Dichlone anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

C10H4Cl2O2- + Methyl Alcohol = (C10H4Cl2O2- • Methyl Alcohol)

By formula: C10H4Cl2O2- + CH4O = (C10H4Cl2O2- • CH4O)

Quantity Value Units Method Reference Comment
Δr<6.3 ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
6.3343.PHPMSChowdhury, 1987gas phase; DG<; M

C10H4Cl2O2- + Acetonitrile = (C10H4Cl2O2- • Acetonitrile)

By formula: C10H4Cl2O2- + C2H3N = (C10H4Cl2O2- • C2H3N)

Quantity Value Units Method Reference Comment
Δr<6.3 ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
6.3343.PHPMSChowdhury, 1987gas phase; DG<; M

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chowdhury, Grimsrud, et al., 1987
Chowdhury, S.; Grimsrud, E.P.; Kebarle, P., Bonding of Charged Delocalized Anions to Protic and Dipolar Aprotic Solvent Molecules, J. Phys. Chem., 1987, 91, 10, 2551, https://doi.org/10.1021/j100294a021 . [all data]

Chowdhury, 1987
Chowdhury, S. Grimsrud, Bonding of Charge Delocalized Anions to Protic and Dipolar Aprotic Solvents, J. Phys. Chem., 1987, 91, 10, 2551, https://doi.org/10.1021/j100294a021 . [all data]


Notes

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