(1S,2E,6E,10R)-3,7,11,11-Tetramethylbicyclo[8.1.0]undeca-2,6-diene


Van Den Dool and Kratz RI, polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20BP-20BP-20RTX-WaxRTX-Wax
Column length (m) 50.50.50.60.60.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.220.220.220.220.22
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 220.220.220.230.230.
Heat rate (K/min) 2.2.2.2.2.
Initial hold (min)      
Final hold (min) 20.20.20.30.35.
I 1730.1708.1742.1699.1724.
ReferenceBoti, Koukoua, et al., 2007Castilho, Liu, et al., 2007Lesueur, de Rocca Serra, et al., 2007Muselli, Rossi, et al., 2007Paolini J., Costa J., et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-WaxDB-WaxHP-WaxDB-WaxPEG-20M
Column length (m) 60.30.30.60.25.
Carrier gas HeHeN2HeHe
Substrate      
Column diameter (mm) 0.220.250.250.320.25
Phase thickness (μm) 0.250.250.250.250.3
Tstart (C) 60.40.60.35.50.
Tend (C) 230.250.220.220.220.
Heat rate (K/min) 2.3.5.3.3.
Initial hold (min)  5.10. 1.
Final hold (min) 35.10.  5.
I 1724.1736.1737.1734.1728.
ReferencePaolini, Muselli, et al., 2007Aromdee and Sriubolmas, 2006Flamini, Tebano, et al., 2006Pala-Paul, Copeland, et al., 2006Rubiolo P., Matteodo M., et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10DB-WaxPEGDB-WaxDB-Wax
Column length (m) 30.60.30.30.30.
Carrier gas HeN2N2HeHe
Substrate      
Column diameter (mm) 0.20.250.320.250.25
Phase thickness (μm) 0.20.250.250.250.25
Tstart (C) 70.70.50.40.40.
Tend (C) 220.230.220.250.250.
Heat rate (K/min) 3.2.2.3.3.
Initial hold (min)  2.3.  
Final hold (min) 15.20.15.20.20.
I 1726.1736.1723.1718.1719.
ReferenceSalgueiro L.R., Pinto E., et al., 2006Choi, 2005Dob, Berramdane, et al., 2005Fanciullino, Gancel, et al., 2005Gancel, Ollitrault, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase InnowaxRTX-WaxBP-20MegawaxDB-Wax
Column length (m) 50.60.50.30.30.
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.250.220.220.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.60.60.40.60.
Tend (C) 220.230.230.220.220.
Heat rate (K/min) 2.2.2.2.5.
Initial hold (min) 3.  6.10.
Final hold (min) 20.35.35.10. 
I 1720.1724.1727.1688.1767.
ReferenceLee, Lee, et al., 2005Paolini, Costa, et al., 2005Vellutini, Baldovini, et al., 2005Verzera, Trozzi, et al., 2005Bertoli, Menichini, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxSupelcowax-10RTX-WaxHP-WaxDB-Wax
Column length (m) 60.30.30.30.30.
Carrier gas HeHeHeN2He
Substrate      
Column diameter (mm) 0.320.20.250.250.25
Phase thickness (μm) 0.250.20.250.250.25
Tstart (C) 32.70.45.60.40.
Tend (C) 220.220.240.220.200.
Heat rate (K/min) 3.3.3.5.4.
Initial hold (min)   6.10.5.
Final hold (min)  15.10. 20.
I 1733.1726.1707.1721.1711.
ReferenceBrophy, Goldsack, et al., 2004Cavaleiro, Salgueiro, et al., 2004Dugo, Mondello, et al., 2004Flamini, Luigi Cioni, et al., 2004Yu, Kim, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-WaxCarbowax 20MDB-WaxDB-WaxDB-Wax
Column length (m) 30.25.30.60.60.
Carrier gas N2HeHeN2H2
Substrate      
Column diameter (mm) 0.250.250.250.250.32
Phase thickness (μm) 0.250.30.250.250.25
Tstart (C) 60.50.40.70.40.
Tend (C) 220.200.250.230.245.
Heat rate (K/min) 5.3.3.2.1.5
Initial hold (min) 10.1. 2. 
Final hold (min)  20.20.20.20.
I 1721.1728.1707.1738.1719.
