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Molybdenum tetrafluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

View reactions leading to F4Mo+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
<2.28095TDEqBorshchevskii, Boltalina, et al., 1988B

Ionization energy determinations

IE (eV) Method Reference Comment
9.7 ± 0.2EIAlikhanyan, Steblevskii, et al., 1978LLK
10.11 ± 0.10EIHildenbrand, 1976LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
F2Mo+19.0 ± 1.0?EIAlikhanyan, Steblevskii, et al., 1978LLK
F3Mo+14.0 ± 0.5FEIAlikhanyan, Steblevskii, et al., 1978LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Borshchevskii, Boltalina, et al., 1988
Borshchevskii, A.Ya.; Boltalina, O.V.; Sorokin, I.D.; Sidorov, L.N., Thermochemical Quantities for Gas Phase Iron, Uranium, and Molybdenum Fluorides, and Their Negative Ions., J. Chem. Thermodyn., 1988, 20, 5, 523, https://doi.org/10.1016/0021-9614(88)90080-8 . [all data]

Alikhanyan, Steblevskii, et al., 1978
Alikhanyan, A.S.; Steblevskii, A.V.; Malkerova, I.P.; Pervov, V.S.; Butskii, V.D.; Gorgoraki, V.I., Mass spectrometric study of the sublimation of molybdenum trifluoride, Russ. J. Inorg. Chem., 1978, 23, 814. [all data]

Hildenbrand, 1976
Hildenbrand, D.L., Thermochemical studies of the gaseous lower valent fluorides of molybdenum, J. Chem. Phys., 1976, 65, 614. [all data]


Notes

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