H2SiO

• Formula: H₂OSi
• Molecular weight: 46.1008
• CAS Registry Number: 22755-01-7
• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

HOSi^- +  = H₂OSi

By formula: HOSi^- + H⁺ = H₂OSi

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess

De-protonation reactions

HOSi^- +  = H₂OSi

By formula: HOSi^- + H⁺ = H₂OSi

Vibrational and/or electronic energy levels

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Additional references: Jacox, 1994, page 145; Jacox, 1998, page 226; Bailleux, Bogey, et al., 1994; Bogey, Delcroix, et al., 1996

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Vibrational and/or electronic energy levels, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gronert, O'Hair, et al., 1990
Gronert, S.; O'Hair, R.A.J.; Prodnuk, S.; Suzle, D.; Damrauer, R.; DePuy, C.H., Gas-Phase Chemistry of the Silaformyl Anion, HSiO-, J. Am. Chem. Soc., 1990, 112, 3, 997, https://doi.org/10.1021/ja00159a016 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Withnall and Andrews, 1985
Withnall, R.; Andrews, L., Infrared spectroscopic evidence for silicon-oxygen double bonds: silanone and the silanoic and silicic acid molecules, J. Am. Chem. Soc., 1985, 107, 8, 2567, https://doi.org/10.1021/ja00294a070 . [all data]

Withnall and Andrews, 1985, 2
Withnall, R.; Andrews, L., Matrix reactions of silane and oxygen atoms. Infrared spectroscopic evidence for the silanol, silanone, and silanoic and silicic acid molecules, J. Phys. Chem., 1985, 89, 15, 3261, https://doi.org/10.1021/j100261a019 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Bailleux, Bogey, et al., 1994
Bailleux, S.; Bogey, M.; Demuynck, C.; Destombes, J.-L.; Walters, A., Millimeter-wave rotational spectrum of H2SiO, J. Chem. Phys., 1994, 101, 4, 2729, https://doi.org/10.1063/1.467654 . [all data]

Bogey, Delcroix, et al., 1996
Bogey, M.; Delcroix, B.; Walters, A.; Guillemin, J.-C., Experimentally Determined Structure of H2SiO by Rotational Spectroscopy and Isotopic Substitution, J. Mol. Spectrosc., 1996, 175, 2, 421, https://doi.org/10.1006/jmsp.1996.0048 . [all data]

Notes

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• Symbols used in this document:
  

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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