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Benzyl radical

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C12H7MnO5 (g) = C5MnO5 (g) + Benzyl radical (g)

By formula: C12H7MnO5 (g) = C5MnO5 (g) + C7H7 (g)

Quantity Value Units Method Reference Comment
Deltar135. ± 19.kJ/molICR/PESMartinho Simões, Schultz, et al., 1985Please also see Martinho Simões and Beauchamp, 1990. The reaction enthalpy was derived from the appearance energy of Mn(CO)5(+), 830. ± 19. kJ/mol, using Mn(CO)5(Bz) as the neutral precursor, together with the adiabatic ionization energy of Bz radical, 694.7 ± 1.9 kJ/mol Martinho Simões, Schultz, et al., 1985. The enthalpy of formation relies on -642.5 ± 9.4 kJ/mol for the enthalpy of formation of Mn(CO)5(Bz)(g)

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões, Schultz, et al., 1985
Martinho Simões, J.A.; Schultz, J.C.; Beauchamp, J.L., Organometallics, 1985, 4, 1238. [all data]

Martinho Simões and Beauchamp, 1990
Martinho Simões, J.A.; Beauchamp, J.L., Chem. Rev., 1990, 90, 629. [all data]


Notes

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