ReferenceBader, Caponi, et al., 2003Bicchi, Rubiolo, et al., 2003Brat, Rega, et al., 2003Choi, 2003Gancel, Ollitrault, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-WaxHP-InnowaxMegawaxBP-20DB-Wax
Column length (m) 30.30.30.50.60.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.220.50
Phase thickness (μm) 0.250.50.250.251.0
Tstart (C) 45.60.40.60.60.
Tend (C) 250.260.220.220.225.
Heat rate (K/min) 3.3.2.2.3.
Initial hold (min) 6. 6.  
Final hold (min)   10.20. 
I 1704.1730.1688.1727.1732.
ReferenceShellie, Marriott, et al., 2003Skaltsa, Demetzos, et al., 2003Verzera, Trozzi, et al., 2003Lota, de Rocca Serra, et al., 2002Brophy, Goldsack, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxCP-Wax 52CBDB-WaxSupelcowax-10
Column length (m) 60.60.25.30.30.
Carrier gas HeHe HeHe
Substrate      
Column diameter (mm) 0.530.530.250.250.32
Phase thickness (μm) 1.01.00.150.250.25
Tstart (C) 50.50.40.40.75.
Tend (C) 220.220.220.200.200.
Heat rate (K/min) 3.3.3.2.2.5
Initial hold (min)   5.5. 
Final hold (min)    20. 
I 1732.1735.1744.1735.1706.
ReferenceBrophy, Goldsack, et al., 2000, 2Brophy, Goldsack, et al., 2000, 3Chagonda, Makanda, et al., 2000Kim, Thuy, et al., 2000Lazari, Skaltsa, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase MegawaxDB-WaxDB-WaxInnowaxCarbowax 20M
Column length (m) 30.60.60.60.25.
Carrier gas HeHeHeHeH2
Substrate      
Column diameter (mm) 0.250.530.530.250.25
Phase thickness (μm) 0.25  0.250.3
Tstart (C) 40.50.50.50.50.
Tend (C) 220.220.220.180.200.
Heat rate (K/min) 2.3.3.2.53.
Initial hold (min) 6.  5.1.
Final hold (min) 10.   20.
I 1688.1732.1732.1744.1726.
ReferenceVerzera, Trozzi, et al., 2000Brophy, Goldsack, et al., 1999Brophy, Goldsack, et al., 1999, 2Stashenko, Cervantes, et al., 1999Bicchi, Rubiolo, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxSP-1000DB-WaxDB-WaxCarbowax 20M
Column length (m) 60.85.60.60.25.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.320.50.320.320.25
Phase thickness (μm)     0.3
Tstart (C) 35.60.65.35.50.
Tend (C) 220.225.225.220.200.
Heat rate (K/min) 3.3.3.3.3.
Initial hold (min)     1.
Final hold (min)     20.
I 1739.1732.1732.1732.1729.
ReferenceBrophy, Forster, et al., 1998Brophy, Forster, et al., 1998, 2Brophy, Goldsack, et al., 1998Brophy, Goldsack, et al., 1998, 2Bicchi, Fresia, et al., 1997
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxSP-1000BP-20Supelcowax-10Carbowax 20M
Column length (m) 60.85.50.60.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.50.220.250.2
Phase thickness (μm)   0.250.250.2
Tstart (C) 65.65.60.60.30.
Tend (C) 225.225.230.230.170.
Heat rate (K/min) 3.3.2.5.4.
Initial hold (min)    5.2.
Final hold (min)   35.20.20.
I 1732.1732.1724.1755.1741.
ReferenceBrophy, Goldsack, et al., 1997Brophy, Goldsack, et al., 1997, 2Mariotti, Costa, et al., 1997Granicher, Christen, et al., 1995Píry, Príbela, et al., 1995
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Capillary
Active phase DB-Wax
Column length (m) 30.
Carrier gas He
Substrate  
Column diameter (mm) 0.32
Phase thickness (μm) 0.5
Tstart (C) 40.
Tend (C) 220.
Heat rate (K/min) 3.
Initial hold (min)  
Final hold (min)  
I 1728.
ReferenceLe Quere and Latrasse, 1990
Comment MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Brophy, Goldsack, et al., 2000, 2
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Brophy, Goldsack, et al., 2000, 3
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Chagonda, Makanda, et al., 2000
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Kim, Thuy, et al., 2000
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Lazari, Skaltsa, et al., 2000
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Notes

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