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[2H3]acetonitrile

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(cyclopentadienide anion bullet 2C2D3N) + C2D3N = (cyclopentadienide anion bullet 3C2D3N)

By formula: (C5H5- bullet 2C2D3N) + C2D3N = (C5H5- bullet 3C2D3N)

Quantity Value Units Method Reference Comment
Deltar42.7kJ/molPHPMSMeot-ner, 1988gas phase; Entropy change calculated or estimated, «DELTA»rH<, CD3CN
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/AMeot-ner, 1988gas phase; Entropy change calculated or estimated, «DELTA»rH<, CD3CN

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
21.232.PHPMSMeot-ner, 1988gas phase; Entropy change calculated or estimated, «DELTA»rH<, CD3CN

(cyclopentadienide anion bullet C2D3N) + C2D3N = (cyclopentadienide anion bullet 2C2D3N)

By formula: (C5H5- bullet C2D3N) + C2D3N = (C5H5- bullet 2C2D3N)

Quantity Value Units Method Reference Comment
Deltar54.8kJ/molPHPMSMeot-ner, 1988gas phase; CD3CN
Quantity Value Units Method Reference Comment
Deltar95.4J/mol*KPHPMSMeot-ner, 1988gas phase; CD3CN

cyclopentadienide anion + C2D3N = (cyclopentadienide anion bullet C2D3N)

By formula: C5H5- + C2D3N = (C5H5- bullet C2D3N)

Quantity Value Units Method Reference Comment
Deltar64.9kJ/molPHPMSMeot-ner, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar95.4J/mol*KPHPMSMeot-ner, 1988gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-ner, 1988
Meot-ner, M., The Ionic Hydrogen Bond and Solvation. 7. Interaction Energies of Carbanions with Solvent Molecules, J. Am. Chem. Soc., 1988, 110, 12, 3858, https://doi.org/10.1021/ja00220a022 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References