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Benzo[h]quinoline

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus325.KN/ABuckingham and Donaghy, 1982BS
Quantity Value Units Method Reference Comment
Ttriple324.1KN/ASteele, Chirico, et al., 1989Uncertainty assigned by TRC = 0.01 K; extrapolation of T vs 1/f to 1; TRC
Quantity Value Units Method Reference Comment
Deltasub90.2 ± 2.0kJ/molCSteele, Chirico, et al., 1989, 2Author was aware that data differs from previously reported values; ALS
Deltasub90.2kJ/molN/ASteele, Chirico, et al., 1989, 2DRB
Deltasub90.2 ± 2.0kJ/molN/ASteele, Chirico, et al., 1989, 2AC
Deltasub80.8 ± 2.6kJ/molVMcEachern, Iniguez, et al., 1975ALS

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
611.20.959Weast and Grasselli, 1989BS
611.0.959Buckingham and Donaghy, 1982BS
496.0.063Buckingham and Donaghy, 1982BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
71.7 ± 0.1380.IPM.EBSteele, Chirico, et al., 1989, 2Based on data from 373. - 672. K.; AC
69.0 ± 0.1420.IPM.EBSteele, Chirico, et al., 1989, 2Based on data from 373. - 672. K.; AC
66.5 ± 0.1460.IPM.EBSteele, Chirico, et al., 1989, 2Based on data from 373. - 672. K.; AC
64.0 ± 0.1500.IPM.EBSteele, Chirico, et al., 1989, 2Based on data from 373. - 672. K.; AC
61.5 ± 0.3540.IPM.EBSteele, Chirico, et al., 1989, 2Based on data from 373. - 672. K.; AC
59.0 ± 0.3580.IPM.EBSteele, Chirico, et al., 1989, 2Based on data from 373. - 672. K.; AC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
80.8 ± 2.5308.MEMcEachern, Iniguez, et al., 1975Based on data from 293. - 323. K. See also Stephenson and Malanowski, 1987.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
14.103324.104Steele, Chirico, et al., 1989, 2DH
14.103324.104Steele, Chirico, et al., 1988DH
14.1324.1Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
43.51324.104Steele, Chirico, et al., 1989, 2DH
43.51324.104Steele, Chirico, et al., 1988DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Steele, Chirico, et al., 1989
Steele, W.V.; Chirico, R.D.; Hossenlopp, I.A.; Nguyen, A.; Smith, N.K.; Gammon, B.E., The thermodynamic properties of the five benzoquinolines, J. Chem. Thermodyn., 1989, 21, 81. [all data]

Steele, Chirico, et al., 1989, 2
Steele, W.V.; Chirico, R.D.; Hossenlopp, I.A.; Nguyen, A.; Smith, N.K.; Gammon, B.E., The thermodynamic properties of the five benzoquinolines, J. Chem. Thermodyn., 1989, 21, 81-107. [all data]

McEachern, Iniguez, et al., 1975
McEachern, D.M.; Iniguez, J.C.; Ornelas, H.C., Enthalpies of combustion and sublimation and vapor pressures of three benzoquinolines, J. Chem. Eng. Data, 1975, 20, 226-228. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Steele, Chirico, et al., 1988
Steele, W.V.; Chirico, R.D.; Hossenlopp, I.A.; Nguyen, A., The thermodynamic properties of the five benzoquinolines, NIPER Report, 1988, 337, 59p. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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