Germacrene D


Van Den Dool and Kratz RI, polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20HP-InnowaxBP-20HP-20MHP-20M
Column length (m) 50.30.50.50.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.220.250.220.20.2
Phase thickness (μm) 0.250.250.250.20.2
Tstart (C) 60.60.60.70.70.
Tend (C) 220.280.220.180.180.
Heat rate (K/min) 2.3.2.4.4.
Initial hold (min)    4.4.
Final hold (min) 20. 20.10.15.
I 1705.1719.1705.1693.1681.
ReferenceBoti, Koukoua, et al., 2007Kundakovic, Fokialakis, et al., 2007Lesueur, de Rocca Serra, et al., 2007Maksimovic, Vidic, et al., 2007Maric, Jukic, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-WaxRTX-WaxRTX-WaxHP-20MHP-Innowax
Column length (m) 60.60.60.50.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.220.220.220.20.25
Phase thickness (μm) 0.250.250.250.20.5
Tstart (C) 60.60.60.70.60.
Tend (C) 230.230.230.180.260.
Heat rate (K/min) 2.2.2.4.3.
Initial hold (min)    4. 
Final hold (min) 30.35.35.15. 
I 1676.1701.1700.1673.1727.
ReferenceMuselli, Rossi, et al., 2007Paolini J., Costa J., et al., 2007Paolini, Muselli, et al., 2007Politeo, Jukic, et al., 2007Saroglou, Marin, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20Polyethylene GlycolHP-WaxBP-20Supelcowax-10
Column length (m) 50.30.30.50.30.
Carrier gas HeN2N2HeHe
Substrate      
Column diameter (mm) 0.220.320.250.220.2
Phase thickness (μm) 0.250.250.250.250.2
Tstart (C) 60.50.60.60.70.
Tend (C) 220.230.220.220.220.
Heat rate (K/min) 2.2.5.2.3.
Initial hold (min)  10.10.  
Final hold (min) 20.15. 20.15.
I 1701.1710.1712.1707.1699.
ReferenceBoti, Bighelli, et al., 2006Dob, Dahmane, et al., 2006Flamini, Tebano, et al., 2006Gonny, Cavaleiro, et al., 2006Pinto, Pina-Vaz, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10BP-20PEGDB-WaxDB-Wax
Column length (m) 30.50.30.30.30.
Carrier gas HeHeN2HeHe
Substrate      
Column diameter (mm) 0.20.220.320.250.25
Phase thickness (μm) 0.20.250.250.250.25
Tstart (C) 70.60.50.40.40.
Tend (C) 220.220.220.250.250.
Heat rate (K/min) 3.2.2.3.3.
Initial hold (min)   3.  
Final hold (min) 15.20.15.20.20.
I 1699.1703.1702.1693.1690.
ReferenceSalgueiro L.R., Pinto E., et al., 2006Boti J.B., Koukoua G., et al., 2005Dob, Berramdane, et al., 2005Fanciullino, Gancel, et al., 2005Gancel, Ollitrault, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase InnowaxRTX-WaxBP-20MegawaxDB-Wax
Column length (m) 50.60.50.30.30.
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.250.220.220.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.60.60.40.60.
Tend (C) 220.230.230.220.220.
Heat rate (K/min) 2.2.2.2.5.
Initial hold (min) 3.  6.10.
Final hold (min) 20.35.35.10. 
I 1694.1701.1704.1664.1716.
ReferenceLee, Lee, et al., 2005Paolini, Costa, et al., 2005Vellutini, Baldovini, et al., 2005Verzera, Trozzi, et al., 2005Bertoli, Menichini, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-WaxDB-WaxSupelcowax-10HP-WaxHP-Wax
Column length (m) 30.60.30.30.30.
Carrier gas N2HeHeHeN2
Substrate      
Column diameter (mm) 0.250.320.20.250.25
Phase thickness (μm) 0.250.250.20.250.25
Tstart (C) 60.32.70.60.60.
Tend (C) 220.220.220.240.240.
Heat rate (K/min) 5.3.3.3.3.
Initial hold (min) 10.    
Final hold (min)   15.  
I 1716.1708.1703.1722.1722.
