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Xenon cation


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar181.21J/mol*KReviewChase, 1998Data last reviewed in March, 1982

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(Xe+ bullet Xenon) + Xenon = (Xe+ bullet 2Xenon)

By formula: (Xe+ bullet Xe) + Xe = (Xe+ bullet 2Xe)

Quantity Value Units Method Reference Comment
Deltar28.kJ/molDTHelm, 1976gas phase; corrected for ln T by Keesee and Castleman, 1986
Deltar28.2kJ/molDTHelm, 1976gas phase; corrected for ln T by Keesee and Castleman, 1986
Quantity Value Units Method Reference Comment
Deltar78.2J/mol*KDTHelm, 1976gas phase; corrected for ln T by Keesee and Castleman, 1986
Deltar78.2J/mol*KDTHelm, 1976gas phase; corrected for ln T by Keesee and Castleman, 1986

Xe+ + Xenon = (Xe+ bullet Xenon)

By formula: Xe+ + Xe = (Xe+ bullet Xe)

Quantity Value Units Method Reference Comment
Deltar99.6kJ/molPINg, Trevor, et al., 1976gas phase
Deltar95.4kJ/molSCATTERINGMittman and Weise, 1974gas phase
Deltar93.7kJ/molSCATTERINGLorentz, Olson, et al., 1973gas phase
Deltar95.4kJ/molPISamson, 1966gas phase

Xe+ + Argon = (Xe+ bullet Argon)

By formula: Xe+ + Ar = (Xe+ bullet Ar)

Quantity Value Units Method Reference Comment
Deltar17.kJ/molPIDehmer and Pratt, 1982gas phase
Deltar25.kJ/molSIFTJones, Lister, et al., 1980gas phase
Deltar13.kJ/molPINg, Tiedemann, et al., 1977gas phase
Quantity Value Units Method Reference Comment
Deltar81.2J/mol*KSIFTJones, Lister, et al., 1980gas phase

(Xe+ bullet 2Xenon) + Xenon = (Xe+ bullet 3Xenon)

By formula: (Xe+ bullet 2Xe) + Xe = (Xe+ bullet 3Xe)

Quantity Value Units Method Reference Comment
Deltar25.2 ± 0.63kJ/molPHPMSHiraoka and Mori, 1990gas phase
Quantity Value Units Method Reference Comment
Deltar63.2J/mol*KPHPMSHiraoka and Mori, 1990gas phase

(Xe+ bullet 3Xenon) + Xenon = (Xe+ bullet 4Xenon)

By formula: (Xe+ bullet 3Xe) + Xe = (Xe+ bullet 4Xe)

Quantity Value Units Method Reference Comment
Deltar11.0 ± 0.63kJ/molPHPMSHiraoka and Mori, 1990gas phase
Quantity Value Units Method Reference Comment
Deltar54.8J/mol*KPHPMSHiraoka and Mori, 1990gas phase

Xe+ + Krypton = (Xe+ bullet Krypton)

By formula: Xe+ + Kr = (Xe+ bullet Kr)

Quantity Value Units Method Reference Comment
Deltar37.kJ/molPIDehmer and Pratt, 1982gas phase
Deltar36.kJ/molPINg, Tiedemann, et al., 1977gas phase

Xe+ + neon = (Xe+ bullet neon)

By formula: Xe+ + Ne = (Xe+ bullet Ne)

Quantity Value Units Method Reference Comment
Deltar4.0kJ/molPIDehmer and Pratt, 1982gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Helm, 1976
Helm, H., Formation of Xe3+ Ions in Xenon at Temperatures Between 210 and 293 K, Phys. Rev. A, 1976, 14, 2, 680, https://doi.org/10.1103/PhysRevA.14.680 . [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]

Ng, Trevor, et al., 1976
Ng, C.Y.; Trevor, D.J.; Mahan, B.H.; Lee, Y.T., Photoionization Study of the Xe2 van der Waals Molecule, J. Chem. Phys., 1976, 65, 10, 4327, https://doi.org/10.1063/1.432849 . [all data]

Mittman and Weise, 1974
Mittman, H.U.; Weise, H.P., Scattering of Ions V. Elastic Scattering of the Symmetric Rare Gas Ion - Rare Gas Atom Systems, Z. Naturforsch., 1974, A29, 400. [all data]

Lorentz, Olson, et al., 1973
Lorentz, D.C.; Olson, R.E.; Conklin, G.M., Rainbow Scattering for Ar+ + Ar and Xe+ + Xe, Chem. Phys. Lett., 1973, 20, 6, 589, https://doi.org/10.1016/0009-2614(73)80508-1 . [all data]

Samson, 1966
Samson, J.A.R., Ionization Potential of Molecular Xenon and Krypton, J. Opt. Soc. Am., 1966, 56, 8, 1140, https://doi.org/10.1364/JOSA.56.001140 . [all data]

Dehmer and Pratt, 1982
Dehmer, P.M.; Pratt, S.T., Photoionization of ArKr, ArXe, and KrXe and bond dissociation energies of the rare gas dimer ions, J. Chem. Phys., 1982, 77, 4804. [all data]

Jones, Lister, et al., 1980
Jones, J.D.C.; Lister, D.G.; Twiddy, N.D., Equilibrium Constant for the Reaction Xe+ + 2Ar ---> XeAr+ + Ar in the Temperature Range 150 - 300 K and the Dissociation Energy of XeAr+, Chem. Phys. Lett., 1980, 70, 3, 575, https://doi.org/10.1016/0009-2614(80)80128-X . [all data]

Ng, Tiedemann, et al., 1977
Ng, C.Y.; Tiedemann, P.W.; Mahan, B.H.; Lee, Y.T., Photoionization Studies of the Diatomic Internuclear Rare Gas Molecules XeKr, XeAr, and KrAr, J. Chem. Phys., 1977, 66, 12, 5737, https://doi.org/10.1063/1.433848 . [all data]

Hiraoka and Mori, 1990
Hiraoka, K.; Mori, T., Stability of Rare - Gas Cluster Ions, J. Chem. Phys., 1990, 92, 7, 4408, https://doi.org/10.1063/1.457751 . [all data]


Notes

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