N,N'-Diethyl-N,N'-dimethylhydrazine
- Formula: C6H16N2
- Molecular weight: 116.2046
- IUPAC Standard InChI: InChI=1S/C6H16N2/c1-5-7(3)8(4)6-2/h5-6H2,1-4H3
- IUPAC Standard InChIKey: WRWLUVYSSFLJRO-UHFFFAOYSA-N
- CAS Registry Number: 23337-93-1
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
View reactions leading to C6H16N2+ (ion structure unspecified)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| Proton affinity (review) | 230.3 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
| Quantity | Value | Units | Method | Reference | Comment |
| Gas basicity | 223.0 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 6.75 ± 0.05 | EQ | Rumack, 1986 | LBLHLM |
| 8.34 | PE | Nelsen, 1984 | Vertical value; LBLHLM |
| 8.08 | PE | Nelsen, Peacock, et al., 1976 | Vertical value; LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Rumack, 1986
Rumack, D.,
Title unavailable,
Personal communication to S.G. Lias, 1986. [all data]
Nelsen, 1984
Nelsen, S.F.,
Ionization from nitrogen and oxygen lone pairs: A comparison of trialkylamine, dialkyl ether, tetraalkylhydrazine, and dialkyl peroxide photoelectron spectroscopic ionization potentials,
J. Org. Chem., 1984, 49, 1891. [all data]
Nelsen, Peacock, et al., 1976
Nelsen, S.F.; Peacock, V.; Weisman, G.R.,
Single-electron oxidation equilibria of tetraalkylhydrazines. Comparison of solution E° values and vapor-phase ionization potentials,
J. Am. Chem. Soc., 1976, 98, 5269. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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