Ch = S, Se, Te): Experiment and theory, J. Phys. Chem. A, 2003, 107, 50, 11153-11160, https://doi.org/10.1021/jp030388v . [all data]

Heil, Check, et al., 2002
Heil, T.E.; Check, C.E.; Lobring, K.C.; Sunderlin, L.S., The thermochemistry of phosphorus tetrahalide anions, J. Phys. Chem. A, 2002, 106, 42, 10043-10048, https://doi.org/10.1021/jp021386y . [all data]

Hao, Gilbert, et al., 2006
Hao, C.; Gilbert, T.M.; Sunderlin, L.S., The Bond Dissociation Energies of SO3-X- (X = F, Cl, Br, and I), Can. J. Chem., 2006, 83, 11, 2013-2019, https://doi.org/10.1139/v05-216 . [all data]

Walker and Sunderlin, 1999
Walker, B.W.; Sunderlin, L.S., The thermochemistry of formic acid halide anion clusters, Int. J. Mass Spectrom., 1999, 184, 2-3, 183-189, https://doi.org/10.1016/S1387-3806(99)00008-1 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References