[2H3]acetonitrile

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(cyclopentadienide anion • 2C2D3N) + C2D3N = (cyclopentadienide anion • 3C2D3N)

By formula: (C5H5- • 2C2D3N) + C2D3N = (C5H5- • 3C2D3N)

Quantity Value Units Method Reference Comment
Δr42.7kJ/molPHPMSMeot-ner, 1988gas phase; Entropy change calculated or estimated, ΔrH<, CD3CN
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/AMeot-ner, 1988gas phase; Entropy change calculated or estimated, ΔrH<, CD3CN

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
21.232.PHPMSMeot-ner, 1988gas phase; Entropy change calculated or estimated, ΔrH<, CD3CN

(cyclopentadienide anion • C2D3N) + C2D3N = (cyclopentadienide anion • 2C2D3N)

By formula: (C5H5- • C2D3N) + C2D3N = (C5H5- • 2C2D3N)

Quantity Value Units Method Reference Comment
Δr54.8kJ/molPHPMSMeot-ner, 1988gas phase; CD3CN
Quantity Value Units Method Reference Comment
Δr95.4J/mol*KPHPMSMeot-ner, 1988gas phase; CD3CN

cyclopentadienide anion + C2D3N = (cyclopentadienide anion • C2D3N)

By formula: C5H5- + C2D3N = (C5H5- • C2D3N)

Quantity Value Units Method Reference Comment
Δr64.9kJ/molPHPMSMeot-ner, 1988gas phase
Quantity Value Units Method Reference Comment
Δr95.4J/mol*KPHPMSMeot-ner, 1988gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-ner, 1988
Meot-ner, M., The Ionic Hydrogen Bond and Solvation. 7. Interaction Energies of Carbanions with Solvent Molecules, J. Am. Chem. Soc., 1988, 110, 12, 3858, https://doi.org/10.1021/ja00220a022 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References