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2-Tetradecanone

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus306.7KN/ASunner, Svensson, et al., 1979Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Tc727.7KN/APulliam, Gude, et al., 1995Uncertainty assigned by TRC = 4.8 K; TRC
Quantity Value Units Method Reference Comment
rhoc1.12mol/lN/APulliam, Gude, et al., 1995Uncertainty assigned by TRC = 0.03 mol/l; TRC
Quantity Value Units Method Reference Comment
Deltavap19.6 ± 0.1kcal/molS-FSunner, Svensson, et al., 1979, 2AC
Quantity Value Units Method Reference Comment
Deltasub31.3 ± 0.1kcal/molCSunner, Svensson, et al., 1979, 2AC

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
478.70.132Weast and Grasselli, 1989BS
407.20.017Weast and Grasselli, 1989BS

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
15.7426.AStephenson and Malanowski, 1987Based on data from 411. - 560. K.; AC
13.3564.AStephenson and Malanowski, 1987Based on data from 549. - 643. K.; AC
15.4387.AStephenson and Malanowski, 1987Based on data from 372. - 551. K. See also Stull, 1947.; AC
12.3556.N/AAmbrose, Ellender, et al., 1975Based on data from 412. - 643. K.; AC

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Reference Comment
11.740306.7Sunner, Svensson, et al., 1979, 2DH
11.74306.7Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
38.29306.7Sunner, Svensson, et al., 1979, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sunner, Svensson, et al., 1979
Sunner, S.; Svensson, C.; Zelepuga, A.S., Enthalpies of Vaporization at 298.15 for Some 2-ALkanones and Methyl Alkanoates, J. Chem. Thermodyn., 1979, 11, 491-5. [all data]

Pulliam, Gude, et al., 1995
Pulliam, M.K.; Gude, M.T.; Teja, A.S., Critical Temperatures and Densities of n-Alkanones, J. Chem. Eng. Data, 1995, 40, 455-8. [all data]

Sunner, Svensson, et al., 1979, 2
Sunner, S.; Svensson, Ch.; Zelepuga, A.S., Enthalpies of vaporization at 298.15 K for some 2-alkanones and methyl alkanoates, J. Chem. Thermodyn., 1979, 11, 491-495. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Ambrose, Ellender, et al., 1975
Ambrose, D.; Ellender, J.H.; Lees, E.B.; Sprake, C.H.S.; Townsend, R., Thermodynamic properties of organic oxygen compounds XXXVIII. Vapour pressures of some aliphatic ketones, The Journal of Chemical Thermodynamics, 1975, 7, 5, 453-472, https://doi.org/10.1016/0021-9614(75)90275-X . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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