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Silane, methylenebis[trimethyl-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
9.5PEHosomi and Traylor, 1975Vertical value; LLK

De-protonation reactions

C7H19Si2- + Hydrogen cation = Silane, methylenebis[trimethyl-

By formula: C7H19Si2- + H+ = C7H20Si2

Quantity Value Units Method Reference Comment
Deltar1563. ± 9.2kJ/molG+TSRomer, Gatev, et al., 1998gas phase; B
Deltar1563. ± 17.kJ/molD-EABrinkman, Berger, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar1531. ± 8.4kJ/molIMRERomer, Gatev, et al., 1998gas phase; B
Deltar1531. ± 17.kJ/molH-TSBrinkman, Berger, et al., 1994gas phase; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hosomi and Traylor, 1975
Hosomi, A.; Traylor, T.G., Studies of interactions of adjacent carbon-metal «sigma» bonds by photoelectron spectroscopy, J. Am. Chem. Soc., 1975, 97, 3682. [all data]

Romer, Gatev, et al., 1998
Romer, B.; Gatev, G.G.; Zhong, M.; Brauman, J.I., Alpha-Stabilization by Silyl and Phosphino Substitution, J. Am. Chem. Soc., 1998, 120, 12, 2919, https://doi.org/10.1021/ja970279s . [all data]

Brinkman, Berger, et al., 1994
Brinkman, E.A.; Berger, S.; Brauman, J.I., alpha-Silyl-substituent stabilization of carbanions and silyl anions, J. Am. Chem. Soc., 1994, 116, 18, 8304, https://doi.org/10.1021/ja00097a042 . [all data]


Notes

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