Tungsten, pentacarbonyl(phosphorus trichloride)-
- Formula: C5Cl3O5PW
- Molecular weight: 461.22
- CAS Registry Number: 21223-85-8
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 86.2 ± 1.7 | kJ/mol | N/A | Boxhoorn, Jesse, et al., 1978 |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.50 ± 0.05 | EI | Distefano, Innorta, et al., 1968 | RDSH |
| 8.39 | PE | Daamen, Boxhoorn, et al., 1978 | Vertical value; LLK |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Boxhoorn, Jesse, et al., 1978
Boxhoorn, G.; Jesse, A.C.; Ernsting, J.M.; Oskam, A.,
Thermochim. Acta, 1978, 27, 261. [all data]
Distefano, Innorta, et al., 1968
Distefano, G.; Innorta, G.; Pignataro, S.; Foffani, A.,
Correlation between the ionization potentials of transition metal complexes and of the corresponding ligands,
J. Organometal. Chem., 1968, 14, 165. [all data]
Daamen, Boxhoorn, et al., 1978
Daamen, H.; Boxhoorn, G.; Oskam, A.,
U. V. photoelectron (He I and He II) studies of M(CO)5PX3 (M=Cr, Mo, W and X=F, Cl, Br),
Inorg. Chim. Acta, 1978, 28, 263. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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