ReferenceBertoli, Pistelli, et al., 2004Brophy, Goldsack, et al., 2004Cavaleiro, Salgueiro, et al., 2004Flamini, Bader, et al., 2004Flamini, Cioni, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-WaxBP-20HP-InnowaxDB-WaxDB-Wax
Column length (m) 30.50.30.30.30.
Carrier gas N2 HeHeHe
Substrate      
Column diameter (mm) 0.250.220.250.250.25
Phase thickness (μm) 0.250.250.50.250.25
Tstart (C) 60.60.60.40.40.
Tend (C) 220.220.260.200.200.
Heat rate (K/min) 5.2.3.4.4.
Initial hold (min) 10.  5.5.
Final hold (min)  20. 20.20.
I 1722.1706.1726.1694.1685.
ReferenceFlamini, Luigi Cioni, et al., 2004Gonny, Bradesi, et al., 2004Grujic-Jovanovic, Skaltsa, et al., 2004Yu, Kim, et al., 2004Yu, Kim, et al., 2004, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxHP-WaxHP-WaxDB-WaxDB-Wax
Column length (m) 30.30.30.30.60.
Carrier gas HeN2N2HeN2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.60.60.40.70.
Tend (C) 200.220.220.250.230.
Heat rate (K/min) 4.5.5.3.2.
Initial hold (min) 5.10.10. 2.
Final hold (min) 20.  20.20.
I 1701.1699.1722.1678.1722.
ReferenceZheng, Kim, et al., 2004Bader, Caponi, et al., 2003Bader, Caponi, et al., 2003, 2Brat, Rega, et al., 2003Choi, 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-WaxDB-WaxRTX-WaxHP-InnowaxHP-Innowax
Column length (m) 30.60.30.30.30.
Carrier gas N2H2HeHeHe
Substrate      
Column diameter (mm) 0.250.320.250.250.25
Phase thickness (μm) 0.250.250.250.50.5
Tstart (C) 60.40.45.60.60.
Tend (C) 220.245.250.260.260.
Heat rate (K/min) 5.1.53.3.3.
Initial hold (min) 10. 6.  
Final hold (min)  20.   
I 1722.1690.1684.1727.1710.
ReferenceEmilio Tomei, Manganelli, et al., 2003Gancel, Ollitrault, et al., 2003Shellie, Marriott, et al., 2003Skaltsa, Demetzos, et al., 2003Tzakou, Couladis, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase MegawaxDB-WaxBP-20RTX-WaxAT-Wax
Column length (m) 30.60.50.30.60.
Carrier gas HeN2HeHeHe
Substrate      
Column diameter (mm) 0.250.250.220.250.32
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.70.60.45.65.
Tend (C) 220.230.220.250.250.
Heat rate (K/min) 2.2.2.3.2.
Initial hold (min) 6.  6.10.
Final hold (min) 10.20.20.10.60.
I 1664.1705.1704.1681.1684.
ReferenceVerzera, Trozzi, et al., 2003Choi, Kim. M.-S.L., et al., 2002Lota, de Rocca Serra, et al., 2002Mondello, Zappia, et al., 2002Pino, Marbot, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxHP-InnowaxBP-20AT-WaxBP-20
Column length (m) 30.30.50.60.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.220.320.22
Phase thickness (μm) 0.500.500.250.250.25
Tstart (C) 60.60.60.65.60.
Tend (C) 260.260.220.250.220.
Heat rate (K/min) 3.3.2.2.2.
Initial hold (min)    10. 
Final hold (min) 10.  60.20.
I 1713.1710.1704.1684.1701.
ReferenceCouladis, Baziou, et al., 2001Couladis, Tzakou, et al., 2001Lota, Serra, et al., 2001Pino, Marbot, et al., 2001Rezzi, Bighelli, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20DB-WaxDB-WaxDB-WaxCP-Wax 52CB
Column length (m) 50.60.60.60.25.
Carrier gas  HeHeHe 
Substrate      
Column diameter (mm) 0.220.50.530.530.25
Phase thickness (μm) 0.250.321.01.00.15
Tstart (C) 60.40.50.50.40.
Tend (C) 220.290.220.220.220.
Heat rate (K/min) 2.4.3.3.3.
Initial hold (min)  2.  5.
Final hold (min) 20.5.   
I 1704.1717.1715.1715.1708.
