Selenium dibromide
- Formula: Br2Se
- Molecular weight: 238.77
- IUPAC Standard InChIKey: MNBLRJWKVLRTKV-UHFFFAOYSA-N
- CAS Registry Number: 22987-45-7
- Chemical structure:
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Reaction thermochemistry data
Go To: Top, Gas phase ion energetics data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
+ = Br3Se-
By formula: Br- + Br2Se = Br3Se-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 110. ± 5.9 | kJ/mol | CIDT | Lobring, Hao, et al., 2003 | gas phase |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.17 ± 0.05 | PE | Nagy-Felsobuki and Peel, 1980 | Vertical value; LLK |
9.07 | PE | De Leeuw, Mooyman, et al., 1979 | Vertical value; LLK |
Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
+ = Br3Se-
By formula: Br- + Br2Se = Br3Se-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 110. ± 5.9 | kJ/mol | CIDT | Lobring, Hao, et al., 2003 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lobring, Hao, et al., 2003
Lobring, K.C.; Hao, C.T.; Forbes, J.K.; Ivanov, M.R.J.; Bachrach, S.M.; Sunderlin, L.S.,
Bond strengths in ChCl(3)(-) and ChOCl(3)(-) (Ch = S, Se, Te): Experiment and theory,
J. Phys. Chem. A, 2003, 107, 50, 11153-11160, https://doi.org/10.1021/jp030388v
. [all data]
Nagy-Felsobuki and Peel, 1980
Nagy-Felsobuki, E.; Peel, J.B.,
Photoelectron spectra of sulfur dibromide and selenium dibromide,
Chem. Phys., 1980, 45, 189. [all data]
De Leeuw, Mooyman, et al., 1979
De Leeuw, D.M.; Mooyman, R.; De Lange, C.A.,
He(I) photoelectron spectroscopy of transient species: The SeX2 molecules (X = F, Cl and Br),
Chem. Phys., 1979, 38, 21. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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