ReferenceBaldovini, Ristorcelli, et al., 2000Bartley and Jacobs, 2000Brophy, Goldsack, et al., 2000Brophy, Goldsack, et al., 2000, 2Chagonda, Makanda, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxSupelcowax-10BP-20BP-20
Column length (m) 60.30.30.50.50.
Carrier gas N2HeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.320.220.22
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 70.40.75.60.60.
Tend (C) 230.200.200.230.230.
Heat rate (K/min) 2.2.2.52.2.
Initial hold (min) 2.5.   
Final hold (min) 20.20. 35.35.
I 1724.1707.1710.1697.1704.
ReferenceChoi and Sawamura, 2000Kim, Thuy, et al., 2000Lazari, Skaltsa, et al., 2000Lota, de Rocca Serra, et al., 2000Lota, de Rocca Serra, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase MegawaxDB-WaxBP-20InnowaxCarbowax 20M
Column length (m) 30.60.50.60.25.
Carrier gas HeHeHeHeH2
Substrate      
Column diameter (mm) 0.250.530.220.250.25
Phase thickness (μm) 0.25 0.250.250.3
Tstart (C) 40.50.60.50.50.
Tend (C) 220.220.230.180.200.
Heat rate (K/min) 2.3.2.2.53.
Initial hold (min) 6.  5.1.
Final hold (min) 10. 35. 20.
I 1664.1715.1704.1721.1690.
ReferenceVerzera, Trozzi, et al., 2000Brophy, Goldsack, et al., 1999Lota, Serra, et al., 1999Stashenko, Cervantes, et al., 1999Bicchi, Rubiolo, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxCarbowax 20MSP-1000DB-Wax
Column length (m) 60.60.25.85.60.
Carrier gas HeHe HeHe
Substrate      
Column diameter (mm) 0.320.320.250.50.32
Phase thickness (μm)   0.3 0.5
Tstart (C) 65.35.50.65.50.
Tend (C) 225.220.200.225.225.
Heat rate (K/min) 3.3.3.3.2.
Initial hold (min)   1.  
Final hold (min)   20. 20.
I 1715.1715.1696.1715.1714.
ReferenceBrophy, Goldsack, et al., 1998Brophy, Goldsack, et al., 1998, 2Bicchi, Fresia, et al., 1997Brophy, Goldsack, et al., 1997Sagrero-Nieves, Bartley, et al., 1997
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP-Wax 52CBDB-WaxCarbowax 20MDB-WaxHP-20M
Column length (m) 50.60.50.60.50.
Carrier gas H2HeHeHeHe
Substrate      
Column diameter (mm) 0.230.250.20.200.25
Phase thickness (μm) 0.120.250.20.20 
Tstart (C) 50.50.30.70.60.
Tend (C) 200.180.170.180.190.
Heat rate (K/min) 1.52.54.2.3.
Initial hold (min) 10.5.2.5. 
Final hold (min) 10. 20.  
I 1720.1726.1708.1713.1705.
ReferenceChyau, Mau, et al., 1996Stashenko, Prada, et al., 1996Píry, Príbela, et al., 1995Stashenko, Wiame, et al., 1995Chung, Eiserich, et al., 1993
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Capillary
Active phase DB-Wax
Column length (m) 30.
Carrier gas He
Substrate  
Column diameter (mm) 0.32
Phase thickness (μm) 0.5
Tstart (C) 40.
Tend (C) 220.
Heat rate (K/min) 3.
Initial hold (min)  
Final hold (min)  
I 1702.
ReferenceLe Quere and Latrasse, 1990
Comment MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Boti, Koukoua, et al., 2007
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Bartley and Jacobs, 2000
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Choi, H.-S.; Sawamura, M., Composition of the essential oil of Citrus tamurana Hort. ex Tanaka (Hyuganatsu), J. Agric. Food Chem., 2000, 48, 10, 4868-4873, https://doi.org/10.1021/jf000651e . [all data]

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Kim, T.H.; Thuy, N.T.; Shin, J.H.; Baek, H.H.; Lee, H.J., Aroma-active compounds of miniature beefsteakplant (Mosla dianthera Maxim.), J. Agric. Food Chem., 2000, 48, 7, 2877-2881, https://doi.org/10.1021/jf000219x . [all data]

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Notes

Go To: Top, Van Den Dool and Kratz RI, polar column, temperature ramp, References